Geochemistry of carbonate cements of ODP Leg 112 samples

The evolution of pore fluids migrating through the forearc basins, continental massif, and accretionary prism of the Peru margin is recorded in the sequence of carbonate cements filling intergranular and fracture porosities. Petrographic, mineralogic, and isotopic analyses were obtained from cemented clastic sediments and tectonic breccias recovered during Leg 112 drilling. Microbial decomposition of the organic-rich upwelling facies occurs during early marine diagenesis, initially by sulfate-reduction mechanisms in the shallow subsurface, succeeded by carbonate reduction at depth. Microcrystalline, authigenic cements formed in the sulfate-reduction zone are 13C-depleted (to -20.1 per mil PDB), and those formed in the carbonate-reduction zone are 13C-enriched (to +19.0 per mil PDB). Calcium-rich dolomites and near-stoichiometric dolomites having uniformly heavy d18O values (+2.7 to +6.6 per mil PDB) are typical organic decomposition products. Quaternary marine dolomites from continental-shelf environments exhibit the strongest sulfate-reduction signatures, suggesting that Pleistocene sea-level fluctuations created a more oxygenated water column, caused periodic winnowing of the sediment floor, and expanded the subsurface penetration of marine sulfate. We have tentatively identified four exotic cement types precipitated from advected fluids and derived from the following diagenetic environments: (1) meteoric recharge, (2) basalt alteration, (3) seafloor venting and (4) hypersaline concentration. Coarsely crystalline, low-magnesium (Lo-Mg) calcite cements having pendant and blocky-spar morphologies, extremely negative d18O values (to -7.5 per mil PDB), and intermediate d13C values (-0.4 per mil to +4.6 per mil PDB) are found in shallow-marine Eocene strata. These cements are evidently products of meteoric diagenesis following subaerial emergence during late Eocene orogenic movements, although the strata have since subsided to greater than 4,000 m below sea level. Lo-Mg calcite cements filling scaly fabrics in the late Miocene accretionary prism sediments are apparently derived from fluids having lowered magnesium/calcium (Mg/Ca) and 18O/16O ratios; such fluids may have reacted with the subducting oceanic crust and ascended through the forearc along shallow-dipping thrust faults. Micritic, high-magnesium (Hi-Mg) calcite cements having extremely depleted d13C values (to -37.3%c PDB), and a benthic fauna of giant clams (Calyptogena sp.) supported by a symbiotic, chemoautotrophic metabolism, provide evidence for venting of methane-charged waters at the seafloor. Enriched d18O values (to +6.6%c PDB) in micritic dolomites from the continental shelf may be derived from hypersaline fluids that were concentrated in restricted lagoons behind an outer-shelf basement ridge, reactivated during late Miocene orogenesis.

Tertiary and Quaternary calcareous nannoplankton biostratigraphy of ODP Leg 112 holes

Positions of all cores recovered during Ocean Drilling Program (ODP) Leg 112 off Peru are shown in the standard calcareous nannoplankton zonation. Stratigraphic and regional occurrences and preservation of calcareous nannoplankton are discussed for all sites, and fossil lists are presented for selected samples. Late Miocene to Holocene nannoplankton assemblages in the upwelling systems off Peru and scattered blooms, especially of Gephyrocapsa species and Helicosphaera carteri, are described. Scyphosphaera assemblages found in late Miocene Zone NN9 {Discoaster hamatus Zone) at Site 684 are compared with similar assemblages from Gabon on the west coast of Africa. Remarkable subsidence is indicated by early and middle Eocene nearshore and shallow-water nannoplankton assemblages for Sites 682, 683, and 688. Besides several local hiatuses, major regional hiatuses were noted at Site 682 (upper Eocene, uppermost middle Eocene, and part of the lower and middle Oligocene missing), Site 683 (uppermost middle Eocene to lower part of the middle Miocene missing), and Site 688 (part of the middle Eocene, uppermost middle Eocene to upper Oligocene, and parts of the lower and middle Miocene missing).

Quaternary through early Eocene benthic foraminifera off Peru

Stratigraphic assemblages of Quaternary through early Eocene benthic foraminifers were recovered among 10 Peru margin drill sites. Various hiatuses and intervals barren in foraminifers characterize the sections, but numerous samples contain abundant, well-preserved benthic foraminifers. Bathymetry of the extant species and California-based estimates of the paleobathymetry of the extinct species permit recognition of Quaternary sea-level fluctuations between shelf and upper bathyal depths that produced vertical migrations of oxygenated and low-oxygen habitats at the six shallow sites. Assemblages from lower-slope sites at about 9° and 11°S indicate a general subsidence of the continental margin from shelf or upper bathyal depths in Eocene time to the present lower bathyal depths. Data from 11°S suggest a major part of this subsidence occurred in late Oligocene to early Miocene time. Downslope-transported shelf specimens, particularly the small biserial species, Bolivina costata and B. vaughani, are major contributors to these lower bathyal assemblages from the middle Miocene through Quaternary time.

