Ydinvoiman säädettävyys laajamittaisesti sähköä varastoivassa energiajärjestelmässä

Tulevaisuudessa tuuli- ja aurinkovoiman osuus sähköntuotannosta tulee kasvamaan. Näiden uusiutuvien energiamuotojen tuotanto kuitenkin vaihtelee sääolosuhteiden mukaan. Tästä johtuen tarvitaan lisää säätövoimaa, jotta voidaan vastata sähkönkulutukseen tuuli- ja aurinkosähkön tuotannon laskiessa. Tässä työssä tarkastellaan mahdollisuutta toteuttaa sähkönkulutuksen ja tuotannon tasapainottaminen Suomessa sähkön varastoinnin avulla sekä ydinvoiman soveltuvuutta säätövoimaksi ja ydinsähkön varastoinnin kannattavuutta. Työssä vertaillaan mahdollisuuksia sähkön varastointiteknologioiksi, joista valitaan potentiaalisimmat vaihtoehdot kustannus- ja soveltuvuustarkasteluun. Varastointikapasiteetin tarvetta tarkastellaan Suomen nykyisen sähkönkulutuksen ja -tuotannon mukaan sekä tilanteessa, jossa tuuli- ja aurinkovoiman osuus on molemmilla 15 % kokonaistuotantokapasiteetista. Vanhempien sekä nykyaikaisten ydinvoimaloiden soveltuvuutta säätövoimaksi tarkastellaan laitosten säädettävyyden perusteella. Ydinvoimalaa on kuitenkin kannattavinta käyttää mahdollisimman suurella käyttökertoimella, joten tarkastelussa on myös mahdollisuus varastoida sähköä tilanteissa, joissa tuotantoa jouduttaisiin rajoittamaan. Varastointiteknologioiden ja eri skenaarioissa vaadittujen varastointikapasiteettien perusteella voidaan todeta, ettei sähkönkulutuksen ja -tuotannon tasapainottaminen sähkön varastoinnilla ole kannattavaa nykyisillä varastointikustannuksilla ja sähkön hinnoilla. Ydinvoiman voidaan todeta soveltuvan hyvin säätövoimaksi ominaisuuksien puolesta, mutta taloudellisesti se ei ole paras vaihtoehto. Ydinvoimalla tuotetun sähkön varastointi ei ole tällä hetkellä Suomessa kannattavaa matalien sähkön hintojen ja korkeiden varastointikustannusten vuoksi. Sähkön varastoinnista on mahdollista tulla kannattavaa 2020-luvulla. Tämä edellyttää Yhdysvaltojen energiaministeriön asettaman strategian toteutumista, jonka tavoitteena on varastoimalla tuotetun sähkön kustannusten saaminen alle 75 €/MWh.

Conservação de sementes de taperebá (Spondias mombin L., Anacardiaceae)

Pós-graduação em Agronomia (Agricultura) - FCA

Processamento e análise de vídeos utilizando Floresta de Caminhos Ótimos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Processamento e análise de vídeos utilizando Floresta de Caminhos Ótimos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Studio del metodo dell'assorbimento diretto della CO2 per l'analisi del radiocarbonio

L’attuale rilevanza rappresentata dalla stretta relazione tra cambiamenti climatici e influenza antropogenica ha da tempo posto l’attenzione sull’effetto serra e sul surriscaldamento planetario così come sull’aumento delle concentrazioni atmosferiche dei gas climaticamente attivi, in primo luogo la CO2. Il radiocarbonio è attualmente il tracciante ambientale per eccellenza in grado di fornire mediante un approccio “top-down” un valido strumento di controllo per discriminare e quantificare il diossido di carbonio presente in atmosfera di provenienza fossile o biogenica. Ecco allora che ai settori applicativi tradizionali del 14C, quali le datazioni archeometriche, si affiancano nuovi ambiti legati da un lato al settore energetico per quanto riguarda le problematiche associate alle emissioni di impianti, ai combustibili, allo stoccaggio geologico della CO2, dall’altro al mercato in forte crescita dei cosiddetti prodotti biobased costituiti da materie prime rinnovabili. Nell’ambito del presente lavoro di tesi è stato quindi esplorato il mondo del radiocarbonio sia dal punto di vista strettamente tecnico e metodologico che dal punto di vista applicativo relativamente ai molteplici e diversificati campi d’indagine. E’ stato realizzato e validato un impianto di analisi basato sul metodo radiometrico mediante assorbimento diretto della CO2 ed analisi in scintillazione liquida apportando miglioramenti tecnologici ed accorgimenti procedurali volti a migliorare le performance del metodo in termini di semplicità, sensibilità e riproducibilità. Il metodo, pur rappresentando generalmente un buon compromesso rispetto alle metodologie tradizionalmente usate per l’analisi del 14C, risulta allo stato attuale ancora inadeguato a quei settori applicativi laddove è richiesta una precisione molto puntuale, ma competitivo per l’analisi di campioni moderni ad elevata concentrazione di 14C. La sperimentazione condotta su alcuni liquidi ionici, seppur preliminare e non conclusiva, apre infine nuove linee di ricerca sulla possibilità di utilizzare questa nuova classe di composti come mezzi per la cattura della CO2 e l’analisi del 14C in LSC.

