Barium measured on water bottle samples during POLARSTERN cruise ARK-XXII/2 (SPACE)

Dissolved barium has been shown to have the potential to distinguish Eurasian from North American (NA) river runoff. As part of the ARK-XXII/2 Polarstern expedition in summer 2007, Ba was analyzed in the Barents, Kara, Laptev seas, and the Eurasian Basins as well as the Makarov Basin up to the Alpha and Mendeleyev Ridges. By combining salinity, d18O and initial phosphate corrected for mineralization with oxygen (PO4*) or N/P ratios we identified the water mass fractions of meteoric water, sea ice meltwater, and marine waters of Atlantic as well as Pacific origin in the upper water column. In all basins inside the lower halocline layer and the Arctic intermediate waters we find Ba concentrations close to those of the Fram Strait branch of the lower halocline (41-45 nM), reflecting the composition of the incoming Atlantic water. A layer of upper halocline water (UHW) with higher Ba concentrations (45-55 nM) is identified in the Makarov Basin. Atop of the UHW, the Surface Mixed Layer (SML), including the summer and winter mixed layers, has high concentrations of Ba (58-67 nM). In the SML of the investigated area of the central Arctic the meteoric fraction can be identified by assuming a conservative behavior of Ba to be primarily of Eurasian river origin. However, in productive coastal regions biological removal compromises the use of Ba to distinguish between Eurasian and NA rivers. As a consequence, the NA river water fraction is underestimated in productive surface waters or waters that have passed a productive region, whereas this fraction is overestimated in subsurface waters containing remineralised Ba, particularly when these waters have passed productive shelf regions. Especially in the Laptev Sea and small regions in the Barents Sea, Ba concentrations are low in surface waters. In the Laptev Sea exceptionally high Ba concentrations in shelf bottom waters indicate that Ba is removed from surface waters to deep waters by biological activity enhanced by increasing ice-free conditions as well as by scavenging by organic matter of terrestrial origin. We interpret high Ba concentrations in the UHW of the Makarov Basin to result from enrichment by remineralisation in bottom waters on the shelf of the Chukchi Sea and therefore the calculated NA runoff is an artefact. We conclude that no NA runoff can be demonstrated unequivocally anywhere during our expedition with the set of tracers considered here. Small contributions of NA runoff may have been masked by Ba depletion and could only be resolved by supportive tracers on the uptake history. We thus suggest that Ba has to be used with care as it can put limits but not yield quantitative water mass distributions. Only if the extra Ba inputs exceed the cumulative biological uptake the signal can be unequivocally attributed to NA runoff.

(Table 2) Vertical distribution of particulate matter and its organic and mineral components in waters of the Tropical Atlantic in November 1984

Results of multiyear investigation of distribution and composition of suspended matter in waters off the northwest coast of Africa are presented. Large-scale circulation, upwelling, river runoff, and aeolian deposition affect distribution and evolution of biochemical composition of particulate matter. Concentrations of organic carbon, nitrogen, chlorophyll, phytoplankton and trace metals in the particulate matter are determined. Ratios of these components exhibit seasonal variations.

Oxygen and carbon isotope measurements of North Atlantic from IODP Hole 307-U1317E

Recent deep-ocean exploration has revealed unexpectedly widespread and diverse coral ecosystems in deep water on continental shelves, slopes, seamounts, and ridge systems around the world. Origin and growth history of these cold-water coral mounds are poorly known, owing to a lack of complete stratigraphic sections through them. Here we show high-resolution oxygen isotope records of planktic foraminifers from the base to the top of Challenger Mound, southwest of Ireland, which was drilled during Integrated Ocean Drilling Program Expedition 307. Challenger Mound began to grow during isotope stage 92 (2.24 million years ago (Ma)), immediately after the onset of Northern Hemisphere glaciation and the initiation of modern stratification in the northeast Atlantic. Mound initiation was likely due to reintroduction of Mediterranean Outflow Water (MOW) and ensuing development of a density gradient with overlying northeastern Atlantic water (NEAW), where organic matter was prone to be stagnated and fueled the coral ecosystem. Coral growth continued for 11 glacial-interglacial cycles until isotopic stage 72 (1.82 Ma) with glacial siliciclastic input from the continental margin. After a long hiatus that separates the lower mound and the upper mound, coral growth restored for a short time in isotope stages 19-18 (0.8-0.7 Ma) in which sediments were either eroded or not deposited during a full glacial stage. The development pattern of the water mass interface between MOW and NEAW might have changed, because of the fluctuations of the MOW production which is responsible for the amplitude in ice volume oscillations from the low-amplitude 41 ka cycles for the lower mound to the high-amplitude 100 ka cycles for the upper mound. The average sedimentation and CaCO3 production rates of the lower mound were evaluated 27 cm/ka and 31.1 g/cm2/ka, respectively.

