Transição do enchimento terciário para o encaixe fluvial quaternário na área de Vila Velha de Ródão (sector NE da Bacia do Baixo Tejo)

The geomorphologic characteristics and lithostratigraphic units of the transition from the Tertiary filling stage to the Quaternary fluvial incision in the Vila Velha de Ródão area (Lower Tagus Basin, NE sector) are presented. Several morphodynamic episodes, which had an important tectonic control, were distinguished. The same main morphosedimentary processes can be identified in other areas of this important river basin. Five periods of Quaternary fluvial incision were characterized.

Proposta metodológica para avaliação preliminar de jazigos de shale gas

O potencial de um reservatório de shale gas e influenciado por um grande número de fatores, tais como a sua mineralogia e textura, o seu tipo e maturação de querogénio, a saturação de fluidos, os mecanismos de armazenamento de gás, a profundidade do reservatório e a temperatura e pressão de poros. Nesse sentido, o principal objetivo desta tese foi estabelecer uma metodologia de avaliação preliminar de potenciais jazigos de shale gas (estudo de afloramentos com base numa litoestratigrafia de alta resolução), que foi posteriormente aplicada na Formação de Vale das Fontes (Bacia Lusitânica, Portugal). Esta tese tem a particularidade de contribuir, não só para o aprofundamento da informação a nível geoquímico do local, mas também na abordagem inovadora que permitiu a caracterização petrofísica da Formação de Vale das Fontes. Para a aplicação da metodologia estabelecida, foi necessária a realização dos seguintes ensaios laboratoriais: Rock-Eval 6, picnometria de gás hélio, ensaio de resistência a compressão simples, Darcypress e a difracção de raios-X, aplicando o método de Rietveld. Os resultados obtidos na análise petrofísica mostram uma formação rochosa de baixa porosidade que segundo a classificação ISRM, e classificada como ”Resistente”, para alem de revelar comportamento dúctil e elevado índice de fragilidade. A permeabilidade média obtida situa a Formação no intervalo correspondente as permeabilidades atribuídas aos jazigos de tigh gas, indicando a necessidade de fracturação hidráulica, no caso de uma eventual exploração de hidrocarbonetos, enquanto a difracção de raios-X destaca a calcite, o quartzo e os filossilicatos como os minerais mais presentes na Formação. Do ponto de vista geoquímico, os resultados obtidos mostram que apesar do considerável teor médio de carbono orgânico total, a natureza da matéria orgânica analisada e maioritariamente imatura, composta, principalmente, por querogénio do tipo IV, o que indica a incapacidade de a formação gerar hidrocarbonetos em quantidades economicamente exploráveis.

Systematic stratigraphic study of cenozoic sediments of Kerala with Special reference to warkalli and quilon formations

Quaternary stratigraphy of the Kerala coast and the genetic aspects of the sediments are discussed. The age of limeshells, and peaty sediments determined by radio carbon dating have been used for reconstruction of sea level changes. Evolution of red sands occurring in some parts of the coastal tract of Kerala is also discussed, based on textural parameters and quartz grain morphology.

Diagênese e proveniência dos arenitos da tectonossequência Rifte na bacias do Rio do Peixe Araripe, NE do Brasil

This thesis presents diagenetic and provenance studies of sandstones belonging to the Rift Tectonosequence of the Rio do Peixe and Araripe basins. These basins are located in the interior of Northeast Brazil aligned along the Trend-Cariri Potiguar. Their origin is related to the Early Cretaceous rifting event. In terms of lithostratigraphy, the studied section corresponds to the Antenor Navarro, Sousa and Rio Piranhas formations of the Rio do Peixe Basin, and the Missão Velha and Abaiara formations of the Araripe Basin, outcropping in the central-west Cariri Valley. A facies analysis was performed and identified nine distinct sedimentary facies for the Rio de Peixe Basin and ten sedimentary facies for the Araripe Basin, individualized according to the different rock types and their sedimentary structures. These facies associations to led paleoenvironments interpretations and their vertical succession allowed understanding the evolution of the depositional setting during the cronostratigraphic interval studied in these basins. Based on petrographic and diagenetic studies it was possible to characterize the texture and mineralogy of these sandstones, identifying their diagenetic stage and the grain framework provenance. The petrographic study allowed to classify the lithotypes studied in both basins as quartzarenites. Such quartzarenites, in general, are rich in quartz, feldspar and lithic fragment grains, and at accessory levels tourmaline, sphene, zircon, epidote and other mineralogy. The diagenetic history of the studied rocks proved to be very complex, being characterized by a variety mineral of phases that succeeded each other during the eo, meso and telodiagenetic stages. According to the studied formation and the textural and compositional aspects of the rocks, some processes were more or less active, while others were even absent. The eodiagenetic stage is marked by mechanical infiltration of clays and early mechanical compactional processes. The mesodiagenetic phase is characterized by continuity of the mechanical compaction and the beggining of chemical compaction, with quartz and feldspar overgrowths, precipitation of kaolinite, alteration of framework grains to chlorite and illite, and finally, precipitation of opaque minerals. The telodiagenetic stage is represented by the oxidation of some grains, matrix and cements. For the provenance analysis of the studied sandstones were used ternary diagrams whose vertices correspond to the percentage of quartz, feldspar and lithic fragments. This study allowed identifies the source area of these rocks as continental blocks. It was also possible, based on the chemical stability and mineralogical maturity of the rocks, recognize that the Antenor Navarro Formation of the Rio do Peixe Basin, and the upper section of the Missão Velha Formation of Araripe Basin have less maturity and stability when compared with the other studied formations

