Diseño de un Procesador de Membranas Paralelo para los Sistemas P de Transición

La computación con membranas surge como una alternativa a la computación tradicional. Dentro de este campo se sitúan los denominados Sistemas P de Transición que se basan en la existencia de regiones que contienen recursos y reglas que hacen evolucionar a dichos recursos para poder llevar a cada una de las regiones a una nueva situación denominada configuración. La sucesión de las diferentes configuraciones conforman la computación. En este campo, el Grupo de Computación Natural de la Universidad Politécnica de Madrid lleva a cabo numerosas investigaciones al amparo de las cuales se han publicado numerosos artículos y realizado varias tesis doctorales. Las principales vías de investigación han sido, hasta el momento, el estudio del modelo teórico sobre el que se definen los Sistemas P, el estudio de los algoritmos que se utilizan para la aplicación de las reglas de evolución en las regiones, el diseño de nuevas arquitecturas que mejoren las comunicaciones entre las diferentes membranas (regiones) que componen el sistema y la implantación de estos sistemas en dispositivos hardware que pudiesen definir futuras máquinas basadas en este modelo. Dentro de este último campo, es decir, dentro del objetivo de construir finalmente máquinas que puedan llevar a cabo la funcionalidad de la computación con Sistemas P, la presente tesis doctoral se centra en el diseño de dos procesadores paralelos que, aplicando variantes de algoritmos existentes, favorezcan el crecimiento en el nivel de intra-paralelismo a la hora de aplicar las reglas. El diseño y creación de ambos procesadores presentan novedosas aportaciones al entorno de investigación de los Sistemas P de Transición en tanto en cuanto se utilizan conceptos que aunque previamente definidos de manera teórica, no habían sido introducidos en el hardware diseñado para estos sistemas. Así, los dos procesadores mantienen las siguientes características: - Presentan un alto rendimiento en la fase de aplicación de reglas, manteniendo por otro lado una flexibilidad y escalabilidad medias que son dependientes de la tecnología final sobre la que se sinteticen dichos procesadores. - Presentan un alto nivel de intra-paralelismo en las regiones al permitir la aplicación simultánea de reglas. - Tienen carácter universal en tanto en cuanto no depende del carácter de las reglas que componen el Sistema P. - Tienen un comportamiento indeterminista que es inherente a la propia naturaleza de estos sistemas. El primero de los circuitos utiliza el conjunto potencia del conjunto de reglas de aplicación así como el concepto de máxima aplicabilidad para favorecer el intra-paralelismo y el segundo incluye, además, el concepto de dominio de aplicabilidad para determinar el conjunto de reglas que son aplicables en cada momento con los recursos existentes. Ambos procesadores se diseñan y se prueban mediante herramientas de diseño electrónico y se preparan para ser sintetizados sobre FPGAs. ABSTRACT Membrane computing appears as an alternative to traditional computing. P Systems are placed inside this field and they are based upon the existence of regions called “membranes” that contain resources and rules that describe how the resources may vary to take each of these regions to a new situation called "configuration". Successive configurations conform computation. Inside this field, the Natural Computing Group of the Universidad Politécnica of Madrid develops a large number of works and researches that provide a lot of papers and some doctoral theses. Main research lines have been, by the moment, the study of the theoretical model over which Transition P Systems are defined, the study of the algorithms that are used for the evolution rules application in the regions, the design of new architectures that may improve communication among the different membranes (regions) that compose the whole system and the implementation of such systems over hardware devices that may define machines based upon this new model. Within this last research field, this is, within the objective of finally building machines that may accomplish the functionality of computation with P Systems, the present thesis is centered on the design of two parallel processors that, applying several variants of some known algorithms, improve the level of the internal parallelism at the evolution rule application phase. Design and creation of both processors present innovations to the field of Transition P Systems research because they use concepts that, even being known before, were never used for circuits that implement the applying phase of evolution rules. So, both processors present the following characteristics: - They present a very high performance during the application rule phase, keeping, on the other hand, a level of flexibility and scalability that, even known it is not very high, it seems to be acceptable. - They present a very high level of internal parallelism inside the regions, allowing several rule to be applied at the same time. - They present a universal character meaning this that they are not dependent upon the active rules that compose the P System. - They have a non-deterministic behavior that is inherent to this systems nature. The first processor uses the concept of "power set of the application rule set" and the concept of "maximal application" number to improve parallelism, and the second one includes, besides the previous ones, the concept of "applicability domain" to determine the set of rules that may be applied in each moment with the existing resources.. Both processors are designed and tested with the design software by Altera Corporation and they are ready to be synthetized over FPGAs.

