Geochemistry and mineralogy of interstitial waters and clays in sediments of ODP Leg 180 sites

Oxygen and strontium isotopes and Rb and Ba were determined in interstitial water (IW) collected from Sites 1109, 1115, and 1118 drilled on the Woodlark Rise during Ocean Drilling Program Leg 180. The trace element and mineralogical composition of the clay fraction of sediments isolated from the squeeze cakes corresponding to IW samples from Site 1109 was also determined.

Primary composition, alteration, and origin of Cretaceous volcaniclastic rocks at DSDP Site 89-585

An upper Aptian to middle Albian series of volcaniclastic rocks more than 300 m thick was drilled at Site 585 in the East Mariana Basin. On the basis of textural and compositional (bulk-rock chemistry, primary and secondary mineral phases) evidence, the volcaniclastic unit is subdivided into a lower (below 830 m sub-bottom) and an upper (about 670-760 m) sequence; the boundary in the interval between is uncertain owing to lack of samples. The rocks are dominantly former vitric basaltic tuffs and minor lapillistones with lesser amounts of crystals and basaltic lithic clasts. They are mixed with shallow-water carbonate debris (ooids, skeletal debris), and were transported by mass flows to their site of deposition. The lower sequence is mostly plagioclase- and olivine-phyric with lesser amounts of Ti-poor clinopyroxene. Mineralogical and bulk-rock chemical data indicate a tholeiitic composition slightly more enriched than N-MORB (normal mid-ocean ridge basalt). Transport was by debris flows from shallow-water sites, as indicated by admixed ooids. Volcanogenic particles are chiefly moderately vesicular to nonvesicular blocky shards (former sideromelane) and less angular tachylite with quench plagioclase and pyroxene, indicating generation of volcanic clasts predominantly by spalling and breakage of submarine pillow and/or sheet-flow lavas. The upper sequence is mainly clinopyroxene- and olivine-phyric with minor plagioclase. The more Ti-rich clinopyroxene and the bulk-rock analyses show that the moderately alkali basaltic composition throughout is more mafic than the basal tholeiitic sequence. Transport was by turbidity currents. Rounded epiclasts of crystalline basalts are more common than in the lower sequence, and, together with the occurrence of oxidized olivine pseudomorphs and vesicular tachylite, are taken as evidence of derivation from eroded subaerially exposed volcanics. Former sideromelane shards are more vesicular than in the lower sequence; vesicularity exceeds 60 vol.% in some clasts. The dominant clastic process is interpreted to be by shallow-water explosive eruptions. All rocks have undergone low-temperature alteration; the dominant secondary phases are "palagonite," chlorite/smectite mixed minerals, analcite, and chabazite. Smectite, chlorite, and natrolite occur in minor amounts. Phillipsite is recognized as an early alteration product, now replaced by other zeolites. During alteration, the rocks have lost up to 50% of their Ca, compared with a fresh shard and fresh glass inclusions in primary minerals, but have gained much less K, Rb, and Ba than expected, indicating rapid deposition prior to significant seafloor weathering.

Mineral chemistry of primary and secondary phases in basaltic rocks

Primary magmatic phases (spinel, olivine, plagioclase, clinopyroxene, amphibole, and biotite) and secondary phyllosilicates (smectite, chlorite-smectite, and celadonite) were analyzed by electron microprobe in alkalic and tholeiitic dolerites and basalts from Ocean Drilling Program Sites 800, 801, and 802. Aphyric alkalic dolerite sills (Hole 800A) and basalt flows (Holes 801B and 801C) share common mineralogical features: matrix feldspars are strongly zoned from labradorite cores to discrete sodic rims of alkali feldspar with a high Or component, which overlaps that of quench microlites in glassy mesostasis; little fractionated clinopyroxenes are Ti-rich diopsides and augites (with marked aegirine-augite rims at Site 801); rare, brown, Fe**3+-rich amphibole is winchite; and late biotites exhibit variable Ti contents. Alkalic rims to feldspars probably developed at the same time as quenched mesostasis feldspars and late-stage magmatic biotite, and represent the buildup of K-rich hydrous fluids during crystallization. Phenocryst phases in primitive mid-ocean ridge tholeiites from Hole 801C (Mg numbers about 70) have extreme compositions with chrome spinel (Cr/Cr + Al ratios about 0.2-0.4), Ni-rich olivine (Fo90), and highly calcic plagioclase (An90). Later glomerophyric clumps of plagioclase (An75-80) and clinopyroxene (diopside-augite) are strongly zoned and probably reflect rapidly changing melt conditions during upward transport, prior to seafloor quenching. In contrast, phenocryst phases (olivine, plagioclase, and clinopyroxene) in the Hole 802A tholeiites show limited variation and do not have such primitive compositions, reflecting the uniform and different chemical composition of all the bulk rocks. Replacive phyllosilicates in both alkalic and tholeiitic basalts include various colored smectites (Fe-, Mg-, and Al-saponites), chlorite-smectite and celadonite. Smectite compositions typically reflect the replaced host composition; glass is replaced by brown Fe-saponites (variable Fe/Mg ratios) and olivine by greenish Mg-saponites (or Al-rich chlorite-smectite).

