Seawater Cd reconstruction for the western subtropical South Atlantic

Benthic foraminiferal Cd/Ca from an intermediate depth, western South Atlantic core documents the history of southward penetration of North Atlantic Intermediate Water (NAIW). Cd seawater estimates (CdW) for the last glacial are consistent with the production of NAIW and its export into the South Atlantic. At ~14.5 ka concurrently with the onset of the Bølling-Allerød to Younger Dryas cooling, the NAIW contribution to the South Atlantic began to decrease, marking the transition from a glacial circulation pattern to a Younger Dryas circulation. High CdW in both the deep North Atlantic and the intermediate South Atlantic imply reduced export of deep and intermediate water during the Younger Dryas and a significant decrease in northward oceanic heat transport. A modern circulation was achieved at ~9 ka, concurrently with the establishment of Holocene warmth in the North Atlantic region, further supporting a close linkage between deepwater variability and North Atlantic climate.

Down-core sedimentary Sr-Nd isotope records from two Cape Basin sediment cores in the South Atlantic: GeoB3603-2 (Meteor cruise M34/1) and MD02-2594 (Marion Dufresne cruise MD128)

We report down-core sedimentary Nd isotope (epsilon Nd) records from two South Atlantic sediment cores, MD02-2594 and GeoB3603-2, located on the western South African continental margin. The core sites are positioned downstream of the present-day flow path of North Atlantic Deep Water (NADW) and close to the Southern Ocean, which makes them suitable for reconstructing past variability in NADW circulation over the last glacial cycle. The Fe-Mn leachates epsilon Nd records show a coherent decreasing trend from glacial radiogenic values towards less radiogenic values during the Holocene. This trend is confirmed by epsilon Nd in fish debris and mixed planktonic foraminifera, albeit with an offset during the Holocene to lower values relative to the leachates, matching the present-day composition of NADW in the Cape Basin. We interpret the epsilon Nd changes as reflecting the glacial shoaling of Southern Ocean waters to shallower depths combined with the admixing of southward flowing Northern Component Water (NCW). A compilation of Atlantic epsilon Nd records reveals increasing radiogenic isotope signatures towards the south and with increasing depth. This signal is most prominent during the Last Glacial Maximum (LGM) and of similar amplitude across the Atlantic basin, suggesting continuous deep water production in the North Atlantic and export to the South Atlantic and the Southern Ocean. The amplitude of the epsilon Nd change from the LGM to Holocene is largest in the southernmost cores, implying a greater sensitivity to the deglacial strengthening of NADW at these sites. This signal impacted most prominently the South Atlantic deep and bottom water layers that were particularly deprived of NCW during the LGM. The epsilon Nd variations correlate with changes in 231Pa/230Th ratios and benthic d13C across the deglacial transition. Together with the contrasting 231Pa/230Th: epsilon Nd pattern of the North and South Atlantic, this indicates a progressive reorganization of the AMOC to full strength during the Holocene.

Stable isotope record of planktonic foraminifera of the South Atlantic

The central problem of late Quaternary circulation in the South Atlantic is its role in transfer of heat to the North Atlantic, as this modifies amplitude, and perhaps phase, of glacialinterglacial fluctuations. Here we attempt to define the problem and establish ways to attack it. We identify several crucial elements in the dynamics of heat export: (1) warm-water pile-up (and lack thereof) in the Western equatorial Atlantic, (2) general spin-up (or spin-down) of central gyre, tied to SE trades, (3) opening and closing of Cape Valve (Agulhas retroflection), (4) deepwater E-W asymmetry. Means for reconstruction are biogeography, stable isotopes, and productivity proxies. Main results concern overall glacial-interglacial contrast (less pile-up, more spin-up, Cape Valve closed, less NADW during glacial time), dominance of precessional signal in tropics, phase shifts in precessional response. To generate working hypotheses about the dynamics of surface water circulation in the South Atlantic we employ Croll's paradigm that glacial - interglacial fluctuations are analogous to seasonal fluctuations. Our general picture for the last 300 kyrs is that, as concerns the South Atlantic, intensity of surface water (heat) transport depends on the strength of the SE trades. From various lines of evidence it appears that strenger SE trades appeared during glacials and cold substages during interglacials, analogous to conditions in southern winter (August).

