Determinação simultânea de ferro e cobre em etanol combustível utilizando eletrodo de nanotubos de carbono modificados

Pós-graduação em Química - IQ

Desenvolvimento de sensores baseados em eletrodos modificados com pentacianonitrosilferratos para determinação de compostos sulfurados em gás natural

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Uma Análise da Heterogeneidade Intrassetorial no Brasil Na Última Década

O conceito de Heterogeneidade Estrutural (HE) pressupõe duas ideias: (i) nos países nos quais se pode afirmar que sua estrutura econômica é marcada pela HE, há uma significativa disparidade entre os níveis de produtividade do trabalho dos diversos agentes econômicos; (ii) tal disparidade se perpetua no tempo, quando não se acentua. Um olhar sobre o comportamento global da economia aponta para resultados positivos, representados por um crescimento da produtividade média do trabalho associado a uma redução no coeficiente de variação dessa produtividade, particularmente a partir do ano de 2006. Do ponto de vista da estrutura produtiva, isso indica um processo de “convergência para cima” (redução da heterogeneidade estrutural com aumento da produtividade). Uma análise do comportamento setorial indica que esse fato, a despeito dos resultados positivos no presente – que vêm se traduzindo nos ganhos sociais citados – há uma ameaça de vulnerabilidade na sustentação de processo. O crescimento da produtividade média da economia foi alavancado, basicamente, por um expressivo aumento da produtividade da agropecuária. A despeito disso, a produtividade desse setor ainda se situa em apenas cerca de 1/3 da produtividade média da economia, boa parte dessas atividades – entre as quais também se deve incluir a de Extração de petróleo e gás natural, que apresenta fortes perspectivas de crescimento nos próximos anos – são intensivas em recursos naturais, e fica patente a perda de competitividade dos setores industriais mais expostos à concorrência internacional. Assim, há uma sinalização de que a economia pode estar caminhando para uma fragilidade em relação à conjuntura internacional, criando dependência dos preços internacionais de commodities e do mercado financeiro global.

Análise energética em refino de petróleo

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Análise de sistemas de cogeração com gaseificação de licor negro no setor de papel e celulose

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo numérico de modelos de arrasto e do coeficiente de restituição no escoamento gás-sólido em leito fluidizado

Pós-graduação em Engenharia Mecânica - FEG

Avaliação do potencial genotóxico e mutagênico do efluente de uma refinaria de petróleo e dos rios sob sua influência, por meio de bioensaios com Oreochromis niloticus (Perciformes, Cichlidae)

The petrochemical industry represents a sector of intense activity, in constant expansion and great economic importance for Brazil. In order to be used in various human activities petroleum needs to suffer a refinement process that, besides requiring large amounts of water, produces large amounts of wastes, which are discharged in hydric resources. Petroleum is a complex mixture mainly comprised by hydrocarbons, many of them are recognized as toxic chemicals, which are able to induce a considerable environmental pollution. Since water is an important resource for the maintenance of ecosystems and is also the final receiver of effluent discharges of the petroleum industry, there is an imminent need to monitor, constantly, the hydric resources that are influenced by this industrial activity, so that it can be ensured the environmental health. This study aimed, mainly, to analyze the quality of water samples derived from refinement process performed of the largest petroleum refinery in Brazil (REPLAN), in distinct steps of the industry treatment, and waters of rivers associated to its activity. Micronuclei and Nuclear Abnormalities tests were performed in erythrocytes of the fish species Oreochromis niloticus exposed to water samples derived from refinery use and to rivers under the influence of their effluents, in order to evaluate its possible toxic, genotoxic and mutagenic effects. The results obtained show that the treatment carried out by the refinery, during the evaluated periods, was effective, since the substances present in the water samples did not induce significant genotoxic and/or mutagenic alterations in the genetic material of the test organisms. On the other hand, when the substances present in the refinery effluent mix with the ones derived from other industrial activities developed upstream of this industry, the resultant compound, in some periods, presented genotoxic potencial, characterized by a rise of erythrocytic...

Caracterização da sensibilidade ambiental da Baixada Santista no estado de São Paulo

This study aimed to perform the analysis and characterization of environmental sensitivity to oil from Baixada Santista in the State of São Paulo. The work was done by integrating data of physical environmet, socio-economic activities and the biological / ecological provided by the Research Group on Environmental Sensitivity to Oil Spill in the Institute of Geosciences and Exact Sciences of UNESP “Julio de Mesquita Filho” wich works in the conjunction with the Program of Human Resources Training in Geosciences and Environmental Sciences Applied to the Oil and Gas (PRH-05) of the National Petroleum Agency (ANP). Were also performed descriptive statistical analysis, based on dispersion and trend parameters, which allowed to answer questions related to environmental sensitivity index (ISL) prevalence, the predominance of the ISL by environment and the predominance of the environments of the area, thus providing an overview of Baixada Santista’s main towns about sensitivity to oil. Analyses performed in this study may also help mitigate the environmental and socioeconomic impacts and contribute to contingency plans development for Baixada Santista

