908 resultados para 16:1(n-7) 16:1(n-5) 20:5(n-3)
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Thermal rearrangement of diethylamino5-(m methoxyphenoxy)-pent-2-yne (3) gives 1-(m-methexyphenoxy)-pent-3,4-diene (14) in about 8% yield. Hydration of the latter yields 1-(m-methoxyphenoxy)-pentan-4-one (6), which has been synthesised by an unambiguous route. A mechanism of formation of the allene (14) from the amine (3) has been suggested.
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The dielectric response of pulsed laser ablated Bi-1 Zn-5(1) Nb-0(1) O-5(7) (BZN) thin films are investigated within the temperature range of 300-660 K and frequency range of 100 Hz-100 kHz Thin film exhibited a strong dielectric relaxation behavior A sharp rise in dielectric constant of BZN thin film at high temperatures is related to disorder in canon and anion lattices Observed dielectric relaxation implies a redistribution of charges within the unit cell This phenomenon suggests that the large change in dielectric constant is due to a dynamical rise of dipolar fluctuations in the unit cell XPS spectra of BZN (A(2)B(2)O(6)O') cubic pyrochlore confirm that the relaxation corresponds to the ionic hopping among the A and O' positions of several local potential minima Barrier height for hopping is distributed between 0 and 0 94 eV The O is spectrum confirms presence of two types of oxygen in BZN thin film The disorder in charge neutralized thin film is correlated with XPS spectra (C) 2010 Elsevier Ltd All rights reserved
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Methyl 5,6-Bis(2-methoxyphenyt)-1,4-dimethyl-7-oxobicyclo[2.2.1]hept-5-en-2-endo-carboxylate, a moderately crowded norbornenone ester, exhibits complex VT-DNMR behaviour. A similar behaviour is not seen in its 7-oxa analogue, showing that conformational transmission from position 7 has a crucial influence on the distance parameters that govern the dynamic processes involving the substituents on the bicycloheptene framework.
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An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundantly available monoterpene (R)-limonene is described. A combination of Claisen rearrangement-intramolecular diazo-ketone cyclopropanation-regiospecific reductive cyclopropane cleavage reactions are employed for the stereo- and regiospecific generation of the two vicinal ring junction quaternary carbon atoms.
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One-dimensional X-1-Y2SiO5:Ce3+ and -Tb3+ nanofibers and quasi-one-dimensional X-1-Y2SiO5:Ce3+ and -Tb3+ microbelts have been prepared by a simple and cost-effective electrospinning process. X-ray powder diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy (SEM), energy-dispersive X-ray spectrometry, transmission electron microscopy, high-resolution transmission electron microscopy, photoluminescence (PL), and cathodoluminescence spectra were used to characterize the samples. SEM results indicate that the as-prepared fibers and belts are smooth and uniform with a length of several tens to hundreds of micrometers, whose diameters decrease after being annealed at 1000 degrees C for 3 h. Under ultraviolet excitation and low-voltage electron beam excitation, the doped rare earth ions show their characteristic emission, that is, Ce3+ 5d-4f and Tb3+ D-5(4)-F-7(J) (J = 6, 5 4, 3) transitions, respectively.
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Electroluminescence (EL) devices with Eu(HTH)(3)phen [HTH: 4,4,5,5,6,6,6-heptafluoro-1-(2-thienyl)-1,3-hexanedione, phen: I 10-phenanthroline] as an emissive centre were fabricated using vacuum evaporation. In addition to the Eu3+ 5D0 --> F-7(J) (J = 0-4) lines that were visible in the photoluminescence signal, the device also showed strong emission from the D-5(1) --> F-7(J) (J = 0-4) transitions. The enhanced emission from the D-5(1) F-7(J) (J = 0-4) transitions was attributed to the increased excitation intensity in the EL device. The luminescence lifetimes of the 5 D, and 5 Do levels were measured to be 0.6 mus and 866 mus, respectively.