(Table 1) Age determination of North Atlantic sediment cores

Four cores raised from the eastern Norwegian Sea and adjacent Norwegian fjords at sites influenced by Atlantic water have been investigated. Oxygen isotope analyses in benthic and planktonic foraminifera are used as a proxy for the paleotemperature development spanning the last 800 years. The cores have been dated using a combination of 210Pb and radiocarbon dates yielding time resolutions of 2-5 years for the last century and 9-25 years beyond this. The proxy records have been compared with instrumental time series covering the last 100 years in order to validate the oxygen isotope measurements as a proxy for paleotemperature. The comparison shows that the paleotemperature variability derived from the oxygen isotope analyses is generally similar to the amplitudes and trends seen in the instrumental time series. In particular, a cooling around 1905-1925 followed by a warming until 1955 is evident in all proxy records as well as in the instrumental time series. Beyond the last century the proxy records show two periods from ~1225-1450 and ~1650-1905(25) when temperatures were 1.3-1.6°C lower than present separated by a period of temperatures periodically comparable to present. The last 80 years represent the modern warming and appear to be the warmest period of the last 800 years. We find that that the ocean temperature variability is comparable to terrestrial reconstructions from the region implying a strong link in the ocean-atmosphere climate system. This suggests that the climate variability in this region beyond the period covered by instrumental time series was also associated with changes in the thermohaline circulation.

Radon 222 excess measured on water bottle samples during HEINCKE cruise HE153

In the years 2000 and 2001 we measured methane concentrations exceeding up to two orders of magnitude the equilibrium with the atmosphere in the water column on the SW-Spitsbergen continental shelf. This methane anomaly extended from its centre on the shelf westwards over the upper slope and eastwards well into the inner basins of the two southernmost Spitsbergen fjords, the Hornsundfjord and the van Mijenfjord. Methane concentrations and stable carbon isotopic ratios varied between 2 and 240 nM, and between -53 per mill and -20 per mill VPDB, respectively. Methane in high concentrations was depleted in 13C whereas in low concentrations d13CCH4 values were highly variable. On the continental shelf we found that methane discharged from seeps on top of sandy and gravelly banks is isotopically heavier than methane escaping from troughs filled with silty and clayey sediments. These distinct isotopic signatures suggest that methane is gently released from several inter-granular seepages or micro-seepages widely spread over the shelf. A potential migration path for thermogenic or hydrate methane may be the Hornsund Fracture Zone, a south-north running reactivated fault system created by stretching of the continental crust. After discharge into the water column, local water currents fed by Atlantic water, coastal water, and freshwater outflows from the fjords further determine pathways and fate of the methane. We used d18Owater and 222Rn data to trace origin and advection of the local water masses and water mixing processes. Methane spreads predominantly along pycnoclines and by vertical mixing. During transport methane is influenced simultaneously by oxidation and dilution, as well as loss into the atmosphere. Together these processes cause the spatial variability of the anomaly and heterogeneity in d13CCH4 in this polar shelf environment.

Age models and stable isotope record of sediment cores from the Atlantic Ocean

The high-resolution delta18O and delta13C records of benthic foraminifera from a 150,000-year long core from the Caribbean Sea indicate that there was generally high delta13C during glaciations and low delta13C during interglaciations. Due to its 1800-m sill depth, the properties of deep water in the Caribbean Sea are similar to those of middepth tropical Atlantic water. During interglaciations, the water filling the deep Caribbean Sea is an admixture of low delta13C Upper Circumpolar Water (UCPW) and high delta13C Upper North Atlantic Deep Water (UNADW). By contrast, only high delta13C UNADW enters during glaciations. Deep ocean circulation changes can influence atmospheric CO2 levels (Broecker and Takahashi, 1985; Boyle, 1988 doi:10.1029/JC093iC12p15701; Keir, 1988 doi:10.1029/PA003i004p00413; Broecker and Peng, 1989 doi:10.1029/GB003i003p00215). By comparing delta13C records of benthic foraminifera from cores lying in Southern Ocean Water, the Caribbean Sea, and at several other Atlantic Ocean sites, the thermohaline state of the Atlantic Ocean (how close it was to a full glacial or full interglacial configuration) is characterized. A continuum of circulation patterns between the glacial and interglacial extremes appears to have existed in the past. Subtracting the deep Pacific (~mean ocean water) delta13C record from the Caribbean delta13C record yields a record which describes large changes in the Atlantic Ocean thermohaline circulation. The delta13C difference varies as the vertical nutrient distribution changes. This new proxy record bears a striking resemblance to the 150,000-year-long atmospheric CO2 record (Barnola et al., 1987 doi:10.1038/329408a0). This favorable comparison between the new proxy record and the atmospheric CO2 record is consistent with Boyle's (1988a) model that vertical nutrient redistribution has driven large atmospheric CO2 changes in the past. Changes in the relative contribution of NADW and Pacific outflow water to the Southern Ocean are also consistent with Broecker and Peng's (1989) recent model for atmospheric CO2 changes.