Isotopic ratios and geochemical composition of ODP Hole 176-735B minerals

The mineralogy and stable (O and C) and Sr isotopic compositions of low-temperature alteration phases were determined in Hole 735B gabbroic rocks in order to understand the processes of low-temperature alteration in this uplifted block of lower oceanic crust. Phyllosilicates include smectite (saponite, Mg montmorillonite, and nontronite), chlorite/smectite, chlorite, talc, and serpentine. Other phases include prehnite, albite, K-feldspar, analcite, natrolite, thompsonite, pyrite, and titanite. The low-grade mineral assemblages mainly represent zeolite facies and lower-temperature "seafloor weathering" processes. Phyllosilicates formed over a range of temperatures but may also reflect variable reaction progress. Alteration temperatures were probably somewhat greater below 1300 meters below seafloor. Mineralogy and isotopic data indicate that conditions were mostly reducing and that seawater solutions were rock dominated. Carbonates formed late from cold and generally oxidizing seawater solution, however, as seawater penetrated downward as the result of fracturing and faulting in the uppermost portion of the uplifted crustal block.

Metamorphic processes in sediments at DSDP Leg 65 Holes

Sites 482, 483, and 485 were drilled during Leg 65 on young oceanic crust south of the Tamayo Transform Fault. The Leg 65 drilling program was part of a multinational effort to study the East Pacific Rise (EPR) and complements sea bottom surveys conducted both in this area (Lewis, 1979; Cyamex Scientific Team and Pastouret, 1981) and farther south at 21 °N (Larson, 1971; Normark, 1976; Cyamex Scientific Team; Rise Project Group, 1980). These studies, which included deep-tow, Angus and submersible surveys, were recently complemented by sea-beam surveys conducted by the Jean Charcot on the Tamayo Fracture Zone and farther south along the EPR. They have led to a better understanding of the magmatic, tectonic, and sedimentary processes occurring on the East Pacific Rise between the Tamayo and Rivera fracture zones. The purpose of this chapter is to describe the metamorphic processes affecting Pliocene through Quaternary sediments found in contact, or inter layered, with basaltic units drilled during Leg 65 at the mouth of the Gulf of California.

Clay mineral assemblages for the last 10 Ma off northeastern Australia

Clay mineral assemblages for the last 10 m.y. are described for Site 823, at 16°S in the Queensland Trough, to the northeast of Australia. Largely unaffected by diagenetic influences, these mostly express the evolution of northeastern Australian continental environments during the late Neogene: (1) beginning during the late Miocene at about 7.0 Ma is an increase of illite derived from rocky substrates at the expense of smectite from deeply weathered soils; this increase was the result of increasing aridity in the Australian interior and globally cooler temperatures, associated with increases in Antarctic glaciation; (2) concomitant and further increases of kaolinite fluxes to the Queensland Trough during the late Miocene-early Pliocene largely reflect an increase in rainfall in northeastern Australia; (3) increases in both soil- and rock-derived minerals probably intensified as a result of late Neogene uplift of the eastern highlands; (4) clay-mineral associations during the Pliocene and Pleistocene display minor variations only and probably resulted in part from differential settling and sea-level changes; (5) similar trends of clay-mineral variations occur at both ODP Site 823 and DSDP Site 588 (Lord Howe Rise). Less abundant kaolinite relative to illite at Site 588 nevertheless suggests a southward decrease of continental humidity and/or of the eastern highlands uplift; (6) influences of global climate and oceanic and atmospheric circulations on clay-mineral associations dominated during the late Miocene and were progressively replaced by influences of more regional environmental variations during the Pliocene and especially the Pleistocene.

