Análise de praguicidas organofosforados em água por extração em fase sólida (SPE) utilizando discos C18 e cromatografia em fase gasosa: avaliação da contaminação do reservatório de Furnas (MG-Brasil)

Solid phase extraction (SPE) in C18 disks has been optimized and validated for extraction of 5 organophosphorus (OP) pesticides in water. Extraction has been followed by separation and detection by gas chromatography/flame photometry. Excellent linearity was obtained for all compounds (r greater than 0.99), with CVs between 1.0-6.9%, recoveries between 73-95% and quantification limits between 2.5-5.0 µg L-1. Samples from Furnas dam were analyzed monthly during one year and 10% showed OP pesticide residues.

AVALIAÇÃO DA BIOACUMULAÇÃO DE METAIS EM Cyprinus carpio PELA INTERAÇÃO COM SEDIMENTO E ÁGUA DE RESERVATÓRIO

Bioaccumulation of Ag, Al, Cd, Co, Cr, Cu, Fe, Mn, Ni, Pb and Zn was determined in the gills and liver of Cyprinus carpio and related to concentrations in the sediment and water of the Alagados Reservoir, Ponta Grossa/Paraná. Cd and Fe exceeded the legal limit for water. Fe was the most abundant metal in the reservoir's water and sediment. The metals in the sediment were below the level of probable adverse effects on biota. There were no significant differences between sampling sites for water and sediment. Liver and gills had higher concentrations of Al, Fe and Zn, with a significant increase in Al (P > 0.05) compared to the increase in weight and size of the specimens. Statistically, gills showed higher concentrations of Al, Cd, Co, Cr, Mn and Zn and liver higher concentrations of Cu and Fe. Co, Cu, Fe, Mn and Zn showed significant differences (P < 0.01) between the organs. The bioaccumulation factors (BAF) showed that the interaction of water with gills promotes greater accumulation of metals in this organ. Despite the low concentrations in the reservoir, bioaccumulation of metals in gills and liver of C. carpio occurs by its interaction with contaminated water and sediment, respectively.

Distribuição de Cr, Ni, Cu, Cd e Pb em frações húmicas de diferentes tamanhos moleculares extraídas de amostras de água e de sedimentos do reservatório de captação de água superficial Anhumas - Araraquara-SP

Estudou-se a distribuição de Cr, Ni, Cu, Cd e Pb em frações de substâncias húmicas (SH) de diferentes tamanhos moleculares. As SH foram extraídas de amostras de água (SHA) e de sedimentos de superfície (SHSS), interface/água (SHSI) e fundo (SHSF) coletados no reservatório de captação de água superficial Anhumas, localizado no município de Araraquara-SP. Para a extração das SH utilizaram-se os procedimentos recomendados pela Sociedade Internacional de Substâncias Húmicas. Após purificação por diálise, as SH foram fracionadas com base no tamanho molecular utilizando-se sistema de fracionamento seqüencial por ultrafiltração e fluxo tangencial. O fracionamento das amostras de SHA permitiu caracterizar uma distribuição de massa relativamente uniforme dentre as frações de diferentes tamanhos moleculares, com valores maiores nas frações F2 (20,8%) e F4 (23,8%). Exceto para os íons Pb(II) e Cu(II) os quais apresentaram concentrações relativamente mais altas nas frações F2 e F4, respectivamente, de maneira geral, crômio, níquel, cádmio e chumbo têm distribuições similares nas cinco frações com tamanhos moleculares maiores e médios (F1 a F5). Quanto às distribuições de massa nas diferentes frações de substâncias húmicas extraídas de amostras de sedimento de superfície (SHSS), sedimento interface/água (SHSI) e sedimento de fundo (SHSF), as três amostras apresentaram 42-48% das SH nas frações com maiores tamanhos moleculares (F1 e F2), 29-31% nas frações intermediárias (F3 e F4) e 13-20% nas frações com menores tamanhos moleculares (F5 e F6). De modo geral, caracterizaram-se para os íons metálicos, distribuições similares dentre as respectivas frações F1 a F6. Exceções para Pb(II) e Ni(II) em sedimento de superfície com concentrações relativamente menores nas frações F2 e F4, respectivamente.