Análise dos royalties do petróleo sob a perspectiva jurídica

This research aims to discuss the division of royalties from a legal perspective and its substitute role towards the non-taxation at source, in other words the taxation of destiny at the Brazilian petroleum industry. The analysis aims to deal with the historical evolution in relation to the aspect of royalties’ payment and its deviation of compensatory character in order to supply the ICMS function. There are some specific study objects in this research: 1. how the transformation of royalties’ payment led to financial compensation; 2. to whom the transference of mineral rent belongs – to the UNIÃO or to the fortunate regions which the oil is extracted; 3. would a tax reform be enough to minimize the competition of States and Cities towards the royalties? The research aims to clarify the real expectation that States have on the royalties’ payment. There is no compensation for damage to the environment as it is stated by the initial characteristic of the Constitution, and, by the contrast, from a compensatory character, there is a lacking of taxation from the sector mentioned before, this fact damages the producing states checked out by this research

Aspectos técnicos e ambientais da incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e gaseificação do bagaço

The purpose of this work is to study the incorporation of hydrogen production (Case A) and the process of gasification of sugarcane bagasse associated with combined cycle gas turbine and steam turbine (Case B) for Distillery Pioneers process. These technologies can be used to improve the energy supply in the sugarcane mill. Initially the processes for obtaining sugar and ethanol from sugarcane is discussed, with a theoretical introduction to hydrogen, the process of steam reforming and gasification of biomass (bagasse) by inserting a turbine associated with the recovery boiler gas. Subsequently makes up the energy and exergy analysis of the incorporation of the above technologies. In end stage makes it an ecological analysis considering or not the carbon cycle (photosynthesis), to determine the levels of emissions of pollutants, carbon dioxide equivalent, indicators of pollution and ecological efficiencies associated with technological developments proposed. It is concluded that hydrogen production by steam reforming of ethanol and gasification of bagasse are viable alternatives from the point of view of technical and environmental applications in the biofuels industry, contributing to the development of the sector in the country

Incorporação de novas tecnologias no setor sucroalcooleiro: produção de hidrogênio e aumento da oferta de eletricidade

This work studies the incorporation of new technologies in the sugarcane sector. Are considered the ethanol steam reforming and the gasification of sugarcane bagasse(by-product) processes associated with combined cycle systems (Gas Turbine + Steam Turbine), aggregating hydrogen production and increased electricity supply in the sector, respectively. To verify the technical feasibility of the incorporation processes was performed a thermodynamic analysis, considering data from a typical Brazilian Sugar Cane Industry. In another step the economic viability study of the hydrogen production process was made, with consideration on hydrated and anhydrous ethanol steam reform, comparing the cost of hydrogen production. Also considered studies of economic engineering of the gasification process and the generation of electricity associated. As conclusions, it follows that the ethanol steam reforming is a great alternative for hydrogen production, presenting production cost relatively low, especially when is considered the steam reforming of hydrated ethanol. For the gasification process associated with combined cycle, can be observed an increase of 8.56 times of the electricity production in the sugar cane industry, indicating a positive annual saving when the sales price of the supply electricity is greater than 0.070 US$/kWh. Finally it can be concluded that the incorporation of these new processes allow greater profitability and operational flexibility of Brazilian sugarcane mills

Desenvolvimento de recobrimento submicrométrico de óxido de nióbio para aplicação em tubulações de prospecção de petróleo

Pós-graduação em Engenharia Mecânica - FEG

Avaliação de recursos hídricos sob a influência de atividades de uma indústria do petróleo, por meio de análises ecotoxicológicas integradas a parâmetros ambientais

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Analise técnica, econômica e ecológica da incorporação de sistemas de gaseificação de bagaço de cana-de-açúcar no setor sucroalcooleiro: uso de ciclos combinados para o aumento da oferta de eletricidade

Pós-graduação em Engenharia Mecânica - FEG

Práticas de gestão da melhoria contínua e aprendizado e suas contribuições para a capacidade de inovação na indústria de construção naval do Brasil

After years of stagnation, the naval construction industry in Brazil has been experiencing a period of recovery caused by investments in the oil and gas sector and the implementation of governmental programs that aimed to regenerate it. However, efforts in learning and innovations are needed in order to reinsert the country in this activity and achieve international levels of competitiveness. Based on literature about learning processes and continuous improvement practices and their impact in the innovative and productive processes, this paper aims to identify the main tendencies, mechanisms and procedures to improve the construction and management processes in the Brazilian naval construction industry. The methodology used for the data analysis classifies obtained information from magazines and annals of congresses of the sector, according to the established analysis categories (phenomena). Such categories study information related to the productive and technological processes of the industry, the main internal and external relations of the industrial park, the management of resources and processes, policies, investments, etc. The data was collected in the period 2004-2010, and more than 500 registers that show a dominance of the investment phenomenon, especially in the increase of productive capacity, were catalogued. In addition to this, there is evidence of modernization in the manufacturing plan and the equipment, diverse forms of cooperation, implementation of human resources management practices and engineering or processes and products. Hence, a process of catching up governs and is guided by modernization and increase training in this industry.