Computational Methods for Studies of Quantum Dots and Boson Condensates

This thesis presents ab initio studies of two kinds of physical systems, quantum dots and bosons, using two program packages of which the bosonic one has mainly been developed by the author. The implemented models, \emph{i.e.}, configuration interaction (CI) and coupled cluster (CC) take the correlated motion of the particles into account, and provide a hierarchy of computational schemes, on top of which the exact solution, within the limit of the single-particle basis set, is obtained. The theory underlying the models is presented in some detail, in order to provide insight into the approximations made and the circumstances under which they hold. Some of the computational methods are also highlighted. In the final sections the results are summarized. The CI and CC calculations on multiexciton complexes in self-assembled semiconductor quantum dots are presented and compared, along with radiative and non-radiative transition rates. Full CI calculations on quantum rings and double quantum rings are also presented. In the latter case, experimental and theoretical results from the literature are re-examined and an alternative explanation for the reported photoluminescence spectra is found. The boson program is first applied on a fictitious model system consisting of bosonic electrons in a central Coulomb field for which CI at the singles and doubles level is found to account for almost all of the correlation energy. Finally, the boson program is employed to study Bose-Einstein condensates confined in different anisotropic trap potentials. The effects of the anisotropy on the relative correlation energy is examined, as well as the effect of varying the interaction potential.}

Strong electronic correlation in the hydrogen chain: A variational Monte Carlo study

<p>In this paper, we report a fully ab initio variational Monte Carlo study of the linear and periodic chain of hydrogen atoms, a prototype system providing the simplest example of strong electronic correlation in low dimensions. In particular, we prove that numerical accuracy comparable to that of benchmark density-matrix renormalization-group calculations can be achieved by using a highly correlated Jastrow-antisymmetrized geminal power variational wave function. Furthermore, by using the so-called "modern theory of polarization" and by studying the spin-spin and dimer-dimer correlations functions, we have characterized in detail the crossover between the weakly and strongly correlated regimes of this atomic chain. Our results show that variational Monte Carlo provides an accurate and flexible alternative to highly correlated methods of quantum chemistry which, at variance with these methods, can be also applied to a strongly correlated solid in low dimensions close to a crossover or a phase transition.p>

When Casimir meets Kibble-Zurek

<p>Verification of the dynamical Casimir effect (DCE) in optical systems is still elusive due to the very demanding requirements for its experimental implementation. This typically requires very fast changes in the boundary conditions of the problem. We show that an ensemble of two-level atoms collectively coupled to the electromagnetic field of a cavity, driven at low frequencies and close to a quantum phase transition, stimulates the production of photons from the vacuum. This paves the way for an effective simulation of the DCE through a mechanism that has recently found experimental demonstration. The spectral properties of the emitted radiation reflect the critical nature of the system and allow us to link the detection of DCE to the Kibble-Zurek mechanism for the production of defects when crossing a continuous phase transition.p>

Metastable Phase Diagram of Nanocrystalline ZrO(2)-Sc(2)O(3) Solid Solutions

We have investigated the crystal structures and phase transitions of nanocrystalline ZrO(2)-1 to -13 mol % Sc(2)O(3) by synchrotron X-ray powder diffraction and Raman spectroscopy. ZrO(2)-Sc(2)O(3) nanopowders were synthesized by using a stoichiometric nitrate-lysine get-combustion route. Calcination processes at 650 and at 850 degrees C yielded nanocrystalline materials with average crystallite sizes of (10 +/- 1) and (25 +/- 2) nm, respectively. Only metastable tetragonal forms and the cubic phase were identified, whereas the stable monoclinic and rhombohedral phases were not detected in the compositional range analyzed in this work. Differently from the results of investigations reported in the literature for ZrO(2)-Sc(2)O(3) materials with large crystallite sizes, this study demonstrates that, if the crystallite sizes are small enough (in the nanometric range), the metastable t ``-form of the tetragonal phase is retained. We have also determined the t`-t `` and t ``-cubic compositional boundaries at room temperature and analyzed these transitions at high temperature. Finally, using these results, we built up a metastable phase diagram for nanocrystalline compositionally homogeneous ZrO(2)-Sc(2)O(3) solid solutions that strongly differs from that previously determined from compositionally homogeneous ZrO(2)-Sc(2)O(3), Solid solutions with much larger crystallite sizes.