Physical oceanography during POLARSTERN cruise ARK-XIX/4b

Exchanges between the North Atlantic and the Arctic Ocean result in the most dramatic water mass conversions in the World Ocean: warm and saline Atlantic waters, flowing through the Nordic Seas into the Arctic Ocean, are modified by cooling, freezing and melting to become shallow fresh waters, ice and saline deep waters. The outflow from the Nordic Seas to the south provides the initial driving of the global thermohaline circulation cell. Knowledge of these fluxes and understanding of the modification processes is a major prerequisite for the quantification of the rate of overturning within the large circulation cells of the Arctic and the Atlantic Oceans, and is also a basic requirement for understanding the role of these ocean areas in climate variability on interannual to decadal time scales. The Fram Strait represents the only deep connection between the Arctic Ocean and the Nordic Seas. Just as the freshwater transport from the Arctic Ocean is of major influence on convection in the Nordic Seas and further south, the transport of warm and saline Atlantic water affects the water mass characteristics in the Arctic Ocean which has consequences for the internal circulation and possibly influences also ice and atmosphere. The West Spitsbergen Current carrying Atlantic Water northward. The East Greenland Current, carrying water from the Arctic Ocean southwards has a concentrated core above the continental slope. It is our aim to measure the oceanic fluxes through Fram Strait and to determine their variability in seasonal to decadal time scales. 53 CTD profiles were taken at 51 stations. Two CTD systems from Sea-Bird Electronics Inc SBE911+ were used. Mainly SN 561 with duplicate T and C sensors (temperature sensors SBE3, SN 2685 and 2678, conductivity sensors SBE4, SN 2325 and 2618 and pressure sensor Digiquartz 410K-105 SN 75659) was in service. For the control of the temperature sensors a SBE35 RT digital reversing thermometer, SN 27 was applied. The CTD was connected to a SBE32 Carousel Water Sampler, SN 273 (24 12-liter bottles). For 3 CTD-Stations (726-3, 727-1, 728-1) the Sea-Bird 911+ probe SN 485 was used with temperature sensor SBE3 SN 2460, conductivity sensor SBE4 SN 2054, pressure sensor Digiquartz 410K SN 68997 and the SBE32 Carousel Water Sampler SN 202. Additionally Benthos Altimeters Model 2110-2, SN 189 and SN 208 and Wetlabs C-Star Transmissiometers SN 403 and SN 267 were mounted on the carousels. During the cruise a total number of 184 water samples were analysed with a Guildline Autosal 8400B salinometer, and IAPSO standard seawater batch number P141, K=0.99993. 20 salinity samples were brought back to AWI for onshore analysis. The CTD sensors were calibrated before and after the cruise by Sea-Bird Electronics.

Ciliate abundance in waters of the Argentine shelf and the Drake Passage, the south-western Atlantic

Ciliates from sub-surface waters of the Argentine shelf and the Drake Passage under austral summer and autumn conditions were examined and compared for the first time. In both environments, the taxonomic structure of ciliates was related to temperature and salinity, and aloricate oligotrichs dominated in density (80%) over loricate oligotrichs, litostomatids and prostomatids, while the microplanktonic fraction prevailed in terms of biomass (90%) over the nanociliates. Myrionecta rubra was found all along the Argentine shelf only in autumn, but showed isolated peaks of abundance (10**3 ind./L) during summer. Mean values of density and biomass of total ciliates decreased ca. 2-fold from the shelf-slope to oceanic waters, while potential maximum production of aloricate oligotrichs decreased 9-fold, in relation with the drop in chlorophyll a concentration and the latitudinal decline of temperature, also reflected in maximum growth rates. Fifty percent of total ciliate abundance was represented by local increases (maximum: 20 000 ind./L and 25 µg C/L), which were spatially superimposed with ranges of seawater temperature and chlorophyll a concentrations of 10-15°C and 0.6-6 µg/L, respectively and were found in the nearby of fronts located on the shelf and the slope.

