Heats of mixing using an isothermal titration calorimeter: Associated thermal effects

[EN] The correct determination of the energy generated or absorbed in the sample cell of an Isothermal Titration Calorimeter (ITC) requires a thorough analysis of the calorimetric signal. This means the identification and quantification of any thermal effect inherent to the working method. In this work, it is carried out a review on several thermal effects, studied by us in previous work, and which appear when an ITC is used for measuring the heats of mixing of liquids in a continuous mode. These effects are due to: (i) the difference between the temperature of the injected liquid and the temperature of the mixture during the mixing process, (ii) the increase of the liquid volume located in the mixing cell and (iii) the stirring velocity. Besides, methods for the identification and quantification of the mentioned effects are suggested.

Technique to measure heats of reaction of Ti-B, Al-Ti-B, and Al-Ti-B4C powder blends

In this research, a modification to initiation aid ignition in bomb calorimetry that involves systemically blending levels of boron and potassium nitrate initiation aids with a bulk structural energetic elemental power blend is developed. A regression is used to estimate the nominal heat of reaction for the primary reaction. The technique is first applied to the synthesis of TiB2 as a validation study to see if close proximity to literature values can be achieved. The technique is then applied to two systems of interest, Al-Ti-B, and Al-Ti-B4C. In all three investigations, x-ray diffraction is used to characterize the product phases of the reactions to determine the extent and identity of the product phases and any by-products that may have formed as a result of adding the initiation aid. The experimental data indicates the technique approximates the heat of reaction value for the synthesis of TiB2 from Ti-B powder blends and the formation of TiB2 is supported by volume fraction analysis by x-ray diffraction. Application to the Al-Ti-B and Al-Ti-B4C blends show some correlation with variation of the initiation aid, with x-ray diffraction showing the formation of equilibrium products. However, these blends require further investigation to resolve more complex interactions and rule out extraneous variables.

The theory of electrons and its applications to the phenomena of light and radiant heat /

Includes bibliographical footnotes and index.

The specific heats of ethyl and propyl alcohols /

Thesis (Ph.D.)--University of California, Berkeley, 1919.

A differential method for the determination of partial molal heat capacities and specific heats of dilute solutions /

Thesis (Ph.D.)--University of California, Berkeley, 1922.

A dictionary of chemistry, exhibiting the present state of the theory and practice of that science, its application to natural philosophy, the processes of manufactures, metallurgy, and numerous other arts dependant on the properties and habitudes of bodies, in the mineral, vegetable, and animal kingdoms. With a considerable number of tables, expressing the elective attractions, specific gravities, comparative heats, component parts, combinations, and other affections of the objects of chemical research. Illustrated with engravings.

Paged continuously.

Visibility of radiant energy,

Mode of access: Internet.

A practical treatise on warming buildings by hot water; on ventilation, and the various methods of distributing artificial heat, and their effects on animal and vegetable physiology. To which are added, an inquiry into the laws of radiant and conducted heat, the chemical constitution of coal, and the combustion of smoke.

"In the present work there have been incorporated several papers ... which have been read before the Institution of Civil Engineers; and also the author's articles on 'Stoves' and 'Ventilation,' published in the Encyclopædia metropolitana."--Pref.

Experimental outlines for a new theory of colours, light and vision : with critical remarks on Sir Isaac Newton's opinions, and some new experiments on radiant caloric.

Mode of access: Internet.

Operator, organizational, and direct support maintenance manual including repair parts and special tools lists : heaters, space, radiant type, portable (type I, model M1941, solid fuel) FSN 4520-257-4877, (type II, model M1941, liquid fuel) FSN 4520-927-4214, (Yukon model M1950, solid or liquid fuel) FSN 4520-287-3353 : heaters, immersion, liquid fuel fired, for corrugated cans ....

"December 1969."

Radiant energy in relation to forests,

"Literature cited": p. 95-103.

Radiant road to reality; tested science of religion,

CONDITION: Good.

Correct procedures for the calculation of heats of adsorption for heterogeneous adsorbents from molecular simulation

Several procedures for calculating the heat of adsorption from Monte Carlo simulations for a heterogeneous adsorbent are presented. Simulations have been performed to generate isotherms for nitrogen at 77 K and methane at 273.15 K in graphitic slit pores of various widths. The procedures were then applied to calculate the heat of adsorption of an activated carbon with an arbitrary pore size distribution. The consistency of the different procedures shows them to be correct in calculating interaction energy contributions to the heat of adsorption. The currently favored procedure for this type of calculation, from the literature, is shown to be incorrect and in serious error when calculating the heat of adsorption of activated carbon.

Comparative studies of hyperhomodesmotic reactions for the calculation of standard heats of formation of fullerenes

How can the accuracy of the calculated standard heats of formation Delta H-f(0) of fullerenes be improved? How reliable are the values of Delta H-f(0) calculated from hyperhomodesmotic reactions? This work is the first to address these questions. By comparing the results obtained from three hyperhomodesmotic reactions containing only fullerenes, it is illustrated that both the resonance contribution and the strain energy contribution should be considered in the construction of hyperhomodesmotic reactions. An attempt to construct such hyperhomodesmotic reactions for fullerenes has been carried out, and several new insights are indicated.