Análisis estático de sistemas de membranas para la determinación de reglas activas

Esta tesis doctoral se enmarca dentro de la computación con membranas. Se trata de un tipo de computación bio-inspirado, concretamente basado en las células de los organismos vivos, en las que se producen múltiples reacciones de forma simultánea. A partir de la estructura y funcionamiento de las células se han definido diferentes modelos formales, denominados P sistemas. Estos modelos no tratan de modelar el comportamiento biológico de una célula, sino que abstraen sus principios básicos con objeto de encontrar nuevos paradigmas computacionales. Los P sistemas son modelos de computación no deterministas y masivamente paralelos. De ahí el interés que en los últimos años estos modelos han suscitado para la resolución de problemas complejos. En muchos casos, consiguen resolver de forma teórica problemas NP-completos en tiempo polinómico o lineal. Por otra parte, cabe destacar también la aplicación que la computación con membranas ha tenido en la investigación de otros muchos campos, sobre todo relacionados con la biología. Actualmente, una gran cantidad de estos modelos de computación han sido estudiados desde el punto de vista teórico. Sin embargo, el modo en que pueden ser implementados es un reto de investigación todavía abierto. Existen varias líneas en este sentido, basadas en arquitecturas distribuidas o en hardware dedicado, que pretenden acercarse en lo posible a su carácter no determinista y masivamente paralelo, dentro de un contexto de viabilidad y eficiencia. En esta tesis doctoral se propone la realización de un análisis estático del P sistema, como vía para optimizar la ejecución del mismo en estas plataformas. Se pretende que la información recogida en tiempo de análisis sirva para configurar adecuadamente la plataforma donde se vaya a ejecutar posteriormente el P sistema, obteniendo como consecuencia una mejora en el rendimiento. Concretamente, en esta tesis se han tomado como referencia los P sistemas de transiciones para llevar a cabo el estudio de dicho análisis estático. De manera un poco más específica, el análisis estático propuesto en esta tesis persigue que cada membrana sea capaz de determinar sus reglas activas de forma eficiente en cada paso de evolución, es decir, aquellas reglas que reúnen las condiciones adecuadas para poder ser aplicadas. En esta línea, se afronta el problema de los estados de utilidad de una membrana dada, que en tiempo de ejecución permitirán a la misma conocer en todo momento las membranas con las que puede comunicarse, cuestión que determina las reglas que pueden aplicarse en cada momento. Además, el análisis estático propuesto en esta tesis se basa en otra serie de características del P sistema como la estructura de membranas, antecedentes de las reglas, consecuentes de las reglas o prioridades. Una vez obtenida toda esta información en tiempo de análisis, se estructura en forma de árbol de decisión, con objeto de que en tiempo de ejecución la membrana obtenga las reglas activas de la forma más eficiente posible. Por otra parte, en esta tesis se lleva a cabo un recorrido por un número importante de arquitecturas hardware y software que diferentes autores han propuesto para implementar P sistemas. Fundamentalmente, arquitecturas distribuidas, hardware dedicado basado en tarjetas FPGA y plataformas basadas en microcontroladores PIC. El objetivo es proponer soluciones que permitan implantar en dichas arquitecturas los resultados obtenidos del análisis estático (estados de utilidad y árboles de decisión para reglas activas). En líneas generales, se obtienen conclusiones positivas, en el sentido de que dichas optimizaciones se integran adecuadamente en las arquitecturas sin penalizaciones significativas. Summary Membrane computing is the focus of this doctoral thesis. It can be considered a bio-inspired computing type. Specifically, it is based on living cells, in which many reactions take place simultaneously. From cell structure and operation, many different formal models have been defined, named P systems. These models do not try to model the biological behavior of the cell, but they abstract the basic principles of the cell in order to find out new computational paradigms. P systems are non-deterministic and massively parallel computational models. This is why, they have aroused interest when dealing with complex problems nowadays. In many cases, they manage to solve in theory NP problems in polynomial or lineal time. On the other hand, it is important to note that membrane computing has been successfully applied in many researching areas, specially related to biology. Nowadays, lots of these computing models have been sufficiently characterized from a theoretical point of view. However, the way in which they can be implemented is a research challenge, that it is still open nowadays. There are some lines in this way, based on distributed architectures or dedicated hardware. All of them are trying to approach to its non-deterministic and parallel character as much as possible, taking into account viability and efficiency. In this doctoral thesis it is proposed carrying out a static analysis of the P system in order to optimize its performance in a computing platform. The general idea is that after data are collected in analysis time, they are used for getting a suitable configuration of the computing platform in which P system is going to be performed. As a consequence, the system throughput will improve. Specifically, this thesis has made use of Transition P systems for carrying out the study in static analysis. In particular, the static analysis proposed in this doctoral thesis tries to achieve that every membrane can efficiently determine its active rules in every evolution step. These rules are the ones that can be applied depending on the system configuration at each computational step. In this line, we are going to tackle the problem of the usefulness states for a membrane. This state will allow this membrane to know the set of membranes with which communication is possible at any time. This is a very important issue in determining the set of rules that can be applied. Moreover, static analysis in this thesis is carried out taking into account other properties such as membrane structure, rule antecedents, rule consequents and priorities among rules. After collecting all data in analysis time, they are arranged in a decision tree structure, enabling membranes to obtain the set of active rules as efficiently as possible in run-time system. On the other hand, in this doctoral thesis is going to carry out an overview of hardware and software architectures, proposed by different authors in order to implement P systems, such as distributed architectures, dedicated hardware based on PFGA, and computing platforms based on PIC microcontrollers. The aim of this overview is to propose solutions for implementing the results of the static analysis, that is, usefulness states and decision trees for active rules. In general, conclusions are satisfactory, because these optimizations can be properly integrated in most of the architectures without significant penalties.

