978 resultados para 324.66


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Taxonomic observations are given on Dangeardia sporapiculata n. sp. Furthermore the term 'apiculus' and the species limitation of some chytrids are being discussed. It is concluded that the newly described species Dangeardia sporapiculata does not fit satisfactorily into the present system of phlyctidiacee, because their characteristics do not agree exactly with any genus.

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The 66 kilo-Dalton (k-Da) protein split off from the cross linked myosin heavy chain (CMHC) formed due to the setting of Alaska pollack surimi, frozen-storage of Pacific cod flesh, and vinegar-curing of Pacific mackerel mince was identified as a light meromyosin (LMM). Puncture and stress-relaxation tests showed that the actomyosin subunits (AMS) of Alaska pollack surimi, upon setting at 30°C, transformed into gel, although the elasticity of this gel was very low when compared to the gels from surimi or actomyosin (AM). Electrophoretic studies showed that the band due to LMM in the gel from AMS gradually disappeared with the progress of setting but higher molecular weight polymer did not form. The intensity of the bands due to other myosin sub-fragments decreased a little. The findings suggest that at setting temperature, LMM of MHC molecule leads to an unfolding resulting in an intramolecular aggregation through non-covalent interactions, and thus plays a significant role in the crosslinking of MHC.

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During these two seasons investigations were carried out with a view to exploring the possibility of this operation on commercial basis and to study the effect of certain meteorological factors on catch.

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An historical account is given of the development of the Lake Albert fisheries since Worthington's survey in 1928. It is noted that the development of the fisheries was related to, and dependent upon, improvements in the type of gear and canoes, an incFease in the number of canoes and outboard engines in use, improved marketing facilities and better road communications. Summarized data, collected mainly since 1954, has been analysed and tabulated to show annual exports to the Congo, total annual catches 'and annual catches of individual species. A change in the relative abundance of the various species in the annual catches is described. It is noted that this change was caused by a change-over from large to small mesh size gill-nets, and that it was associated with an increased demand within Uganda for the smaller species of fish, such as Aleste's baremose and Hydrocynus forskahlii. A brief description of fish processing and marketing in the Lake Albert region is given, which emphasizes the suitability of salt-cured fish to the social and physical environment of the area. Finally, a summary of a recent survey of the potential fish resources of the lake is given in the discussion, and estimates of the 1965 catch at the north and south ends of the lake are compared with the findings of the survey. This showed that there is little danger of overfishing the Alestes baremose stocks of the Wanseko area at the 1965 rate of exploitation of the species, and that the total catch for 1965 at the south end of the lake was well below the estimated annual sustainable yield from the area.

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The low-temperature heat capacities of 2-chloro-5-trichloromethylpyridine were measured with a high-precision automated adiabatic calorimeter in the temperature range from 80 K to 345 K. A solid-liquid phase transition was observed from 318.57 K to 327.44 K with peak temperature 324.67 K; the molar enthalpy and entropy of phase transition, DeltaH(m) and DeltaS(m), were determined to be 14.50 +/-0.02 kJ mol(-1) and 44.66 +/- 0.07 kJ K-1 mol(-1), respectively. The thermal stability was investigated through thermogravimetric analysis (TG). The TG and DTG results reveal that 2-chloro-5-trichloromethylpyridine starts to lose mass at 332 K due to evaporation and completely changes into vapour at 483 K under the present experimental conditions.

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The crystalline-phase transition in polyamide-66/montmorillonite nanocomposites before melting was investigated by in situ X-ray diffraction and is reported for the first time in this work. The phase-transition temperature in the nanocomposites was 170 degreesC, 20 degreesC lower than that in polyamide-66. The lower phase-transition temperature of the nanocomposites could be attributed to the gamma-phase-favorable environment caused by silicate layers. Meanwhile, the addition of silicate layers changed the crystal structure of the polyamide-66 matrix and influenced the phase-transition behavior.

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The analysis of the small angle X-ray scattering (SAXS) data was based upon particle characteristic function, one-dimensional electron-density correlation function and particle distribution function. The microstructure of nylon 66 with different degrees of crystallinity was studied by means of X-ray scattering method. The radius of gyration R-g, the Porod radius R-p, the thickness of crystalline region L-c the thickness of non-crystalline region L-n, the thickness of interphase region d(tr), the long period L, the semiaxises of particles (a, a, b), the distribution of the particle sizes and the scattering invariant were calculated. The results indicate that there was a significant interphase region between the crystalline region and the non-crystalline region. and its content (W-t,W-x) should not be neglected in comparison with that of crystalline region W-c,W-x. The morphology of nylon 66 prepared by isothermal crystallization at a high temperature was mainly a lamellar structure, while the spherical crystals dominated in the quenched sample. The size of the particles in the quenched sample was smaller than that of those in the isothermally crystallized sample. and the distribution of the particle sizes in the isothermally crystallized sample was wider.

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Analysis of isothermal and nonisothermal crystallization kinetics of nylon 66 was carried out using differential scanning calorimetry (DSC). The commonly used Avrami equation and that modified by Jeziorny were used, respectively, to fit the primary stage of isothermal and nonisothermal crystallizations of nylon 66. In the isothermal crystallization process, mechanisms of spherulitic nucleation and growth were discussed. The lateral and folding surface free energies determined from the Lauritzen-Hoffman treatment are sigma = 9.77 erg/cm(2) and sigma (e) = 155.48 erg/cm(2), respectively; and the work of chain folding is q = 33.14 kJ/mol. The nonisothermal crystallization kinetics of nylon 66 was analyzed by using the Mo method combined with the Avrami and Ozawa equations. The average Avrami exponent (n) over bar was determined to be 3.45. The activation energies (DeltaE) were determined to be -485.45 kJ/mol and -331.27 kJ/mol, respectively, for the isothermal and nonisothermal crystallization processes by the Arrhenius and the Kissinger methods.

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用红外光谱法研究了Pa1010/66共聚物氢键含量、N-H键伸缩振动力常数分布与组成的关系,发现66盐重量含量为40%时氢键含量最低,N-H伸缩振动力常数分布最宽,解释了PA1010/66共聚物热力学、结晶、机械等性能随组成改变而变化的原因.