Qualidade da água do Reservatório da Usina Hidrelétrica (UHE) de Peti, Minas Gerais

Este trabalho foi desenvolvido no Reservatório da Usina Hidrelétrica (UHE) de Peti, localizado nos Municípios de Barão de Cocais, Santa Bárbara e São Gonçalo do Rio Abaixo, em Minas Gerais, durante o período de setembro de 2004 a maio de 2005, visando avaliar a influência do uso do solo do entorno do reservatório na qualidade da água. Para isso, foram escolhidos cinco pontos no reservatório que representassem os diferentes usos e coberturas do solo e analisados os parâmetros físico-químicos: temperatura, oxigênio dissolvido, condutividade elétrica, pH, turbidez, cor, sólidos totais, sólidos totais fixos, sólidos totais voláteis e sólidos totais em suspensão, em três profundidades de cada ponto de coleta; o parâmetro transparência foi analisado em cada ponto. Os resultados de qualidade da água foram divididos em época de estiagem (setembro, outubro, abril e maio) e chuvosa (novembro, dezembro, janeiro, fevereiro e março) e, no geral, apresentaram variação sazonal. Na época chuvosa, parâmetros como sólidos, turbidez e cor aumentaram a concentração; foi observada também maior variação entre as profundidades na época de estiagem, e à medida que se adentrava no reservatório (montante para jusante) parâmetros como turbidez, cor e sólidos totais em suspensão diminuíam em função da sua própria dinâmica. Pelos parâmetros analisados, não foi possível detectar nitidamente a influência dos diferentes usos do solo na qualidade da água.

Análise comparativa entre simuladores de linha de fluxo e diferenças finitas para um reservatório de petróleo submetido a injeção de água

Water injection is the most widely used method for supplementary recovery in many oil fields due to various reasons, like the fact that water is an effective displacing agent of low viscosity oils, the water injection projects are relatively simple to establish and the water availability at a relatively low cost. For design of water injection projects is necessary to do reservoir studies in order to define the various parameters needed to increase the effectiveness of the method. For this kind of study can be used several mathematical models classified into two general categories: analytical or numerical. The present work aims to do a comparative analysis between the results presented by flow lines simulator and conventional finite differences simulator; both types of simulators are based on numerical methods designed to model light oil reservoirs subjected to water injection. Therefore, it was defined two reservoir models: the first one was a heterogeneous model whose petrophysical properties vary along the reservoir and the other one was created using average petrophysical properties obtained from the first model. Comparisons were done considering that the results of these two models were always in the same operational conditions. Then some rock and fluid parameters have been changed in both models and again the results were compared. From the factorial design, that was done to study the sensitivity analysis of reservoir parameters, a few cases were chosen to study the role of water injection rate and the vertical position of wells perforations in production forecast. It was observed that the results from the two simulators are quite similar in most of the cases; differences were found only in those cases where there was an increase in gas solubility ratio of the model. Thus, it was concluded that in flow simulation of reservoirs analogous of those now studied, mainly when the gas solubility ratio is low, the conventional finite differences simulator may be replaced by flow lines simulator the production forecast is compatible but the computational processing time is lower.

Controle inteligente de pressão para uma rede sem reservatório de abastecimento urbano de água

The sanitation companies from Brazil has a great challenge for the XXI century: seek to mitigate the rate of physical waste (water, chemicals and electricity) and financial waste caused by inefficient operating systems drinking water supply, considering that currently we already face, in some cases, the scarcity of water resources. The supply systems are increasingly complex as they seek to minimize waste and at the same time better serve the growing number of users. However, this technological change is to reduce the complexity of the challenges posed by the need to include users with higher quality and efficiency in services. A major challenge for companies of water supplies is to provide a good quality service contemplating reducing expenditure on electricity. In this situation we developed a research by a method that seeks to control the pressure of the distribution systems that do not have the tank in your setup and the water comes out of the well directly to the distribution system. The method of pressure control (intelligent control) uses fuzzy logic to eliminate the waste of electricity and the leaks from the production of pumps that inject directly into the distribution system, which causes waste of energy when the consumption of households is reduced causing the saturation of the distribution system. This study was conducted at Green Club II condominium, located in the city of Parnamirim, state of Rio Grande do Norte, in order to study the pressure behavior of the output of the pump that injects water directly into the distribution system. The study was only possible because of the need we had to find a solution to some leaks in the existing distribution system and the extensions of the respective condominium residences, which sparked interest in developing a job in order to carry out the experiments contained in this research