Simulating accepting networks of evolutionary processors with filtered connections by accepting evolutionary P systems

In this work, we propose a variant of P system based on the rewriting of string-objects by means of evolutionary rules. The membrane structure of such a P system seems to be a very natural tool for simulating the filters in accepting networks of evolutionary processors with filtered connections. We discuss an informal construction supporting this simulation. A detailed proof is to be considered in an extended version of this work.

A green fluorescent protein-reporter mammalian two-hybrid system with extrachromosomal maintenance of a prey expression plasmid: Application to interaction screening

An improved mammalian two-hybrid system designed for interaction trap screening is described in this paper. CV-1/EBNA-1 monkey kidney epithelial cells expressing Epstein–Barr virus nuclear antigen 1 (EBNA-1) were stably transfected with a reporter plasmid for GAL4-dependent expression of the green fluorescent protein (GFP). A resulting clone, GB133, expressed GFP strongly when transfected transiently with transcriptional activators fused to GAL4 DNA-binding domain with minimal background GFP expression. GB133 cells maintained plasmids containing the OriP Epstein–Barr virus replication origin that directs replication of plasmids in mammalian cells in the presence of the EBNA-1 protein. GB133 cells transfected stably with a model bait expressed GFP when further transfected transiently with an expression plasmid for a known positive prey. When the bait-expressing GB133 cells were transfected transiently with an OriP-containing expression plasmid for the positive prey together with excess amounts of empty vector, cells that received the positive prey were readily identified by green fluorescence in cell culture and eventually formed green fluorescent microcolonies, because the prey plasmid was maintained by the EBNA-1/Ori-P system. The green fluorescent microcolonies were harvested directly from the culture dishes under a fluorescence microscope, and total DNA was then prepared. Prey-encoding cDNA was recovered by PCR using primers annealing to the vector sequences flanking the insert-cloning site. This system should be useful in mammalian cells for efficient screening of cDNA libraries by two-hybrid interaction.

Researching Framework for Simulating/Implementating P Systems

Researching simulation/implementation of membranes systems is very recent. Present literature gathers new publications frequently about software/hardware, data structures and algorithms for implementing P system evolution. In this context, this work presents a framework which goal is to make tasks of researchers of this field easier. Hence, it establishes the set of cooperating classes that form a reusable and flexible design for the customizable evaluation with new data structures and algorithms. Moreover, it includes customizable services for correcting, monitoring and logging the evolution and edition, recovering, automatic generating, persistence and visualizing P systems.

Analysis of P-Systems under a Multiagent Systems Perspective

Membrane computing is a recent area that belongs to natural computing. This field works on computational models based on nature's behavior to process the information. Recently, numerous models have been developed and implemented with this purpose. P-systems are the structures which have been defined, developed and implemented to simulate the behavior and the evolution of membrane systems which we find in nature. What we show in this paper is an application capable to simulate the P-systems based on a multiagent systems (MAS) technology. The main goal we want to achieve is to take advantage of the inner qualities of the multiagent systems. This way we can analyse the proper functioning of any given p-system. When we observe a P-system from a different perspective, we can be assured that it is a particular case of the multiagent systems. This opens a new possibility, in the future, to always evaluate the P-systems in terms of the multiagent systems technology.