Assessment of Hydrogen as suistinable clean energy

The progressive depletion of fossil fuels and their high contribution to the energy supply in this modern society forces that will be soon replaced by renewable fuels. But the dispersion and alternation of renewable energy production also undertake to reduce their costs to use as energy storage and hydrogen carrier. It is necessary to develop technologies for hydrogen production from all renewable energy storage technologies and the development of energy production from hydrogen fuel cells and cogeneration and tri generation systems. In order to propel this technological development discussed where the hydrogen plays a key role as energy storage and renewable energy, the National Centre of Hydrogen and Fuel Cell Technology Experimentation in Spain equipped with installations that enable scientific and technological design, develop, verify, certify, approve, test, measure and, more importantly, the facility ensures continuous operation for 24 hours a day, 365 days year. At the same time, the system is scalable so as to allow continuous adaptation of new technologies are developed and incorporated into the assembly to verify integration at the same time it checks the validity of their development. The transformation sector can be said to be the heart of the system, because without neglecting the other sectors, this should prove the validity of hydrogen as a carrier - energy storage are important efforts that have to do to demonstrate the suitability of fuel cells or internal combustion systems to realize the energy stored in hydrogen at prices competitive with conventional systems. The multiple roles to meet the fuel cells under different conditions of operation require to cover their operating conditions, many different sizes and applications. The fourth area focuses on integration is an essential complement within the installation. We must integrate not only the electricity produced, but also hydrogen is used and the heat generated in the process of using hydrogen energy. The energy management in its three forms: hydrogen chemical, electrical and thermal integration requires complicated and require a logic and artificial intelligence extremes to ensure maximum energy efficiency at the same time optimum utilization is achieved. Verification of the development and approval in the entire production system and, ultimately, as a demonstrator set to facilitate the simultaneous evolution of production technology, storage and distribution of hydrogen fuel cells has been assessed.

Estudio de la viabilidad económica de la tecnología de captura y almacenamiento de Co2

El informe más reciente del Grupo Intergubernamental de Expertos sobre el Cambio Climático (IPCC) define que las emisiones globales de CO2 deben ser recortados en un 50-80 % para el año 2050 con el fin de evitar los efectos más dañinos del cambio climático. El mundo depende actualmente de los combustibles fósiles para satisfacer el 80% de sus necesidades energéticas. La demanda de energía va en aumento y no se puede satisfacer a medio plazo únicamente por las energías renovables. Para hacer frente a los retos de esta creciente demanda de energía y la necesidad de reducir rápidamente emisiones de CO2, se necesita, entre otros, el uso de tecnologías de captura y almacenamiento de CO2. En el presente trabajo se analiza técnicamente esta tecnología y se comparan los costos de la misma según los estudios más importantes que actualmente están publicados. ABSTRACT The most recent report from the Intergovernmental Panel on Climate Change (IPCC) concluded that global CO2 emissions need to be cut by 50-80% by 2050 in order to avoid the most damaging effects of climate change. The world currently relies on fossil fuels to meet 80% of its energy needs. The demand for energy is increasing and cannot be met in the medium term solely by renewables. To address the challenges of this rising demand for energy and the need to rapidly reduce CO2 emissions, is needed, among others, the CO2 capture and storage technologies. In this paper, this technology is technically analyzed and compared the costs thereof as the most important studies that are currently published.