A stratigraphic chart of the Late Carboniferous/Permian succession of the eastern border of the Parana Basin, Brazil, South America

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Sucessão sedimentar do Grupo Bauru na região de Pirapozinho (SP)

There is yet enthusiastic debate in the literature about the environmental conditions that originated the Cretaceous deposits of the Bauru Group, despite many authors accept that arid climatic conditions widely dominant at the base, evolved to chiefly fluvial-lacustrine conditions at the intermediate portion, and to arid conditions again at the top of the unit. The Bauru Group covers an area of about 117.000 km 2 of the Paraná Basin in São Paulo State territory. Core samples of this lithostratigraphic unit collected from a drill hole at Pirapozinho (Southwest of the São Paulo State) are described and together with well log data brought new information that do not agree with the described model. It was identified in this well the Caiuá, Pirapozinho, Santo Anastácio, Araçatuba and Adamantina formations. The study of these core samples clearly showed the dominance of hydrodynamic sedimentary structures and high to medium intensity of bioturbation in whole profile. These characteristics observed in core samples and compared to patterns of geophysical logs testify the dominance of fluvial processes in the Bauru Group deposition at the studied area. These new data suggests that the paleo-environmental evolution of the unit was much more complex, showing strong lateral and vertical changes that diverges from the model more widely accepted in the literature.

Grupo itararé (P - C da bacia do Paraná) nas regiões de Limeira e Piracicaba - SP: Contribuição ao estudo das litofácies

The Permian-Carboniferous Itararé Group is one complexe lithostratigraphic unit of the Paraná Basin, southeastern Brazil, typically marked by discontinuity of its lithofacies. Under the exploratory point of view, the unit represents one of the most significant intervals of the basin, since several occurrences of mineral and energetic resources are associated to it, as groundwater, petroleum and coal. The prospection and exploitation of these resources depend on a good understanding of the stratigraphic architecture and the paleogeography. There are many contributions on the specialized literature which deal with this subject, although the regions of Limeira and Piracicaba (superior portion of the unit) still lack new investigations, which may contribute to the understanding of its lithofacies and related sedimentary processes. It was analyzed the sedimentary sets pilling up, followed by stratigraphic correlations between the two regions. Moreover, from sedimentary structures, it was made paleocurrent measurement with the purpose of obtaining indicative patterns of the sedimentary polarity, contributing for the comprehension of the paleogeography. Recent studies in the Domo de Pitanga region (between Rio Claro and Piracicaba cities) and in the Corumbataí river drainage basin, were taken also as basis for possible correlations. It was obtained a frame of the lithofacies arrangement, their vertical and lateral relations, as well as their depositional polarities.