Disorder driven transitions in non-equilibrium quantum systems

<p>This thesis presents studies of the role of disorder in non-equilibrium quantum systems. The quantum states relevant to dynamics in these systems are very different from the ground state of the Hamiltonian. Two distinct systems are studied, (i) periodically driven Hamiltonians in two dimensions, and (ii) electrons in a one-dimensional lattice with power-law decaying hopping amplitudes. In the first system, the novel phases that are induced from the interplay of periodic driving, topology and disorder are studied. In the second system, the Anderson transition in all the eigenstates of the Hamiltonian are studied, as a function of the power-law exponent of the hopping amplitude. p> <p>In periodically driven systems the study focuses on the effect of disorder in the nature of the topology of the steady states. First, we investigate the robustness to disorder of Floquet topological insulators (FTIs) occurring in semiconductor quantum wells. Such FTIs are generated by resonantly driving a transition between the valence and conduction band. We show that when disorder is added, the topological nature of such FTIs persists as long as there is a gap at the resonant quasienergy. For strong enough disorder, this gap closes and all the states become localized as the system undergoes a transition to a trivial insulator. p> <p>Interestingly, the effects of disorder are not necessarily adverse, disorder can also induce a transition from a trivial to a topological system, thereby establishing a Floquet Topological Anderson Insulator (FTAI). Such a state would be a dynamical realization of the topological Anderson insulator. We identify the conditions on the driving field necessary for observing such a transition. We realize such a disorder induced topological Floquet spectrum in the driven honeycomb lattice and quantum well models.p> <p>Finally, we show that two-dimensional periodically driven quantum systems with spatial disorder admit a unique topological phase, which we call the anomalous Floquet-Anderson insulator (AFAI). The AFAI is characterized by a quasienergy spectrum featuring chiral edge modes coexisting with a fully localized bulk. Such a spectrum is impossible for a time-independent, local Hamiltonian. These unique characteristics of the AFAI give rise to a new topologically protected nonequilibrium transport phenomenon: quantized, yet nonadiabatic, charge pumping. We identify the topological invariants that distinguish the AFAI from a trivial, fully localized phase, and show that the two phases are separated by a phase transition.p> <p>The thesis also present the study of disordered systems using Wegner's Flow equations. The Flow Equation Method was proposed as a technique for studying excited states in an interacting system in one dimension. We apply this method to a one-dimensional tight binding problem with power-law decaying hoppings. This model presents a transition as a function of the exponent of the decay. It is shown that the the entire phase diagram, i.e. the delocalized, critical and localized phases in these systems can be studied using this technique. Based on this technique, we develop a strong-bond renormalization group that procedure where we solve the Flow Equations iteratively. This renormalization group approach provides a new framework to study the transition in this system.p>

Development priority zoning (DPZ)-led scenario simulation for regional land use change : the case of Suichang County, China

China has experienced an extraordinary level of economic development since the 1990s, following excessive competition between different regions. This has resulted in many resource and environmental problems. Land resources, for example, are either abused or wasted in many regions. The strategy of development priority zoning (DPZ), proposed by the Chinese National 11th Five-Year Plan, provides an opportunity to solve these problems by coordinating regional development and protection. In line with the rational utilization of land, it is proposed that the DPZ strategy should be integrated with regional land use policy. As there has been little research to date on this issue, this paper introduces a system dynamic (SD) model for assessing land use change in China led by the DPZ strategy. Land use is characterized by the prioritization of land development, land utilization, land harness and land protection (D-U-H-P). By using the Delphi method, a corresponding suitable prioritization of D-U-H-P for the four types of DPZ, including optimized development zones (ODZ), key development zones (KDZ), restricted development zones (RDZ), and forbidden development zones (FDZ) are identified. Suichang County is used as a case study in which to conduct the simulation of land use change under the RDZ strategy. The findings enable a conceptualization to be made of DPZ-led land use change and the identification of further implications for land use planning generally. The SD model also provides a potential tool for local government to combine DPZ strategy at the national level with land use planning at the local level.