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The effect of La/Ce ratio on the structure and electrochemical characteristics of the La0.7-xCexMg0.3Ni2.8Co0.5 (x = 0.1, 0.2, 0.3, 0.4, 0.5) alloys has been studied systematically. The result of the Rietveld analyses shows that, except for small amount of impurity phases including LaNi and LaNi2, all these alloys mainly consist of two phases: the La(La, Mg)(2)Ni-9 phase with the rhombohedral PuNi3-type structure and the LaNi5 phase with the hexagonal CaCU5-type structure. The abundance of the La(La, Mg)(2)Ni-9 phase decreases with increasing cerium content whereas the LaNi5 phase increases with increasing Ce content, moreover, both the a and cell volumes of the two phases decrease with the increase of Ce content. The maximum discharge capacity decreases from 367.5 mAh g(-1) (x = 0.1) to 68.3 mAh g(-1) (x = 0.5) but the cycling life gradually improve. As the discharge current density is 1200 mA g(-1), the HRD increases from 55.4% (x = 0.1) to 67.5% (x = 0.3) and then decreases to 52.1% (x = 0.5). The cell volume reduction with increasing x is detrimental to hydrogen diffusion D and accordingly decreases the low temperature dischargeability of the La0.7-xCexMg0.3Ni2.8Co0.5 (x = 0.1-0.5) alloy electrodes.
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A novel dianhydride, 3,3'-dioxo-[1,1']-spirodiphthalan-5,5',6,6'-tetracarboxlic dianhydride, was synthesized and used as a monomer to prepare polyimides with several diamines via a conventional two-stage procedure. The intermediate poly(amic-acid)s had inherent viscosities of 0.84-1.71 dL/g and could be thermally converted into lightly yellow, transparent, flexible and tough films. Films cast from chemically imidized polyimides were transparent and colorless. The glass transition temperatures (Tg) were > 400 degrees C, and the 5% weight-loss temperatures were > 420 degrees C in N-2 and in air. The solubilities of these polyimides in various solvents were evaluated. The mechanical properties of some polyimides were also tested. (C) 1999 Elsevier Science Ltd. All rights reserved.
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C16H15Br2O7.5, orthorhombic, P2(1)2(1)2 (no. 18), a = 18.483(2) angstrom, b = 9.413(1) angstrom, c = 10.072(1) angstrom, V = 1752.3 angstrom(3), Z = 4, R-gt(F) = 0.083, wR(ref)(F-2) = 0.202, T= 293 K.
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Larthrose (OA) est une maladie dgnrative et multifactorielle caractrise par une destruction de cartilage, une formation dostophytes et une inflammation au niveau de la membrane synoviale. Le 4-hydroxynonnal (HNE), un produit final de la peroxydation lipidique, a t identifi rcemment comme un facteur catabolique et un mdiateur inflammatoire dans le cartilage arthrosique humain. Notre projet vise tudier leffet du HNE sur la rgulation de la prostaglandine E2 synthase-1 microsomale (mPGES-1) et de la protine activante 5-lipoxygnase (FLAP)/5-lipoxygnase (5-LOX) dans les chondrocytes arthrosiques humains. Lorsque les cellules sont traites une seule fois avec 10 M HNE, les rsultats de Western blot et de PCR en temps rel montrent que lexpression de la cyclooxygnase-2 (COX-2) et de la mPGES-1 augmente de manire significative et atteint respectivement le maximum aprs 8 et 16 heures dincubation puis diminue graduellement. Cependant, lorsque les cellules sont traites plusieurs fois avec 10 M HNE 2 heures dintervalle, lexpression de la COX-2 et de la mPGES-1 augmente en fonction du temps sans subir une baisse aprs 24 heures dincubation. Le HNE induit lactivit du promoteur de la mPGES-1 via