Structure and order of the discotic compound 2,3,6,7,10,11-hexakispentyloxytriphenylene as revealed by diffraction and molecular simulation studies

The aggregate structure of the discotic compound 2,3,6,7,10,11-hexakispentyloxytriphenylene (HPT) was studied both for the crystalline state and the liquid crystalline state by using electron crystallography and a molecular simulation approach. In the crystalline state, HPT was found to adopt an orthorhombic P-2212 space group with cell parameters a = 36.73 Angstrom, b = 27.99 Angstrom and c = 4.91 Angstrom. Molecular packing calculations were conducted to elucidate the molecular conformation and mutual orientational characteristics in the different states. Phase transitions and relationships are discussed from a structural point of view.

On trip planning queries in spatial databases

In this paper we discuss a new type of query in Spatial Databases, called Trip Planning Query (TPQ). Given a set of points P in space, where each point belongs to a category, and given two points s and e, TPQ asks for the best trip that starts at s, passes through exactly one point from each category, and ends at e. An example of a TPQ is when a user wants to visit a set of different places and at the same time minimize the total travelling cost, e.g. what is the shortest travelling plan for me to visit an automobile shop, a CVS pharmacy outlet, and a Best Buy shop along my trip from A to B? The trip planning query is an extension of the well-known TSP problem and therefore is NP-hard. The difficulty of this query lies in the existence of multiple choices for each category. In this paper, we first study fast approximation algorithms for the trip planning query in a metric space, assuming that the data set fits in main memory, and give the theory analysis of their approximation bounds. Then, the trip planning query is examined for data sets that do not fit in main memory and must be stored on disk. For the disk-resident data, we consider two cases. In one case, we assume that the points are located in Euclidean space and indexed with an Rtree. In the other case, we consider the problem of points that lie on the edges of a spatial network (e.g. road network) and the distance between two points is defined using the shortest distance over the network. Finally, we give an experimental evaluation of the proposed algorithms using synthetic data sets generated on real road networks.

Fuzzy Absolutes and Related Topics

The study on the fuzzy absolutes and related topics. The different kinds of extensions especially compactification formed a major area of study in topology. Perfect continuous mappings always preserve certain topological properties. The concept of Fuzzy sets introduced by the American Cyberneticist L. A Zadeh started a revolution in every branch of knowledge and in particular in every branch of mathematics. Fuzziness is a kind of uncertainty and uncertainty of a symbol lies in the lack of well-defined boundaries of the set of objects to which this symbol belongs. Introduce an s-continuous mapping from a topological space to a fuzzy topological space and prove that the image of an H-closed space under an s-continuous mapping is f-H closed. Here also proved that the arbitrary product fi and sum of  fi of the s-continuous maps fi are also s-continuous. The original motivation behind the study of absolutes was the problem of characterizing the projective objects in the category of compact spaces and continuous functions.

Structure and thermal reactivity of Zn(II) salts of isocinchomeronic acid (2,5-pyridinedicarboxylic acid)

The synthesis, an improved refined crystal and molecular structure re-determination, and the thermal decomposition behavior of two Zn(II) derivatives of isocinchomeronic acid (2,5-pyridinedicarboxylic acid or H(2)2,5-pydc) are presented. [Zn(2,5-pydc)(H(2)O)(3)Zn(2,5-pydc)(H(2)O)(2)](2) (1) crystallizes in the triclinic P-1 space group with a = 7.106(2), b = 11.450(2), c = 11.869(1) angstrom, alpha = 107.29(1), beta = 104.08(1), gamma = 90.32(2)degrees, and Z = 2. [Zn(2,5-pydc)(H(2)O)(2)] center dot H(2)O (2) is orthorhombic (P2(1)2(1)2(1) space group), with a = 7.342(1), b = 9.430(1), c = 13.834(2) angstrom, and Z = 4. The structures were refined to agreement R(1)-factors of 0.0315 (1) and 0.0336 (2). Complex (1) is arranged as molecular Zn(4)(2,5-pydc)(4)(H(2)O)(10) tetramers, the cages of which define channels that remain unblocked by anions. Compound (2) is polymeric with Zn(2,5-pydc)(H(2)O)(2) and Zn(2,5-pydc)(H(2)O)(3) units linked through bridging ligands. Both compounds were synthesized under mild conditions in aqueous media, without need to resort to hydrothermal media. Changing the pH from 4.51 to 5.75 suffices to direct the chemical processes toward the orthorhombic compound rather than to the triclinic one.