Studies of new inorganic species using relativistic quantum chemistry

In the present work the methods of relativistic quantum chemistry have been applied to a number of small systems containing heavy elements, for which relativistic effects are important. First, a thorough introduction of the methods used is presented. This includes some of the general methods of computational chemistry and a special section dealing with how to include the effects of relativity in quantum chemical calculations. Second, after this introduction the results obtained are presented. Investigations on high-valent mercury compounds are presented and new ways to synthesise such compounds are proposed. The methods described were applied to certain systems containing short Pt-Tl contacts. It was possible to explain the interesting bonding situation in these compounds. One of the most common actinide compounds, uranium hexafluoride was investigated and a new picture of the bonding was presented. Furthermore the rareness of uranium-cyanide compounds was discussed. In a foray into the chemistry of gold, well known for its strong relativistic effects, investigations on different gold systems were performed. Analogies between Au$^+$ and platinum on one hand and oxygen on the other were found. New systems with multiple bonds to gold were proposed to experimentalists. One of the proposed systems was spectroscopically observed shortly afterwards. A very interesting molecule, which was theoretically predicted a few years ago is WAu$_{12}$. Some of its properties were calculated and the bonding situation was discussed. In a further study on gold compounds it was possible to explain the substitution pattern in bis[phosphane-gold(I)] thiocyanate complexes. This is of some help to experimentalists as the systems could not be crystallised and the structure was therefore unknown. Finally, computations on one of the heaviest elements in the periodic table were performed. Calculation on compounds containing element 110, darmstadtium, showed that it behaves similarly as its lighter homologue platinum. The extreme importance of relativistic effects for these systems was also shown.

The Chinese Television Industry

Television is a massive industry in China, yet fewer people are watching television screens. This ground-breaking study explores how television content is changing, how the Chinese government is responding to the challenges presented by digital media, and how businesses are brokering alliances in both traditional and new media sectors. Table of Contents Acknowledgments p. vi Introduction p. 1 1 Television in Transition p. 8 2 Nation Building p. 34 3 Soft Power p. 56 4 Formats p. 85 5 Channels and Content p. 111 6 Convergence p. 141 7 Rethinking Chinese Television Research p. 164 Bibliography p. 173 Index p. 184

Electron energy-loss spectroscopy study of polyatomic molecular systems under pyrolytic conditions

<p>The technique of variable-angle, electron energy-loss spectroscopy has been used to study the electronic spectroscopy of the diketene molecule. The experiment was performed using incident electron beam energies of 25 eV and 50 eV, and at scattering angles between 10° and 90°. The energy-loss region from 2 eV to 11 eV was examined. One spin-forbidden transition has been observed at 4.36 eV and three others that are spin-allowed have been located at 5.89 eV, 6.88 eV and 7.84 eV. Based on the intensity variation of these transitions with impact energy and scattering angle, and through analogy with simpler molecules, the first three transitions are tentatively assigned to an n → π* transition, a π - σ* (3s) Rydberg transition and a π → π* transition.p> <p>Thermal decomposition of chlorodifluoromethane, chloroform, dichloromethane and chloromethane under flash-vacuum pyrolysis conditions (900-1100°C) was investigated by the technique of electron energy-loss spectroscopy, using the impact energy of 50 eV and a scattering angle of 10°. The pyrolytic reaction follows a hydrogen-chloride α-elimination pathway. The difluoromethylene radical was produced from chlorodifluoromethane pyrolysis at 900°C and identified by its X^1 A_1 → A^1B_1 band at 5.04 eV.p> <p>Finally, a number of exploratory studies have been performed. The thermal decomposition of diketene was studied under flash vacuum pressures (1-10 mTorr) and temperatures ranging from 500°C to 1000°C. The complete decomposition of the diketene molecule into two ketene molecules was achieved at 900°C. The pyrolysis of trifluoromethyl iodide molecule at 1000°C produced an electron energy-loss spectrum with several iodine-atom, sharp peaks and only a small shoulder at 8.37 eV as a possible trifluoromethyl radical feature. The electron energy-loss spectrum of trichlorobromomethane at 900°C mainly showed features from bromine atom, chlorine molecule and tetrachloroethylene. Hexachloroacetone decomposed partially at 900°C, but showed well-defined features from chlorine, carbon monoxide and tetrachloroethylene molecules. Bromodichloromethane molecule was investigated at 1000°C and produced a congested, electron energy-loss spectrum with bromine-atom, hydrogen-bromide, hydrogen-chloride and tetrachloroethylene features.p>