271 resultados para CEF3-TB3
Resumo:
Phosphate glasses 60P<inf>2</inf>O<inf>5</inf>-15CS<inf>2</inf>O- 15Al<inf>2</inf>O<inf>3</inf>-10BaO were made by high temperature melt-annealing method. The absorption spectra, excitation spectra and emission spectra of Gd<sup>3+</sup>-Tb<sup>3+</sup> and Ce<inf>3+</inf>-Gd<sup>3+</sup>-Tb<sup>3+</sup> co-doped phosphate glass 60P<inf>2</inf>O<inf>5</inf>-15CS<inf>2</inf>O- 15Al<inf>2</inf>O<inf>3</inf>-10BaO were studied. The experimental results indicate that, the doping of Ce<inf>3+</inf> and Gd<sup>3+</sup> in Tb<sup>3+</sup> phosphate glass has a good effect on the 545 nm emission of Tb<sup>3+</sup> at UV excitation. The Ce<inf>3+</inf>-Gd<sup>3+</sup>-Tb<sup>3+</sup> co-doped phosphate glass have a good x-ray luminescence at the radiation of x-ray with energy in 50-120 kev, and a high space resolution. The Ce<inf>3+</inf>-Gd<sup>3+</sup>-Tb<sup>3+</sup> co-doped phosphate luminescence glass is a promising material for using in the digital radiography system in medical devices.
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The synthesis and optical properties of Y3Al5O12:Tb3+ phosphors are reported in this paper. Y3Al5O12:Tb3+ phosphors were synthesized by a facile solution combustion method. Citric acid traps the constituent cations and also acts as a fuel. Y3Al5O12 (YAG) phase can crystallize through sintering at 900 degrees C for 2 h, and there were no intermediate phases such as YAlO3 (YAP) and Y4Al2O9 (YAM) in the sintering process. The excitation spectra of crystalline Y3Al5O12:Tb3+ are different from that of amorphous one due to the crystal field effect. The emission spectra mainly show D-5(4) -> F-7(6) transition under UV excitation. The higher concentration quenching in Y3Al5O12:Tb3+ nanophosphors may be due to the confinement effect on resonant energy transfer of nanocrystalline. It is also indicated that the solution combustion synthesis method provides a good distribution of Tb3+ activators in Y3Al5O12 host. (c) 2005 Published by Elsevier B.V.
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Tb/Yb
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CePO4:TbCePO4:Tb/LaPO4(/)CePO4CePO4:Tb10-30 nm200 nmCePO4:Tb/LaPO4(/)LaPO42-10 nmCePO4:TbCePO4:Tb/LaPO4(/)Ce3+ (5d - 4f)Tb3+ 5D4-7FJ(J = 6-3)CePO4:TbCePO4:Tb/LaPO4(/)/ (KBF4NaFNH4F)CeF3CeF3UV-VisEuF30.9 m-1.0 m0.14 mEuF3EuF3 CeVO4YVO4:Eu3+ CeVO45 nm150 nmCeVO4(122 m2•g-1)YVO4:Eu3+ 90-150 nm250-300 nmYVO4:EuEu3+ 5D0-7FJ(J = 1- 4)5D0-7F2(614nm)
Resumo:
Without introducing concentration quenching phenomenon, a few wt% of Tb3+ and Yb3+ ions were doped into a group of easily-fiberized tellurite glasses characterized by loose polyhedron structures and rich interstitial positions. Intense green upconversion emission from Tb3+ ions centered at 539 nm due to transition 5D4→7F5 was observed by direct excitation of Yb3+ ions with a laser diode at 976 nm. Optimizing the concentration ratio of Tb3+/Yb3+, a tellurite glass with composition of 80TeO2-10ZnO-10Na2O (mol%)+1.0wt% Tb2O3+3.0wt% Yb2O3 was found to present the highest green light intensity and therefore is especially suitable for efficient green fiber laser development.
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Luminescent Ln (Eu3+, Tb3+) doped hydroxyapatite (Eu:HAp, Tb:HAp) phosphors were successfully fabricated via the cetyltrimethylammonium bromide (CTAB)/n-octane/n-butanol/water microemulsion-mediated solvothermal process. The structure, morphology, and optical properties were systematically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron spectra (XPS), Fourier transform infrared spectroscopy (FT-IR), and photoluminescence (PL) spectra as well as the kinetic decays, respectively.