Empregadas domésticas e Relações de trabalho nos loteamentos fechados de Presidente Prudente - SP

Pós-graduação em Geografia - FCT

Estudo de geração de campo uniforme para modelagem eletromagnética

Para estudar os problemas de prospecção geofísica eletromagnética através de modelagem analógica, as condições em escala natural são representadas, no laboratório, em escala reduzida de acordo com a teoria da similitude. Portanto, para investigar os problemas de técnicas VLF, AFMAG e MT, frequentemente é necessário criar campo uniforme no arranjo experimental. Vários sistemas físicos para geração de campos uniformes são analisados teoricamente nesta tese. Os sistemas estudados aqui são a bobina circular, bobina de Helmholtz, solenóide, um plano de corrente e dois planos paralelos de correntes. As equações analíticas foram obtidas para campo magnético num ponto do espaço e subsequentemente as condições de campo uniforme. Nos casos em que as condições para o campo uniforme não puderam ser obtidas analiticamente, a porcentagem de desvio do campo em relação a um ponto pré-selecionado foi calculada. Contudo, os mapas de campo magnético, assim como o mapa de porcentagem de desvio, estão presentes para todos os sistemas estudados aqui. Também, foram calculados as áreas e os volumes espaciais de vários desvios de porcentagem do campo uniforme. Um estudo comparativo desses sistemas mostra que o solenóide é a maneira mais eficiente para criar um campo uniforme, seguido pelo sistema de bobinas de Helmholtz. Porém, o campo criado em um solenóide está em um espaço fechado onde é difícil colocar modelos e substituí-los para executar experimentos. Portanto, recomenda-se o uso de bobinas de Helmholtz para criar um campo uniforme. Este último sistema fornece campo uniforme com espaço aberto suficiente, o que facilita o experimento.

Spectroscopic characterization and crystal structure of cis-Bis(N-(2-benzoyl)-N ',N '-diphenylthioureato-k O-2,S)nickel(II)

The title compound [Ni(C20H15N2OS)(2)] is prepared by the reaction of metal acetate with the corresponding acylthiourea derivative. The complex is characterized by elemental analysis, IR, H-1 and C-13 NMR, and its structure is determined by single crystal X-ray diffraction. The Ni(II) ion is coordinated by the S and O atoms of two N-benzoyl-N',N'-diphenylthiourea ligands in a slightly distorted square-planar coordination geometry. The two O and two S atoms are mutually cis to each other. The substance crystallizes triclinic (P-1 space group) with cell dimensions a = 10.7262(9) , b = 12.938(3) , c = 14.2085(12) , alpha = 74.650(4)A degrees, beta = 78.398(4)A degrees, gamma = 68.200(5)A degrees, and two formula units in the unit cell. The structure is very close to the related N-(2-furoyl) Ni complex reported previously.

La creación del espacio trágico en la obra de Gabriel García Márquez : Una lectura sofoclea

La influencia de Sófocles y, concretamente, de las tragedias tebanas en la obra de García Márquez se manifiesta a niveles diversos: en la construcción de la trama, en la elaboración del personaje tiránico, en los temas de la violencia y el destino y, por supuesto, en el tratamiento del tiempo y del espacio. En este artículo se analiza la creación del espacio en García Márquez a través de dos elementos contrapuestos que provienen de su lectura de la tragedia sofoclea: el genos, símbolo de un espacio cerrado y ligado a un tiempo "redondo", el espacio del relato, y la polis, un lugar abierto y lejano, donde se produce la Historia con mayúsculas. Esta dicotomía será observada en distintas obras de García Márquez, pero especialmente en Edipo Alcalde. El conflicto trágico de la discordia civil se refleja, así pues, en la construcción de un espacio único, claustrofóbico y corrompido

La creación del espacio trágico en la obra de Gabriel García Márquez : Una lectura sofoclea

La influencia de Sófocles y, concretamente, de las tragedias tebanas en la obra de García Márquez se manifiesta a niveles diversos: en la construcción de la trama, en la elaboración del personaje tiránico, en los temas de la violencia y el destino y, por supuesto, en el tratamiento del tiempo y del espacio. En este artículo se analiza la creación del espacio en García Márquez a través de dos elementos contrapuestos que provienen de su lectura de la tragedia sofoclea: el genos, símbolo de un espacio cerrado y ligado a un tiempo "redondo", el espacio del relato, y la polis, un lugar abierto y lejano, donde se produce la Historia con mayúsculas. Esta dicotomía será observada en distintas obras de García Márquez, pero especialmente en Edipo Alcalde. El conflicto trágico de la discordia civil se refleja, así pues, en la construcción de un espacio único, claustrofóbico y corrompido

La creación del espacio trágico en la obra de Gabriel García Márquez : Una lectura sofoclea