Analytical approach to quantile estimation in regional frequency analysis based on fuzzy framework

Regional frequency analysis is widely used for estimating quantiles of hydrological extreme events at sparsely gauged/ungauged target sites in river basins. It involves identification of a region (group of watersheds) resembling watershed of the target site, and use of information pooled from the region to estimate quantile for the target site. In the analysis, watershed of the target site is assumed to completely resemble watersheds in the identified region in terms of mechanism underlying generation of extreme event. In reality, it is rare to find watersheds that completely resemble each other. Fuzzy clustering approach can account for partial resemblance of watersheds and yield region(s) for the target site. Formation of regions and quantile estimation requires discerning information from fuzzy-membership matrix obtained based on the approach. Practitioners often defuzzify the matrix to form disjoint clusters (regions) and use them as the basis for quantile estimation. The defuzzification approach (DFA) results in loss of information discerned on partial resemblance of watersheds. The lost information cannot be utilized in quantile estimation, owing to which the estimates could have significant error. To avert the loss of information, a threshold strategy (TS) was considered in some prior studies. In this study, it is analytically shown that the strategy results in under-prediction of quantiles. To address this, a mathematical approach is proposed in this study and its effectiveness in estimating flood quantiles relative to DFA and TS is demonstrated through Monte-Carlo simulation experiments and case study on Mid-Atlantic water resources region, USA. (C) 2015 Elsevier B.V. All rights reserved.

Biologie et dynamique d'un Sciaenidae ouest-africain Pseudotolithus senegalensis (V.)

In relation to the hydroclimate prevailing off Congo (B) and Côte d'Ivoire, synchronic variations are described in abundance and distribution of Pseudotolithus senegalensis V., economically the most important species in the West African trawl fishery. Although this fish prefers the warm surface layer, it is relatively indifferent to hydrological conditions, since it may also occur in the thermocline down to the higher levels of 'Central South Atlantic Water'. The oxygen concentration appears to have an important effect upon their distribution, especially the low concentrations occurring with the upwelling. The main biological functions, such as spawning and recruitment times, condition factor, diet and ring appearance on otoliths, also follow cycles, which are parallel with the hydroclimate one. Therefore, the ring-shaped structures revealed by burning previously ground otoliths could be easily interpreted. Thus, an accurate method for ageing tropical fish is now available. From the age determinations for the Congolese stock, it appears that growth is fast and total mortality rate high. An influence of fishing effort, which increased 3 times during the exploited phase of sampled specimens, appears both in growth and in total mortality. From there an estimate for the fishing mortality could be given. The estimates of dynamic parameters for the Congolese stock are then used in the Beverton-Holt model. A valuable increase of the yield could be expected, if mesh size is widened and effort restricted.

Wetland resource evaluation and the NRA's role in its conservation. 1. Resource assessment

This is the Wetland resource evaluation and the NRA's role in its conservation: Resource assessment report produced by the National Rivers Authority in 1995. This R&D document provides a strategy for the assessment of the wetland resource of England and Wales. As a first step the report defines wetlands in their UK context. The following working definition is suggested: Wetland is land that has (or had until modified) a water level predominantly at, near, or up to 1.5 m above the ground surface for sufficient time during the year to allow hydrological processes to be a major influence on the soils and biota. These processes may be expressed in certain features, such as characteristic soils and vegetation. The report also summarises a hydrotopographical classification of wetlands. The report then develops a strategy for the establishment of a wetland resource Inventory based on a geographical information system (GIS) as a means of storing and manipulating site data from across England and Wales.

Circulation pattern of the Egyptian Mediterranean waters during winter and summer seasons

The water circulation of the Egyptian Mediterranean waters was computed during winter and summer seasons using the dynamic method. The reference level was set at the 1000db surface. The results showed that the surface circulation is dominated by the Atlantic water inflow along the North African coast and by two major gyres, the Mersa Matruth anticyclonic gyre and El-Arish cyclonic gyre. The results showed a seasonal reversal of El-Arish gyre, being cyclonic in winter and anticyclonic in summer. El-Arish gyre had not been previously measured. The geostrophic current velocity at the edges of the Mersa Matruth gyre varied between 12.5 and 29.1cm/sec in winter and between 6.5 and 13.1cm/sec in summer. The current velocity reached its maximum values (>40cm/sec) at El-Arish gyre. The current velocity at the two gyres decreased with increasing depth. The North African Current affects the surface waters down to a depth of 100m, and that its mean velocity varies between 6 and 38cm/sec.