A influência da poluição difusa e do regime hidrológico peculiar do semiárido na qualidade da água de um reservatório tropical

In semiarid region of northeast Brazil, the majority of reservoirs used for public supply has suffered degradation of water quality affected by diffuse pollution from agricultural and livestock areas of the watershed and by hydrologic regime peculiar to the region, characterized by a rainy season with higher volumes stored in reservoirs and a dry season with a reduction in water level due to high evaporation and increase of eutrophication. The Dourado reservoir, located in Currais Novos city, semiarid region of Rio Grande do Norte state, is one example of a water supply reservoir that can have degradation of water quality and impracticability of their use, due to the high external input of nutrients from non-point sources of watershed during the rainy season and increasing of eutrophication due to decrease the stored volume during the dry period. This study aimed to investigate and quantify diffuse pollution and the hydrologic regime of semiarid region in order to establish standards regarding the water quality of Dourado reservoir. The study period was between the months of May 2011 to March 2012. The diffuse pollution was quantified in terms of watershed from the mass balance of phosphorus in the reservoir, as in relation to areas under different types of land use within the riparian zone of the reservoir from the assessment of soil chemical properties and losses of phosphorus in each area. The influence of hydrological regime on water quality of the reservoir was evaluated from the monthly monitoring of the morphometric, meteorological and limnological features throughout the study period. The results showed that the reservoir has received a high load of phosphorus coming from the drainage basin and presents itself as a system able to retain some of that load tributary, giving an upward trend of the eutrophication process. Diffuse pollution by nutrients from areas under different types of land use within the riparian zone of the reservoir was higher in areas under the influence of livestock, being this area considered a potential diffuse source of nutrients to the reservoir. Regarding the water regime during the rainy season the reservoir was characterized by high concentrations of nutrients and small algal biomass, while in the dry season the reduction of volume and increase of the water retention time of the reservoir, contributing to the excessive growth algal biomass, favoring an increase in eutrophication and deterioration of water quality. In synthesis the water quality of Dourado reservoir is directed by diffuse pollution coming from the drainage basin and the hydrological regime of the peculiar semiarid region, where the rainy season is characterized by high input of allochthonous compounds from the tributaries and erosion of the soil in the reservoir riparian zone, and the dry season characterized by reducing the storage volume due to high evaporation, high residence time of water and consequent degradation of water quality due to the increase of eutrophication process

Análise do uso e ocupação do solo das margens de um reservatório e a sua influência na qualidade da água

The building of water reservoirs has become a solution for water scarcity of the semiarid regions, however, the land use and occupation near the margins of the reservoirs have been causing serious damage to water quality, harming their use. This paper aims to analyze the land use and occupation in the margins of the Northeast reservoir and evaluate their influence on the water quality, to identify the areas and activities that represent an higher risk of contamination to the reservoir. The study was conducted at the reservoir Dourado, located in the city of Currais Novos - RN, during the period from August 2012 to February 2013. Were defined six areas regarding the land use and occupation, then, Water samples were collected from the margins in these areas for the characterization of water quality. The results showed that almost all Permanent Preservation Areas (PPA) from the reservoir is degraded, increasing the susceptibility of large input of nutrients and contaminants loads. The water reservoir showed low quality, being with strong evidence of eutrophication due to the nutrient accumulation arising from the activities surrounding the reservoir, mainly from agriculture and Livestock. The Areas 1 and 2 are the areas that present a greater risk of reservoir degradation, because are the possible major sources of nutrients (phosphorus total, orthophosphate and nitrate), however, due to the small size of the reservoir, any compound that reaches its margins ultimately affects the water quality of the same

Influência do uso e ocupação de solo na qualidade de água de um reservatório mesotrófico na região semiárida tropiocal