Superfícies geomórficas e variabilidade de latossolos em uma vertente sobre arenito-basalto em Jaboticabal (SP)

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Análise tectono-estratigráfica das sequências permotriassica e jurocretácea da bacia Chacoparanense Uruguaia (Cuenca Norte)

Pós-graduação em Geologia Regional - IGCE

Estratigrafia do vulcanismo mesozóico ácido da província magmática do Paraná

The Paraná Magmatic Province was generated by a large volcanic event occurred in the Lower Cretaceous, it was a phenomenon that preceded the fragmentation of the supercontinent Gondwana. In Brazil the volcanic rocks overlying about 75% of the surface of the Parana basin being the Serra Geral Formation essentially represented by basalts and andesites of tholeiitic nature and subordinate porphyritic rhyodacites, called Chapecó type and aphyric rhyolites, Palms type. Based on the chemical compositions, rocks of Palmas type are subdivided into Santa Maria, Clevelândia, Caxias do Sul, Jacuí and Anita Garibaldi. Rocks of Chapecó type are grouped into three distinct subtypes called Guarapuava, Tamarana and Ourinhos. These acidic rocks that overlying basalts are of two main types: high-Ti (Paranapanema, Pitanga and Urubici) and low-Ti (Gramado, Esmeralda and Ribeira). Representative profiles of these rocks were studied in detail in order to establish the lithostratigraphy and Chemostratigraphy of Palmas and Chapecó type. To do this was made a field work and the use of a database with 1109 samples with their geographical coordinates and geochemical information of major and trace elements, which were launched in maps generated by Google Earth. From these maps, it was verified that rocks of the Palmas type are distributed predominantly in the south region of the basin in the state of Rio Grande do Sul, accumulated along Torres Syncline, while those Chapecó type occur in the plateaus of midwestern Paraná, in this region was observed that Chapecó type overlap those Palmas type. In the profiles studied, within Palmas type, Caxias do Sul type is spread throughout the southern region of the basin, occurring at the base of the acid volcanic sequences, in other words, they are older compared to the others. It was also observed that the rocks of Santa Maria and Anita Garibaldi type occupy the top of the sequences, both covering rocks of Caxias do Sul..

Tuzla City (BiH): an example of geohazard induced by salt extraction

Salt deposits characterize the subsurface of Tuzla (BiH) and made it famous since the ancient times. Archeological discoveries demonstrate the presence of a Neolithic pile-dwelling settlement related to the existence of saltwater springs that contributed to make the most of the area a swampy ground. Since the Roman times, the town is reported as “the City of Salt deposits and Springs”; "tuz" is the Turkish word for salt, as the Ottomans renamed the settlement in the 15th century following their conquest of the medieval Bosnia (Donia and Fine, 1994). Natural brine springs were located everywhere and salt has been evaporated by means of hot charcoals since pre-Roman times. The ancient use of salt was just a small exploitation compared to the massive salt production carried out during the 20th century by means of classical mine methodologies and especially wild brine pumping. In the past salt extraction was practised tapping natural brine springs, while the modern technique consists in about 100 boreholes with pumps tapped to the natural underground brine runs, at an average depth of 400-500 m. The mining operation changed the hydrogeological conditions enabling the downward flow of fresh water causing additional salt dissolution. This process induced severe ground subsidence during the last 60 years reaching up to 10 meters of sinking in the most affected area. Stress and strain of the overlying rocks induced the formation of numerous fractures over a conspicuous area (3 Km2). Consequently serious damages occurred to buildings and infrastructures such as water supply system, sewage networks and power lines. Downtown urban life was compromised by the destruction of more than 2000 buildings that collapsed or needed to be demolished causing the resettlement of about 15000 inhabitants (Tatić, 1979). Recently salt extraction activities have been strongly reduced, but the underground water system is returning to his natural conditions, threatening the flooding of the most collapsed area. During the last 60 years local government developed a monitoring system of the phenomenon, collecting several data about geodetic measurements, amount of brine pumped, piezometry, lithostratigraphy, extension of the salt body and geotechnical parameters. A database was created within a scientific cooperation between the municipality of Tuzla and the city of Rotterdam (D.O.O. Mining Institute Tuzla, 2000). The scientific investigation presented in this dissertation has been financially supported by a cooperation project between the Municipality of Tuzla, The University of Bologna (CIRSA) and the Province of Ravenna. The University of Tuzla (RGGF) gave an important scientific support in particular about the geological and hydrogeological features. Subsidence damage resulting from evaporite dissolution generates substantial losses throughout the world, but the causes are only well understood in a few areas (Gutierrez et al., 2008). The subject of this study is the collapsing phenomenon occurring in Tuzla area with the aim to identify and quantify the several factors involved in the system and their correlations. Tuzla subsidence phenomenon can be defined as geohazard, which represents the consequence of an adverse combination of geological processes and ground conditions precipitated by human activity with the potential to cause harm (Rosenbaum and Culshaw, 2003). Where an hazard induces a risk to a vulnerable element, a risk management process is required. The single factors involved in the subsidence of Tuzla can be considered as hazards. The final objective of this dissertation represents a preliminary risk assessment procedure and guidelines, developed in order to quantify the buildings vulnerability in relation to the overall geohazard that affect the town. The historical available database, never fully processed, have been analyzed by means of geographic information systems and mathematical interpolators (PART I). Modern geomatic applications have been implemented to deeply investigate the most relevant hazards (PART II). In order to monitor and quantify the actual subsidence rates, geodetic GPS technologies have been implemented and 4 survey campaigns have been carried out once a year. Subsidence related fractures system has been identified by means of field surveys and mathematical interpretations of the sinking surface, called curvature analysis. The comparison of mapped and predicted fractures leaded to a better comprehension of the problem. Results confirmed the reliability of fractures identification using curvature analysis applied to sinking data instead of topographic or seismic data. Urban changes evolution has been reconstructed analyzing topographic maps and satellite imageries, identifying the most damaged areas. This part of the investigation was very important for the quantification of buildings vulnerability.

