Polyamide thin film composite membranes prepared from 3,4',5-biphenyl triacyl chloride, 3,3',5,5'-biphenyl tetraacyl chloride and m-phenylenediamine

Two novel of tri- and tetra-functional biphenyl acid chloride: 3,4',5-biphenyl triacyl chloride (BTRC) and 3,3',5,5'-biphenyl tetraacyl chloride (BTEC), were synthesized, and used as new monomers for the preparations of the thin film composite (TFC) reverse osmosis (RO) membranes. The TFC RO membranes were prepared on a polysulfone supporting film through interfacial polymerization with the two new monomers and m-phenylenediamine (MPD). The membranes were characterized for the permeation properties, chemical composition, d-space between polymer chains, hydrophilicity, membrane morphology including top surface and cross-section. Permeation experiment was employed to evaluate the membranes performance including salt rejection and water flux. The surface structure and chemical composition of membranes were analyzed by attenuated total reflectance infrared (ATR-IR) and X-ray photoelectronic spectroscopy (XPS). The results revealed that the active layer of membranes was composed of highly cross-linked aromatic polyamide with the functional acylamide (-CONH-) bonds. The TFC membranes prepared from biphenyl acid chloride exhibit higher salt rejection compared with that prepared from trimesoyl chloride (TMC) at the expanse of some flux.

Plasma modification of aromatic polyamide reverse osmosis composite membrane surface

The surface of aromatic polyamide reverse osmosis composite membrane was modified by oxygen and argon plasma. The water permeability of oxygen-plasma-modified membrane increases, and the chlorine resistance of argon-plasma-modified membrane increases. The spectra of the attenuated total reflection-Fourier transform infrared and X-ray photoelectron spectroscopy and the contact angle of the water were analyzed to explain the improvement of the two performances of the composite membrane. The carboxyl groups were introduced when modified by oxygen plasma, and cross-linking occurred when modified by argon plasma. (C) 1997 John Wiley & Sons, Inc.

A comparison of reverse osmosis, nanofiltration and ultrafiltration as concentration processes for skim milk prior to drying

Skim milk was concentrated by reverse osmosis (RO), nanofiltration (NF) and ultrafiltration (UF) and the retentates were spray-dried. The resulting powders were reconstituted to 25% TS and sterilised to evaluate their heat stability. Reverse osmosis led to maximum retention of calcium, a fall in pH for its retentate and its reconstituted powder. All RO powders produced a weak gel on heating. Some calcium was lost during NF and a greater amount during UF. Their resulting reconstituted powders had a higher pH than those produced by RO. Powders produced by UF showed poor heat stability. Only one powder produced by NF showed good heat stability. This could be improved by addition of stabilisers at appropriate addition rates.

Brackish groundwater desalination by reverse osmosis in southeastern Spain. Presence of emerging contaminants and potential impacts on soil-aquifer media

Desalinated brackish groundwater is becoming a new source of water supply to comply with growing water demands, especially in (semi-) arid countries. Recent publications show that some chemical compounds may persist in an unaltered form after the desalination processes and that there is an associated risk of mixing waters with different salinity for irrigation. At the university of Alicante campus (Spain), a mix of desalinated brackish groundwater and water from the existing aquifer is currently applied for landscape irrigation. The presence of 209 emerging compounds, surfactants, priority substances according to the 2008/105/EC Directive, 11 heavy metals and microbiological organisms in blended water and aquifer samples was investigated. Thirty-five compounds were detected (pesticides, pharmaceuticals and surfactants) among them two priority substances α-endosulfan and Ni were found above the permitted maximum concentration. Blended water used for landscape irrigation during the summer period is supersaturated with respect to carbonates, which may ultimately lead to mineral precipitation in the soil-aquifer media and changes in hydraulic parameters.

PBI reverse osmosis membrane for chromuim plating rinse water /

Mode of access: Internet.

Combined reverse osmosis and freeze concentration of bleach plant effluents /

Mode of access: Internet.

Wastewater demineralization by tubular reverse osmosis process /

Mode of access: Internet.

Demineralization of carbon-treated secondary effluent by spiral-wound reverse osmosis process /

Mode of access: Internet.

Recycling nickel electroplating rinse waters by low temperature evaporation and reverse osmosis /

"Contract no. CR-815829."

Operator's manual : water purification unit, reverse osmosis, 600 GPH trailer mounted ... model 0996108001 (4610-01-234-2190).

Includes index.

Organizational, direct support and general support maintenance repair parts and special tool list for water purification unit, reverse osmosis, 600 GPH trailer mounted, flatbed cargo, 5 ton 4 wheel tandem model Rowpu 600-1, (4610-01-093-2380).

"September 1983."

Organizational, direct support, and general support maintenance manual : water purification unit, reverse osmosis, 600 GPH trailer mounted, flatbed cargo, 5 ton 4 wheel tandem model Rowpu 600-1 (4610-01-093-2380) and 600 GPH skid mounted model Rowpu 600-3 (4610-01-113-8651).

Includes index.

Development of an integrated reverse osmosis-greenhouse system driven by solar photovoltaic generators

The development of a system that integrates reverse osmosis (RO) with a horticultural greenhouse has been advanced through laboratory experiments. In this concept, intended for the inland desalination of brackish groundwater in dry areas, the RO concentrate will be reduced in volume by passing it through the evaporative cooling pads of the greenhouse. The system will be powered by solar photovoltaics (PV). Using a solar array simulator, we have verified that the RO can operate with varying power input and recovery rates to meet the water demands for irrigation and cooling of a greenhouse in north-west India. Cooling requires ventilation by a fan which has also been built, tested and optimised with a PV module outdoors. Results from the experiments with these two subsystems (RO and fan) are compared to theoretical predictions to reach conclusions about energy usage, sizing and cost. For example, the optimal sizing for the RO system is 0.12–1.3 m2 of PV module per m2 of membrane, depending on feed salinity. For the fan, the PV module area equals that of the fan aperture. The fan consumes <30 J of electrical energy per m3 of air moved which is 3 times less than that of standard fans. The specific energy consumption of the RO, at 1–2.3 kWh ?m-3, is comparable to that reported by others. Now that the subsystems have been verifi ed, the next step will be to integrate and test the whole system in the field.