In the semiarid region of northeastern of Brazil, the reservoirs are vulnerable to water level seasonal fluctuations, they re related to the hydrological cycle. The rain periods are irregular and there are long periods of drought that increases eutrophication process. That happens because of the water level s reduction and nutrient concentration. The Boqueirao, located in northeastern Brazil , is a mesotrophic reservoir. The reservoir is naturally susceptible to deterioration of water quality. This happens because of the potential diffuse sources arising from the use and occupation of the basin, associated with shallow soil caatinga biome and highly vulnerable to erosion. This study aimed to analyze the influence of the use and occupation of the area around and the water quality of the watershed. A study of the area around the Boqueirão was performed, taking the potentially polluting activities. Limnological variables were monitored monthly in 3 points of the reservoir to assess the water quality. Was evidenced an event of prolonged drought, with rainfall below the historical average for the year of study. By the index of water quality, the watershed was classified as " good " during the whole year of 2012. According to the trophic index adopted the reservoir is characterized as mesotrophic. The main anthropogenic impacts identified in the soil were arboreal selective logging, mining, diffuse contribution of residues from agricultural and livestock activities. The lack of precipitation and the degradation of the surrounding area, affect negatively the water quality, requiring immediate control to prevent degradation of the watershed . Although there wasn t a majority polluting activity in the region. The total of several impacting activities, the high susceptibility of the soil and the selective clearing of caatinga vegetation can accelerate the natural process of eutrophication in the water body

Caracterização espectral da água do reservatório de Itupararanga, SP, a partir de imagens hiperespectrais hyperion e análise derivativa

The current accessibility to hyperspectral images of Hyperion/EO1 orbital sensor has brought new perspectives for studies of aquatic environments for allowing the remote estimative of several optically active constituents (OACs) in water body. The changes in the composition and concentration of OACs cause different patterns of absorption and scattering of electromagnetic radiation, likely to be detected using hyperspectral data. Therefore, an investigation was conducted taking into account the spectral characterization of water of a reservoir intended for public supply (Itupararanga Reservoir), from Hyperion/EO1 images and derivative analysis technique applied to spectral curves generated. Simultaneously to the acquisition of a Hyperion/EO1 image, a field campaign was carried out to collect limnological data in situ in georeferenced points. After radiometric correction of the image, reflectance curves of pixels were extracted for each station and the curves obtained were subjected to the technique of derivative analysis, which revealed features of absorption and scattering mainly associated to the presence of algal pigments. The results obtained show the presence of phytoplankton and algal activity, matching the field observation.

Sustentabilidade ambiental e qualidade da água do reservatório Itans (Caicó-RN)

This study aimed to assess the sustainability of the Caicó-RN through the application of the Barometer of Sustainability. Scales of performance were made and the results were processed and placed in the scale of that tool, varying from 0 to 100. The results indicate that Caicó has a potentially untenable position in accordance with the Barometer of Sustainability

Distribuição de Cr, Ni, Cu, Cd e Pb em frações húmicas de diferentes tamanhos moleculares extraídas de amostras de água e de sedimentos do reservatório de captação de água superficial Anhumas - Araraquara-SP

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Índice de Qualidade da Água (IQA) do reservatório Tanque Grande, Guarulhos (SP): Análise sazonal e efeitos do uso e ocupação do solo

The Tanque Grande Reservoir is located at the Serra da Cantereira, Guarulhos (SP), and provides 3% of the municipal drinking water. In the last years, the urban zone has expanded towards the reservoir and has significantly altered the land use. In this work, water samples from three stations were monitored from August/2007 up to July/2008 in terms of the Water Quality Index (IQA) adopted by CETESB. The waters were usually classified in the band Good during the study period. Nevertheless, termotolerants coliforms, BOD and total phosphorus have exceeded the legal limits several times. Such occurrences may be related to the economical activities at the sub-watersheds in addition to changes in the land use of the surroundings of the reservoir.

A influência do uso e ocupação do solo na qualidade e genotoxicidade da água no reservatório de itupararanga, São Paulo, Brasil

The Brazilian reservoirs have been under great anthropogenic pressure due to continued population growth, which in turn places great pressures on the environment. Given this issue, this study aimed to analyze the influence of land use on the quality and genotoxicity of water in the Itupararanga reservoir, São Paulo, Brazil. Water and sediment samples were analyzed for their quality, genotoxicity and benthic diversity, as well as their interrelationship with the landscape. The reservoir was found to be eutrophic in most sampling stations, and genetic al terations were found in radicular cells of exposed Allium cepa in some sampling stations, besides a low diversity of benthic organisms. Among the variables that most contributed to the genetic alterations and water quality are the presence of riparian vegetation, the bare soil and urban occupation. With the results obtained in this study it was concluded that the quality of water and sediment at the Itupararanga reservoir is compromised, requiring emergency managements to ensure the sustainability of water resources.

Avaliação da qualidade da água do reservatório de Itupararanga, bacia do Alto Sorocaba (SP)

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)