Optimização de um sistema híbrido off-grid PV, Gerador Diesel e Baterias

Tese de mestrado integrado, Engenharia da Energia e do Ambiente, Universidade de Lisboa, Faculdade de Ciências, 2016

Analysis of Lead-Acid batteries with a third-order dynamical model

Electrical energy storage is a really important issue nowadays. As electricity is not easy to be directly stored, it can be stored in other forms and converted back to electricity when needed. As a consequence, storage technologies for electricity can be classified by the form of storage, and in particular we focus on electrochemical energy storage systems, better known as electrochemical batteries. Largely the more widespread batteries are the Lead-Acid ones, in the two main types known as flooded and valve-regulated. Batteries need to be present in many important applications such as in renewable energy systems and in motor vehicles. Consequently, in order to simulate these complex electrical systems, reliable battery models are needed. Although there exist some models developed by experts of chemistry, they are too complex and not expressed in terms of electrical networks. Thus, they are not convenient for a practical use by electrical engineers, who need to interface these models with other electrical systems models, usually described by means of electrical circuits. There are many techniques available in literature by which a battery can be modeled. Starting from the Thevenin based electrical model, it can be adapted to be more reliable for Lead-Acid battery type, with the addition of a parasitic reaction branch and a parallel network. The third-order formulation of this model can be chosen, being a trustworthy general-purpose model, characterized by a good ratio between accuracy and complexity. Considering the equivalent circuit network, all the useful equations describing the battery model are discussed, and then implemented one by one in Matlab/Simulink. The model has been finally validated, and then used to simulate the battery behaviour in different typical conditions.

Next generation high density three-dimensional magnetic recording systems

This work is the first work using patterned soft underlayers in multilevel three-dimensional vertical magnetic data storage systems. The motivation stems from an exponentially growing information stockpile, and a corresponding need for more efficient storage devices with higher density. The world information stockpile currently exceeds 150EB (ExaByte=1x1018Bytes); most of which is in analog form. Among the storage technologies (semiconductor, optical and magnetic), magnetic hard disk drives are posed to occupy a big role in personal, network as well as corporate storage. However; this mode suffers from a limit known as the Superparamagnetic limit; which limits achievable areal density due to fundamental quantum mechanical stability requirements. There are many viable techniques considered to defer superparamagnetism into the 100's of Gbit/in2 such as: patterned media, Heat-Assisted Magnetic Recording (HAMR), Self Organized Magnetic Arrays (SOMA), antiferromagnetically coupled structures (AFC), and perpendicular magnetic recording. Nonetheless, these techniques utilize a single magnetic layer; and can thusly be viewed as two-dimensional in nature. In this work a novel three-dimensional vertical magnetic recording approach is proposed. This approach utilizes the entire thickness of a magnetic multilayer structure to store information; with potential areal density well into the Tbit/in2 regime. ^ There are several possible implementations for 3D magnetic recording; each presenting its own set of requirements, merits and challenges. The issues and considerations pertaining to the development of such systems will be examined, and analyzed using empirical and numerical analysis techniques. Two novel key approaches are proposed and developed: (1) Patterned soft underlayer (SUL) which allows for enhanced recording of thicker media, (2) A combinatorial approach for 3D media development that facilitates concurrent investigation of various film parameters on a predefined performance metric. A case study is presented using combinatorial overcoats of Tantalum and Zirconium Oxides for corrosion protection in magnetic media. ^ Feasibility of 3D recording is demonstrated, and an emphasis on 3D media development is emphasized as a key prerequisite. Patterned SUL shows significant enhancement over conventional "un-patterned" SUL, and shows that geometry can be used as a design tool to achieve favorable field distribution where magnetic storage and magnetic phenomena are involved. ^

Coupled diusion and mechanics in battery electrodes

Thesis (Ph.D.)--University of Washington, 2016-08

Experimental characterization of hydrogen containing flames

The current environmental and socio-economic situation promotes the development of carbon-neutral and sustainable solutions for energy supply. In this framework, the use of hydrogen has been largely indicated as a promising alternative. However, safety aspects are of concern for storage and transportation technologies. Indeed, the current know-how promotes its transportation via pipeline as compressed gas. However, the peculiar properties of hydrogen make the selection of suitable materials challenging. For these reasons, dilution with less reactive species has been considered a short and medium solution. As a way of example, methane-hydrogen mixtures are currently transported via pipelines. In this case, the hydrogen content is limited to 20% in volume, thus keeping the dependence on natural gas sources. On the contrary, hydrogen can be conveniently transported by mixing it with carbon dioxide deriving from carbon capture and storage technologies. In this sense, the interactions between hydrogen and carbon dioxide have been poorly studied. In particular, the effects of composition and operative conditions in the case of accidental release or for direct use in the energy supply chain are unknown. For these reasons, the present work was devoted to the characterization of the chemical phenomena ruling the system. To this aim, laminar flames containing hydrogen and carbon dioxide in the air were investigated experimentally and numerically. Different detailed kinetic mechanisms largely validated were considered at this stage. Significant discrepancies were observed among numerical and experimental data, especially once a fuel consisting of 40%v of hydrogen was studied. This deviation was attributed to the formation of a cellular flame increasing the overall reactivity. Hence, this observation suggests the need for combined models accounting for peculiar physical phenomena and detailed kinetic mechanisms characterizing the hydrogen-containing flames.