Minerals of bulk samples and clay fraction at DSDP Leg 80 Holes

At the request of the Leg 80 scientific party, selected samples of Cretaceous age were processed by X-ray diffraction at the mineralogy laboratories at the Ecole des Mines (Albian to Late Cretaceous samples) and at the Institut de Géologie at Dijon (Barremian samples). The results were used in developing the lithostratigraphy and sedimentology discussed in this volume by Rat et al. 1985 (doi:10.2973/dsdp.proc.80.140.1985) in their study of Barremian-Albian paleoenvironment, by Graciansky and Gillot in their study of Albian and Cenomanian limestones, and by Graciansky and Bourbon in their paleoenvironmental reconstructions for the Late Cretaceous chalks.

Mineralogical and geochemical analyses of serpentines from ODP Hole 125-778A

Thirty-five samples from Hole 778A were prepared for X-ray diffraction (XRD) mineralogical analyses and for chemical analyses of major and trace elements. Most of the selected samples were silt- and sand-sized sedimentary serpentinites or microbreccias except for a soft clast of mafic rock, a hard clast of massive serpentinized peridotite, and a pebble of consolidated, undeformed serpentine microbreccia that contained planktonic foraminifers. Both mineralogical and geochemical analyses allow discrimination of three groups among the analyzed samples. These groups correspond to three stratigraphic intervals present along the drilled section. Group A contains the upper samples (lithologic Unit I). These consist of poorly consolidated serpentine muds carrying hard-rock clasts (serpentinized peridotites, metabasalts). They are characterized by the following mineralogical assemblage: serpentine, Fe-oxides and hydroxides, aragonite, and halite. They exhibit variable SiO2, MgO contents, but are characterized by a SiO2/MgO ratio near 1. CaO content is high in relation to development of aragonite. Al2O3 content is low. Relatively high K2O, Na2O, and Sr contents are present, presumably in relation to interactions with seawater. Group B (30-77 mbsf) contains samples exhibiting very homogeneous chemical and mineralogical compositions. They consist of serpentinite microbreccias exhibiting frequent shear structures. Hard-rock clasts are also present (serpentinized peridotites, metabasalts, one possible chert fragment). The mineralogy of the Group B samples is characterized by the presence of serpentine and authigenic minerals: hydroxycarbonates and hydrogrossular. Calcite and chlorite are also present, but all the samples lack aragonite. Their chemical compositions are remarkably similar to compositions of their parent rocks. Group C contains silt- and sand-sized serpentine and serpentine microbreccias, which are locally rich in red clasts, probably strongly altered (oxidized?) mafic fragments. Intervals having clasts of more diverse origin than those higher in the section were recovered. Clast lithology includes serpentinized peridotites, metabasalts, metavolcaniclastite, meta-olivine gabbro, and amphibolite sandstone. Mineralogy and geochemistry reflect these compositions. Serpentine content of the samples is less than in previous groups. Correlatively, sepiolite, palygorskite, and chlorite-smectite are mineral phases present in the analyzed samples. Accessory igneous minerals (amphiboles, pyroxenes, hematite) also were found. The chemical compositions of most of Group C samples differ from that of massive serpentinized peridotites. The main differences are (1) higher SiO2, CaO, TiO2 and Al2O3 contents, (2) a SiO2/MgO ratio greater than 1, and (3) a negative correlation between Al2O3, and MgO, Cr, and Ni. These characteristics suggest new constraints relative to the flow structure of the flank of Conical Seamount.