Megnetic susceptibility of a subtropical South Atlantic transect

The Mid-Pleistocene transition (MPT) of the global climate system, initiated by a shift towards much larger northern hemisphere ice shields at around 920 ka and ending with predominance of 100 kyr ice age cyclicity since about 640 ka, is one of the fundamental enigmas in Quaternary climate evolution. Climate proxy records not exclusively linked to global ice volume are necessary to advance understanding of the MPT. Here we present a high-resolution Pleistocene magnetic susceptibility time series of 12 sediment cores from the subtropical South Atlantic essentially reflecting dissolution driven variations in carbonate accumulation controlled by changes in deep water circulation. In addition to characteristics known from delta18O records, the data sets reveal three remarkable features intimately related to the MPT: (1) an all-Pleistocene minimum of carbonate accumulation in the South Atlantic at 920 ka, (2) a MPT interim state of reduced carbonate deposition, indicating that the MPT period may have been a discrete state of the Pleistocene deep water circulation and climate system and (3) a terminal MPT event at around 540-530 ka documented in several peculiarities such as thick laminated layers of the giant diatom Ethmodiscus rex.

Benthic foraminifera analysis of two sediments cores from the northern Cape Basin in the eastern South Atlantic Ocean

Two late Quaternary sediment cores from the northern Cape Basin in the eastern South Atlantic Ocean were analyzed for their benthic foraminiferal content and benthic stable carbon isotope composition. The locations of the cores were selected such that both of them presently are bathed by North Atlantic Deep Water (NADW) and past changes in deep water circulation should be recorded simultaneously at both locations. However, the areas are different in terms of primary production. One core was recovered from the nutrient-depleted Walvis Ridge area, whereas the other one is from the continental slope just below the coastal upwelling mixing area where present day organic matter fluxes are shown to be moderately high. Recent data served as the basis for the interpretation of the late Quaternary faunal fluctuations and the paleoceanographic reconstruction. During the last 450,000 years, NADW flux into the eastern South Atlantic Ocean has been restricted to interglacial periods, with the strongest dominance of a NADW-driven deep water circulation during interglacial stages 1, 9 and 11. At the continental margin, high productivity faunas and very low epibenthic d13C values indicate enhanced fluxes of organic matter during glacial periods. This can be attributed to a glacial increase and lateral extension of coastal upwelling. The long term glacial-interglacial paleoproductivity cycles are superimposed by high-frequency variations with a period of about 23,000 yr. Enhanced productivity in surface waters above the Walvis Ridge, far from the coast, is indicated during glacial stages 8, 10 and 12. During these periods, cold, nutrient-rich filaments from the mixing area were probably driven as far as to the southeastern flank of the Walvis Ridge.

Sea surface temperatures derived from alkenones from Late Quaternary sediments of the East Equatorial South Atlantic

Angola Basin and Walvis Ridge records of past sea surface temperatures (SST) derived from the alkenone Uk 37 index are used to reconstruct the surface circulation in the east equatorial South Atlantic for the last 200,000 years. Comparison of SST estimates from surface sediments between 5° and 20°S with modern SST data suggests that the alkenone temperatures represent annual mean values of the surface mixed layer. Alkenone-derived temperatures for the warm climatic maxima of the Holocene and the penultimate interglacial are 1 to 4°C higher than latest Holocene values. All records show glacial to interglacial differences of about 3.5°C in annual mean SST, which is about 1.5°C greater than the difference estimated by CLIMAP (1981) for the eastern Angola Basin. At the Walvis Ridge, significant SST variance is observed at all of the Earth's orbital periodicities. SST records from the Angola Basin vary predominantly at 23- and 100-kyr periodicities. For the precessional cycle, SST changes at the Walvis Ridge correspond to variations of boreal summer insolation over Africa and lead ice volume changes, suggesting that the east equatorial South Atlantic is sensitive to African monsoon intensity via trade-wind zonality. Angola Basin SST records lag those from the Walvis Ridge and the equatorial Atlantic by about 3 kyr. The comparison of Angola Basin and Walvis Ridge SST records implies that the Angola-Benguela Front (ABF) (currently at about 14-16°S) has remained fairly stationary between 12° and 20°S (the limits of our cores) during the last two glacial-interglacial cycles. The temperature contrast associated with the ABF exhibits a periodic 23-kyr variability which is coherent with changes in boreal summer insolation over Africa. These observations suggest that surface waters north of the present ABF have not directly responded to monsoon-modulated changes in the trade-wind vector, that the central field of zonally directed trades in the southern hemisphere was not shifted or extended northward by several degrees of latitude during glacials, and that a cyclonic gyre circulation has existed in the east equatorial South Atlantic over the last 200,000 years. This scenario contradicts former assumptions of glacial intensification of the Benguela Current into the eastern Angola Basin and increased coastal upwelling off Angola.