Reservoir characterization of the Cardium Formation in the Ferrier Oilfield, west-central Alberta, Canada.

This thesis has the main aim of defining the lithostratigraphy, depositional architecture, post-depositional modifications and reservoir characteristics of the Cardium Formation in the Ferrier Oilfield, and how these characteristics can have great impact over production rates, GOR and produced fluid discrimination. In the Ferrier area, the Cardium Formation is composed by a NE prograding clastic sequence made up of offshore to shoreface deposits sealed by marine shales. The main reservoir is composed by sandstones and conglomerates interpreted to have deposited in a shoreface depositional environment. Lithofacies and net reservoir thickness mapping led to more detailed understanding of the 3D reservoir architecture, and cross-sections shed light on the Cardium depositional architecture and post-deposition sediment erosion in the Ferrier area. Detailed core logging, thin section, SEM and CL analyses were used to study the mineralogy, texture and pore characterization of the Cardium reservoir, and three main compartments have been identified based on production data and reservoir characteristics. Finally, two situations showing odd production behaviour of the Cardium were resolved. This shed light on the effect of structural features and reservoir quality and thickness over hydrocarbon migration pathways. The Ferrier example offers a unique case of fluid discrimination in clastic reservoirs due both to depositional and post-depositional factors, and could be used as analogue for similar situations in the Western Canadian Sedimentary Basin.

Sedimentary evolution and environmental history of Lake Van (Turkey) over the past 600,000 years

The lithostratigraphic framework of Lake Van, eastern Turkey, has been systematically analysed to document the sedimentary evolution and the environmental history of the lake during the past ca 600,000 years. The lithostratigraphy and chemostratigraphy of a 219 m long drill core from Lake Van serves to separate global climate oscillations from local factors caused by tectonic and volcanic activity. An age model was established based on the climatostratigraphic alignment of chemical and lithological signatures, validated by 40Ar/39Ar ages. The drilled sequence consists of ca 76% lacustrine carbonaceous clayey silt, ca 2% fluvial deposits, ca 17% volcaniclastic deposits and 5% gaps. Six lacustrine lithotypes were separated from the fluvial and event deposits, such as volcaniclastics (ca 300 layers) and graded beds (ca 375 layers), and their depositional environments are documented. These lithotypes are: (i) graded beds frequently intercalated with varved clayey silts reflect rising lake-levels during the terminations; (ii) varved clayey silts reflect strong seasonality and an intralake oxic–anoxic boundary, for example, lake-level highstands during interglacials/interstadials; (iii) CaCO3-rich banded sediments are representative of a lowering of the oxic-anoxic boundary, for example, lake-level decreases during glacial inceptions; (iv) CaCO3-poor banded and mottled clayey silts reflect an oxic–anoxic boundary close to the sediment-water interface, for example, lake-level low-stands during glacials/stadials; (v) diatomaceous muds were deposited during the early beginning of the lake as a fresh water system; and (vi) fluvial sands and gravels indicate the initial flooding of the lake basin. The recurrence of lithologies (i) to (iv) follows the past five glacial/interglacial cycles. A 20 m thick disturbed unit reflects an interval of major tectonic activity in Lake Van at ca 414 ka BP.