lactivation du facteur de transcription Egr-1. Linvestigation de la 2me voie du mtabolisme de lacide arachidonique, savoir 5-LOX/FLAP, montre que le HNE induit lexpression de FLAP aprs 24 heures de stimulation et celle de 5-LOX seulement aprs 48 heures. Ceci semble survenir ltape de transcription au cours de laquelle HNE induit lexpression de lARNm et lactivit du promoteur du gne 5-LOX. Nous avons dmontr aussi que le niveau de leukotrine B4 (LTB4) augmente et suit le mme profil que celui de la 5-LOX. Ltude des mcanismes molculaires susceptibles dtre impliqus dans la rgulation de la 5-LOX/FLAP par le HNE montre que ce dernier stimule leur expression via laction de prostaglandine E2 (PGE2) et du facteur de croissance transformant-beta 1 (TGF-1). En conclusion, notre tude dmontre que le HNE induit court-terme dincubation la voie de COX-2/mPGES-1 puis par la suite stimule celle de FLAP/5-LOX long-terme dincubation dans les chondrocytes arthrosiques humains. Ces rsultats suggrent que la mPGES-1 et 5-LOX/FLAP sont des potentielles cibles thrapeutiques intressantes pour contrler la production de PGE2 et LTB4 dans OA.
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Metathesis reactions were used to prepare a range of dicopper(II), monocopper(I), diruthenium(II, III), dimolybdenum(II,II) and dirhodium(II,II) complexes of either racemic or resolved forms of endo- and exo-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid (C7H9CO2H). The X-ray crystal structure of [Cu2{()-endo--O2CC7H9}4(CH3OH)2]2CH3OH shows the two copper(II) ions bridged by two (+)-endo-bicyclo[2.2.1]hept-5-ene-2-carboxylate anions and two ()-endo-bicyclo[2.2.1]hept-5-ene-2-carboxylate anions. Methanol molecules occupy the two trans axial sites, and there are also two methanol molecules hydrogen bonded to opposite carboxyl oxygens.
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The presence of paramagnetic species in the aqueous ring opening metathesis polymerizations of the exo,exo-7-oxabicyclo[2.2.1]hept-5-ene-2,3-dicarboxylic acid monomer with RuCl(3) and K(2)[RuCl(5)H(2)O] compounds was studied using ESR techniques. It was observed that the intensities of the Ru(III) signals in the ESR spectra decrease on the time scale of the induction period so that the ROMP can take place. The intensity of the Ru(III) signal almost disappeared 50 min after reacting with K(2)[RuCl(5)H(2)O] and after 100 mm in the case of RuCl(3). Reactions of the cis-[Ru(NH(3))(4)(H(2)O)(2)](tfms)(3) and [Ru(NH(3))(5)H(2)O](tfms)(3) complexes with the monomer and different organic compounds representing the organic functions in the monomer (furan, norbornene, but-2-ene-1,4-diol and formic, acetic, oxalic and maleic acids) were also monitored by ESR and UV/vis spectra. It was deduced that the organic acids provide the disappearance of the Ru(III) signal. The proton NMR relaxation times of the residual water in D(2)O for reactions with oxalic acid suggested that the presence of paramagnetic ions in the solution decreases along with
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A newsletter published periodically to keep the faculty, students, staff, and community informed about the activities taking place on the campus of LaGuardia Community College. Cover article: SONY SHIFT SCHEDULED SOON, SPOKESMAN SAYS. Other entries include: CUNY TEACHING EXCELLENCE AWARD TO PROFESSOR MILLER; CHILD CARE LEAVE ADOPTED BY BHE; NINETY SENIOR CITIZENS RECEIVE CERTIFICATES; COLLEGE COMMENCEMENT TO BE HELD AT QUEENS COLLEGE AUDITORIUM; DEAN PALMER TO SING AT SEPT. 16, COMMENCEMENT; FOUR MORE PARAPROFESSIONALS COMPLETE DEGREES.