La influencia de Sófocles y, concretamente, de las tragedias tebanas en la obra de García Márquez se manifiesta a niveles diversos: en la construcción de la trama, en la elaboración del personaje tiránico, en los temas de la violencia y el destino y, por supuesto, en el tratamiento del tiempo y del espacio. En este artículo se analiza la creación del espacio en García Márquez a través de dos elementos contrapuestos que provienen de su lectura de la tragedia sofoclea: el genos, símbolo de un espacio cerrado y ligado a un tiempo "redondo", el espacio del relato, y la polis, un lugar abierto y lejano, donde se produce la Historia con mayúsculas. Esta dicotomía será observada en distintas obras de García Márquez, pero especialmente en Edipo Alcalde. El conflicto trágico de la discordia civil se refleja, así pues, en la construcción de un espacio único, claustrofóbico y corrompido

Flexible structure control laboratory development and technology demonstration /

"Final report for the period July 1985 to July 1987."

ON CLOSED GEODESICS IN THE LEAF SPACE OF SINGULAR RIEMANNIAN FOLIATIONS

In this paper we prove the existence of closed geodesics in the leaf space of some classes of singular Riemannian foliations (s.r.f.), namely s.r.fs. that admit sections or have no horizontal conjugate points. We also investigate the shortening process with respect to Riemannian foliations.

Improving the statistical preparation for measuring soil N2O flux by closed chamber

Nitrous oxide emissions from soil are known to be spatially and temporally volatile. Reliable estimation of emissions over a given time and space depends on measuring with sufficient intensity but deciding on the number of measuring stations and the frequency of observation can be vexing. The question of low frequency manual observations providing comparable results to high frequency automated sampling also arises. Data collected from a replicated field experiment was intensively studied with the intention to give some statistically robust guidance on these issues. The experiment had nitrous oxide soil to air flux monitored within 10 m by 2.5 m plots by automated closed chambers under a 3 h average sampling interval and by manual static chambers under a three day average sampling interval over sixty days. Observed trends in flux over time by the static chambers were mostly within the auto chamber bounds of experimental error. Cumulated nitrous oxide emissions as measured by each system were also within error bounds. Under the temporal response pattern in this experiment, no significant loss of information was observed after culling the data to simulate results under various low frequency scenarios. Within the confines of this experiment observations from the manual chambers were not spatially correlated above distances of 1 m. Statistical power was therefore found to improve due to increased replicates per treatment or chambers per replicate. Careful after action review of experimental data can deliver savings for future work.

Taking cues from outer space : the E&P sector can learn much about asset maintenance from the space and satellite industry

The E&P sector can learn much about asset maintenance from the space and satellite industry. Practitioners from both the upstream oil and gas industry and the space and satellite sector have repeatedly noted several striking similarities between the two industries over the years, which have in turn resulted in many direct comparisons in the media and industry press. The similarities between the two industries have even resulted in a modest amount of cross-pollinating between the respective supply chains. Because the operating conditions of both industries are so extreme, some oil and gas equipment vendors have occasionally sourced motors and other parts from aerospace contractors. Also, satellites are now being used to assess oil fires, detect subsidence in oil fields, measure oil spills, collect and transmit operational data from oil and gas fields, and monitor the movement of icebergs that might potentially collide with offshore oil and gas installations.

Open and closed boundaries in large-scale convective dynamos

Earlier work has suggested that large-scale dynamos can reach and maintain equipartition field strengths on a dynamical time scale only if magnetic helicity of the fluctuating field can be shed from the domain through open boundaries. To test this scenario in convection-driven dynamos by comparing results for open and closed boundary conditions. Three-dimensional numerical simulations of turbulent compressible convection with shear and rotation are used to study the effects of boundary conditions on the excitation and saturation level of large-scale dynamos. Open (vertical field) and closed (perfect conductor) boundary conditions are used for the magnetic field. The contours of shear are vertical, crossing the outer surface, and are thus ideally suited for driving a shear-induced magnetic helicity flux. We find that for given shear and rotation rate, the growth rate of the magnetic field is larger if open boundary conditions are used. The growth rate first increases for small magnetic Reynolds number, Rm, but then levels off at an approximately constant value for intermediate values of Rm. For large enough Rm, a small-scale dynamo is excited and the growth rate in this regime increases proportional to Rm^(1/2). In the nonlinear regime, the saturation level of the energy of the mean magnetic field is independent of Rm when open boundaries are used. In the case of perfect conductor boundaries, the saturation level first increases as a function of Rm, but then decreases proportional to Rm^(-1) for Rm > 30, indicative of catastrophic quenching. These results suggest that the shear-induced magnetic helicity flux is efficient in alleviating catastrophic quenching when open boundaries are used. The horizontally averaged mean field is still weakly decreasing as a function of Rm even for open boundaries.