Sedimentology on two core from the Bransfield Strait area

The raw material for these investigations are samples from marine (sub)surface sediments around the northern part of the Antarctic Peninsula. They had been sampled in the years 1981 to 1986 during several expeditions of the research vessels Meteor, Polarstern and Walther Herwig. 83 box core, gravity core and dredge samples from the area of the Bransfield Strait, the Powell Basin and the northern Weddell Sea have been examined for their grain-size distribution, their mineralogical and petrographical composition. Silt prevails and its clay proportions exceed 25% wt. in water depths greater than 2000 m. The granulometrical results reveal some typical sedimentation processes within the area of investigation. While turbiditic processes together with sediment input from melting icebergs control the sedimentation in the Weddell Sea, the South Orkney Island Plateau and the Powell Basin, the fine grained material from Bransfield Strait mainly relies on marine currents in the shelf area. In addition, the direct sediment input of coarse shelf sediments from the Bransfield Strait into the Powell Basin through submarine canyons could be proven. Variations in the grain-size composition with sediment depth are smalI. The mineral composition of the clay and fine silt fractions is quite uniform in all samples. There are (in decreasing order): illite, montmorillonite, chlorite, smectite, mixed-Iayers, as well as detrital quartz and feldspars. A petrographically based sediment stratigraphy can be established in using the considerable changes in the chlorite- and Ca-plagioclase portions in samples from Core 224. For this sedimentation area a mean sedimentation rate of 7 cm/1000 a is assumed. Remarkable changes in the portions of amorphous silica components - diatom skeletons and volcanic glass shards - appear all over the area of investigation. They contribute between 4-83 % to the clay and fine silt fraction. Several provinces according to the heavy mineral assemblages in the fine sand fraction can be distinguished: (i) a province remarkably influenced by minerals of volcanic origin south and north of the South Shetland Islands; (ii) a small strip with sediment dominated by plutonic material along the western coast of the Antarctic Peninsula and (iii) a sediment controlled by metamorphic minerals and rock fragments in the area of the Weddell Sea and Elephant Island. While taking the whole grain-size spectrum into account a more comprehensive interpretation can be given: the accessoric but distinct appearance of tourmaline, rutile and zircon in the heavy mineral assembly along the northwestern coast of the Antarctic Peninsula is in agreement with the occurrence of acid volcanic rock pieces in the coarse fraction of the ice load detritus in this region. In the vicinity of the South Shetland Islands chlorite appears in remarkable portions in the clay fraction in combination with leucoxene, sphene and olivine, and pumice as well as pyroclastic rocks in the medium and coarse grain fractions, respectively. Amphiboles and amphibole-schists are dominant on the South Orkney Island Plateau. In the sediments of the northwestern Weddell Sea the heavy mineral phases of red spinel, garnet, kyanite and sillimanite in connection with medium to highgrade metamorphic rocks especially granulitic gneisses, are more abundant. A good conformity between the ice rafted rock sampIes and the rocks in the island outcrops could be proven, especially in the vicinity of offshore islands nearby. On the continent enrichments of rock societies and groups appear in spacious outlines: acid effusive rocks in the west of the ice divide on the Antarctic Peninsula, clastic sedimentites at the tip of the Antarctic Peninsula and granoblastic gneisses in central and eastern Antarctica. Coarse grain detritus with more than 1 cm of diameter must have been rafted by icebergs. These rock fragments are classified as rock types, groups and societies. The spacial distribution of their statistically determined weight relations evidently shows the paths of the iceberg drift and in nexus with already known iceberg routes also point to the possible areas of provenance, provided that the density of sample locations and the number of rock pieces are sufficient.

Chemistry of secondary minerals from the deep sheeted dike complex of ODP Holes 137-504B and 140-504B

Dolerites sampled from the lower sheeted dikes from Hole 504B during Ocean Drilling Program Legs 137 and 140, between 1562.4 and 2000.4 mbsf, were examined to document the mineralogy, petrography, and mineral parageneses associated with secondary alteration, to constrain the thermal history and composition of hydrothermal fluids. The main methods used were mineral chemical analyses by electron microprobe, X-ray diffraction, and cathodoluminescence microscopy. Temperatures of alteration were estimated on the basis of single and/or coexisting mineral chemistry. Permeability is important in controlling the type and extent of alteration in the studied dike section. At the meter-scale, intervals of weakly altered dolerites containing fresh olivine are interpreted as having experienced restricted exposure to hydrothermal fluids. At the centimeter- or millimeter-scale, alteration patches and extensively altered halos adjacent to veins reflect the permeability related to intergranular primary porosity and cracks. Most of the sheeted dike alteration in this case resulted from non-focused, pervasive fluid-rock interaction. This study confirms and extends the previous model for hydrothermal alteration at Hole 504B: hydrothermal alteration at the ridge axis followed by seawater recharge and off-axis alteration. The major new discoveries, all related to higher temperatures of alteration, are: (1) the presence of hydrothermal plagioclase (An80-95), (2) the presence of deuteric and/or hydrothermal diopside, and (3) the general increasing proportion of amphiboles, and particularly magnesio-hornblende with depth. We propose that the dolerites at Hole 504B were altered in five stages. Stage 1 occurred at high temperatures (less than 500° to 700°C) and involved late-magmatic formation of Na- and Ti-rich diopside, the hydrothermal formation of Na, Ti-poor diopside and the hydrothermal formation of an assemblage of An-rich plagioclase + hornblende. Stage 2 occurred at lower temperatures (250°-320°C) and is characterized by the appearance of actinolite, chlorite, chlorite-smectite, and/or talc (in low permeability zones) and albite. During Stage 3, quartz and epidote precipitated from evolved hydrothermal fluids at temperatures between 310° and 320°C. Anhydrite appeared during Stage 4 and likely precipitated directly from heated seawater. Stage 5 occurred off-axis at low temperatures (250°C) with laumontite and prehnite from evolved fluids.