Sedimentology and planktonic foraminiferal dissolution during the latest Cretaceous in the South Atlantic

A high-resolution (10-20 kyr) record of variations in CaCO3 content and dissolution was established for latest Cretaceous (last 0.7 Myr) deep-sea sediments from the South Atlantic Ocean (DSDP Site 516 from the Rio Grande Rise, and sites 525 and 527 from the Walvis Ridge). The degree of fragmentation of planktonic foraminifera (DFP) was used as a measure of calcite dissolution. High negative correlations between DFP and other independent measures of carbonate dissolution (percentage of sand fraction, absolute abundance of planktonic foraminifera, and planktonic/benthic foraminiferal ratio) validate its use as a sensitive index of calcite dissolution in upper Maastrichtian deep-sea sediments. Very high DFP and a significant negative correlation between DFP and CaCO 3 content suggest that Site 516 was located below the foraminiferal lysocline during the entire interval studied. Such a shallow position of the lysocline (paleodepth of Site 516 was 1.2 km) may be explained by "upwelling" of corrosive deep waters along the southern margin of the Rio Grande Rise. Sites 525 and 527 were located above the foraminiferal lysocline; however, three short periods of enhanced dissolution were recognised at Site 525 (paleodepth 1 km) and one interval of strong dissolution was identified at Site 527 (paleodepth 2.7 km). The lack of correspondence between the dissolution regimes at sites from the Walvis Ridge suggests limited deep-water communication across this physiographic barrier. Two of the dissolution maxima recognised at Site 525 correspond to carbonate maxima at Site 527. Variations in "upwelling" intensity along the Walvis Ridge, resulting in fluctuations in primary productivity in this area, may be the proximal cause of both carbonate cycles at Site 527 and dissolution cycles at Site 525. We suggest that development of the bottom Ekman layer between a hypothetical westward geostrophic current and the topographical height of the Rio Grande Rise-Walvis Ridge system may be a plausible hydrodynamical explanation for the proposed "'upwelling" along the southern margin of this topographical structure.

Radionuclides measured in surface water samples from the South Atlantic

In the nutrient-rich Southern Ocean, Fe is a vital constituent controlling the growth of phytoplankton. Despite much effort, the origin and transport of Fe to the oceans are not well understood. In this study we address the issue with geochemical data and Nd isotopic compositions of suspended particle samples collected from 1997 to 1999 in the South Atlantic Sector of the Southern Ocean. Al, Th, and rare earth element (REE) concentrations as well as 143Nd/144Nd isotopic ratios in acetic acid-leached particle samples representing the lithogenic fraction delineate three major sources: (1) Patagonia and the Antarctic Peninsula provide material with eNd > -4 that is transported toward the east with the polar and subpolar front jets, (2) the south African shelf, although its influence is limited by the circumpolar circulation and wind direction, can account for material with eNd of -12 to -14 adjacent to South Africa, and (3) East Antarctica provides material with eNd of -10 to -15 to the eastern Weddell Sea and adjacent Antarctic Circumpolar Current. For this region we interpret the Nd isotopic evidence in combination with oceanographic/atmospheric constraints as evidence for supply of significant amounts of terrigenous detritus by icebergs.