Systematic Approach for the selection of monitoring technologies in CO2 geological storage projects. Application of multicriteria decision making

Geologic storage of carbon dioxide (CO2) has been proposed as a viable means for reducing anthropogenic CO2 emissions. Once injection begins, a program for measurement, monitoring, and verification (MMV) of CO2 distribution is required in order to: a) research key features, effects and processes needed for risk assessment; b) manage the injection process; c) delineate and identify leakage risk and surface escape; d) provide early warnings of failure near the reservoir; and f) verify storage for accounting and crediting. The selection of the methodology of monitoring (characterization of site and control and verification in the post-injection phase) is influenced by economic and technological variables. Multiple Criteria Decision Making (MCDM) refers to a methodology developed for making decisions in the presence of multiple criteria. MCDM as a discipline has only a relatively short history of 40 years, and it has been closely related to advancements on computer technology. Evaluation methods and multicriteria decisions include the selection of a set of feasible alternatives, the simultaneous optimization of several objective functions, and a decision-making process and evaluation procedures that must be rational and consistent. The application of a mathematical model of decision-making will help to find the best solution, establishing the mechanisms to facilitate the management of information generated by number of disciplines of knowledge. Those problems in which decision alternatives are finite are called Discrete Multicriteria Decision problems. Such problems are most common in reality and this case scenario will be applied in solving the problem of site selection for storing CO2. Discrete MCDM is used to assess and decide on issues that by nature or design support a finite number of alternative solutions. Recently, Multicriteria Decision Analysis has been applied to hierarchy policy incentives for CCS, to assess the role of CCS, and to select potential areas which could be suitable to store. For those reasons, MCDM have been considered in the monitoring phase of CO2 storage, in order to select suitable technologies which could be techno-economical viable. In this paper, we identify techniques of gas measurements in subsurface which are currently applying in the phase of characterization (pre-injection); MCDM will help decision-makers to hierarchy the most suitable technique which fit the purpose to monitor the specific physic-chemical parameter.

Integrating toxicity testing in the wastewater management of chemical storage terminals - A proposal based on a ten-year study

Wastewater control at storage terminals of liquid chemical products in bulk is very difficult because of the variety of products handled in the facilities generating effluents of variable composition. The main objective of this work was to verify if the Vibrio fischeri acute toxicity test could be routinely included in the wastewater management of those facilities along with physical and chemical analysis in order to evaluate and improve the quality of the generated effluents. The study was performed in two phases before and after the implementation of better operational practices/treatment technologies. Chemical oxygen demand (COD) and toxicity of treated effluents did not correlate showing that effluents with low COD contain toxic substances and non-biodegradable organic matter, which may be not degraded when discharged into the aquatic environment. Segregation of influents or pre-treatment based on toxicity results and biodegradability index were implemented in the facilities generating significant improvements in the quality of final effluents with reduction of Biochemical oxygen demand (BOD) and toxicity. The integration of physical and chemical analysis with the V.fischeri toxicity test turned out to be an excellent tool for wastewater management in chemical terminals allowing rapid decision making for pollution control and prevention measures. Reuse of rain water was also proposed and when implemented by the facilities resulted in economical and environmental benefits. (C) 2010 Elsevier B.V. All rights reserved.

Database technologies for l-system simulations in virtual plant applications on bioinformatics

One of the most important advantages of database systems is that the underlying mathematics is rich enough to specify very complex operations with a small number of statements in the database language. This research covers an aspect of biological informatics that is the marriage of information technology and biology, involving the study of real-world phenomena using virtual plants derived from L-systems simulation. L-systems were introduced by Aristid Lindenmayer as a mathematical model of multicellular organisms. Not much consideration has been given to the problem of persistent storage for these simulations. Current procedures for querying data generated by L-systems for scientific experiments, simulations and measurements are also inadequate. To address these problems the research in this paper presents a generic process for data-modeling tools (L-DBM) between L-systems and database systems. This paper shows how L-system productions can be generically and automatically represented in database schemas and how a database can be populated from the L-system strings. This paper further describes the idea of pre-computing recursive structures in the data into derived attributes using compiler generation. A method to allow a correspondence between biologists' terms and compiler-generated terms in a biologist computing environment is supplied. Once the L-DBM gets any specific L-systems productions and its declarations, it can generate the specific schema for both simple correspondence terminology and also complex recursive structure data attributes and relationships.