Facies investigations on sediment core CRP-3 from the Ross Sea, Antarctica

The Cenozoic Victoria Land Basin (VLB) stratigraphic section penetrated by CRP-3 is mostly of Early Oligocene age. It contains an array of lithofacies comprising fine-grained mudrocks, interlaminated and interbedded mudrocks/sandstones, mud-rich and mud-poor sandstones, conglomerates and diamctites that are together interpreted as the products of shallow marine to possibly non-marine environments of deposition, affected by the periodic advance and retreat of tidewater glaciers. This lithofacies assemblage can be readily rationalised using the facies scheme designed originally for CRP-2/2A, and published previously. The uppermost 330 metres below sea floor (mbsf) shows a cyclical arrangement of lithofacies also similar to that recognised throughout CRP-2/2A, and interpreted to reflect cyclical variations in relative sea-level driven by ice volume fluctuations ('Motif A'). Between 330 and 480 mbsf, a series of less clearly cyclical units, generally fining-upward but nonetheless incorporating a significant subset of the facies assemblage, has been identified and noted in the Initial Report as 'Motif B' Below 480 mbsf, the section is arranged into a repetitive succession of fining-upward units, each of which comprises dolerite clast conglomerate at the base passing upward into relatively thick intervals of sandstones. The cycles present down 480 mbsf are defined as sequences, each interpreted to record cyclical variation of relative sea-level. The thickness distribution of sequences in CRP-3 provides some insights into the geological variables controlling sediment accumulation in the Early Oligocene section. The uppermost part of the section in CRP-3 comprises two or three thick, complete sequences that show a broadly symmetrical arrangement of lithofacies (similar to Sequences 9-11 in CRP-2/2A). This suggests a period of relatively rapid tectonic subsidence, which allowed preservation of the complete facies cycle. Below Sequence 3, however, is a considerable interval of thin, incomplete and erosionally truncated sequences (4-23), which incorporates both the remainder of Motif A sequences and all Motif B sequences recognised. The thinner and more truncated sequences suggest sediment accumulation under conditions of reduced accommodation, and given the lack of evidence for glacial conditions (see Powell et al., this volume) tends to argue for a period of reduced tectonic subsidence. The section below 480 mbsf consists of a series of fining-upward, conglomerate to sandstone intervals which cannot be readily interpreted in terms of relative sea-level change. A relatively mudrock-rich interval above the basal conglomerate/breccia (782-762 mbsf) may record initial flooding of the basin during early rift subsidence. The lithostratigraphy summarised above has been linked to seismic reflection data using depth conversion techniques (Henrys et al., this volume). The three uppermost reflectors ('o', 'p' and 'q') correlate to the package of thick sequences 1-3, and several deeper reflectors can also be correlated to sequence boundaries. The package of thick Sequences 1-3 shows a sheet-like cross-sectional geometry on seismic reflection lines, unlike the similar package recognised in CRP-2/2A.

Potassium and argon concentrations and age determination of ODP Site 125-782 and 125-786

K-Ar whole-rock ages have been obtained for 30 samples from Sites 782 and 786, Ocean Drilling Program Leg 125 in the Izu-Bonin (Ogasawara) forearc region. They form a trimodal spread of ages between 9 Ma and 44 Ma and are, with a few exceptions, consistent with the inferred lithostratigraphy. The ages have been interpreted in terms of at least two distinct episodes of magmatic and/or hydrothermal activity. A group of ten samples, including the lava flows, gave an isochron age of 41.3 ± 0.5 Ma (middle-late Eocene). This is thought to represent the age of the principal magmatic development of the volcanic forearc basement, and is comparable to published ages on equivalent rocks from other parts of the forearc basement high (e.g., the Ogasawara Islands). It may be significant that this age is slightly younger than the timing of major plate reorganization in the Western Pacific at about 43 Ma. This was followed by a minor episode of intrusive magmatism at 34.6 ± 0.7 Ma (early Oligocene) which appears to have reset the ages of some of the earlier units. This event probably corresponds to the initiation of rifting of the "proto-arc" to form the Parece Vela Basin. Boninitic samples were erupted during both episodes of magmatism, the earlier being of low-Ca boninite type and the later being of medium- and high-Ca types. It is also possible that a third episode of intrusive magmatism affected the Izu-Bonin forearc region at both Sites 782 and 786 at about 17 Ma. This would be consistent with magmatic activity elsewhere in the region during the Miocene, associated with the end of active spreading in the Parece Vela Basin and the start of arc activity in the West Mariana Ridge.