Eocene through Pleistocene planktonic foraminifera off Peru

Planktonic foraminifers were studied from 213 samples collected during Leg 112 at 10 sites located on the continental shelf and slope off Peru. Because planktonic foraminifers occur discontinuously downcore, detailed biostratigraphic zonation was not defined. However, it was possible to distinguish early and middle Eocene, early and late Miocene, Pliocene, and Pleistocene sediments on the basis of the planktonic foraminifers. The oldest sediments of Zone P6 of early Eocene age were obtained from the basal part of Hole 688E, which was penetrated to 779.0 m below seafloor (bsf). A biosiliceous facies of the area predominates above the N6-N7 zonal interval of early Miocene age. All sites are within the present coastal upwelling area off Peru, and many of the late Pliocene and Pleistocene assemblages are similar to those that are characteristic of modern upwelling areas. The core samples differ, however, by having a predominance of cold-water elements, such as Neogloboquadrina incompta and N. pachyderma. Warm-water species are prevalent at some horizons in the cores, suggesting shifts of the coastal upwelling centers or warmer climatic events.

Volcanic ash from the Peru continental margin

During Leg 112 off Peru, volcanic material was recorded from middle Eocene to Holocene time. The petrographical and chemical composition of tephra is consistent with an origin from the Andean volcanic arc. The amount and thickness of ash layers provide valuable evidence for explosive volcanic episodicity. The first indication of volcanism was found in mid-Eocene sediments. Three volcanic pulses date from Miocene time. Two intense episodes took place in upper Pliocene and from Pleistocene to Holocene time. Pliocene-Pleistocene tephra are restricted to the southern upper-slope and shelf sites, indicating a removal of the volcanic arc and the extinction of the northern Peru volcanoes. The Cenozoic tectonic phases of the Andean margin may be correlated with the Leg 112 volcanic records. The explosive supply of evolved magmatic products succeeded the Incaic and Quechua tectonic phases. Acidic glasses are related to both andesitic and shoshonitic series. The calc-alkaline factor (CAF) of these glasses exhibited moderate magmatic variations during middle and late Miocene time. A dramatic change occurred during the Pliocene-Pleistocene, reflected in a strong CAF increase and the appearance of potassium-rich evolved shoshonitic glasses. This took place when the Nazca Ridge subduction began. This change in the magma genesis and/or differentiation conditions is probably related to thickening of the upper continental plate and to a new configuration of the Benioff Zone.

Temperature and d18O measurements from different ODP Sites at the shelf and upper slope of the Peru Margin

The first experimentally determined temperature dependent oxygen-18 fractionation factor between dolomite and water at low temperatures [Vasconcelos et al. 1995 doi:10.1130/G20992.1] allows now the precise calculation of temperatures during early diagenetic dolomite precipitation. We use d18O values of early diagenetic dolomite beds sampled during ODP Legs 112 and 201 on the Peru continental margin (Sites 1227, 1228 and 1229) [Meister et al. 2007, doi:10.1111/j.1365-3091.2007.00870.x] to calculate paleo-porewater temperatures at the time of dolomite precipitation. We assumed unaltered seawater d18O values in the porewater, which is supported by d18O values of the modern porewater presented in this study. The dolomite layers in the Pleistocene part of the sedimentary columns showed oxygen isotope temperatures up to 5 °C lower than today. Since Sites 1228 and 1229 are located at 150 and 250 m below sealevel, respectively, their paleo-porewater temperatures would be influenced by considerably colder surface water during glacial sealevel lowstands. Thus, Pleistocene dolomite layers in the Peru Continental margin probably formed during glacial times. This finding is consistent with a model for dolomite precipitation in the Peru Margin recently discussed by Meister et al. [Meister et al. 2007, doi:10.1111/j.1365-3091.2007.00870.x], where dolomite forms episodically at the sulphate methane interface. It was shown that the sulphate methane interface migrates upwards and downwards within the sedimentary column, but dolomite layers may only form when the sulphate-methane interface stays at a fixed depth for a sufficient amount of time. We hypothesize that the sulphate-methane interface persists within TOC-rich interglacial sediments, while this zone is buried by TOC-poor sedimentation during glacial times. Thus, the presented oxygen isotope data provide additional information on the timing of early diagenetic dolomite formation and a possible link between episodicity in dolomite formation and sealevel variations. A similar link between early diagenesis and oceanography may also explain spacing of dolomite layers in a Milankovitch type pattern observed in the geological record, such as in the Miocene Monterey Formation.

Heat-flow studies in the Peru Trench subduction zone

New heat-flow values were obtained in the central Peru Trench area during site surveys and drilling of Ocean Drilling Program (ODP) Leg 112 by measuring temperatures with ordinary surface heat-flow probes and in the drill holes and by estimating from bottom-simulating reflectors resulting from gas hydrates. The values determined by these methods are consistent with each other within the limits of error. When combined with existing data, heat-flow distribution from the trench to the coast was delineated. Heat flow is lower than 40 mW/m**2 at the bottom of the trench and 40 to 50 mW/m**2 on the landward slope. The low heat flow at the trench bottom can be explained partly by a high sedimentation rate. Heat flow is variable about where the Mendana Fracture Zone meets the trench. This low heat flow might result from hydrothermal circulation in the fracture zone, which some scientists believe is a new propagating rift. On the landward slope, no significant difference in heat flow is recognized between the northern side and the southern side of the fracture zone, in spite of differences in the age of the subducting plate and the tectonic history. Heat flow on the landward slope may be slightly higher than that in most other subduction zones.