Uber basische Derivate von 1-Phenyl-3-methyl-4-azobenzol und 4-azobenzolsulfosaure-5-chlorpyrazol /

Thesis (doctoral)--Universitat Rostock, 1906.

Zur kenntnis des 1-phenyl-3-methyl-4-dimethyl-5-pyrazolons.

Thesis (doctoral)--

Uber (1)-phenyl-(3)-methyl-(4)-nitro-(5)-pyrazolon und (1)-phen...

Thesis (doctoral)--

Ueber das 1-Phenetyl-3 Methyl-5 Chlorpyrazol und einige Derivate Desselben /

Thesis (doctoral)--Universität Rostock, 1903.

Uber das 1 phenyl-3 essigsaure-5 pyrazolon und dessen derivate.

Thesis (doctoral)--

Uber phosphorhaltige derivate des 1-phenyl-3-methyl-pyrazols.

Thesis (doctoral)--

Ueber die Einwirkung von Natrium und Alkohol auf Antipyrin, Methylantipyrin und (1)Phenyl(3)methyl(4)dimethylpyrazolon /

Thesis (doctoral)--Universität Jena, 1896.

Analysis of the monosaccharide composition of fucoidan by precolumn derivation HPLC

We developed an HPLC method for analysis of the monosaccharide composition of fucoidans. The fucoidan was hydrolyzed into monosaccharides with 2 mol/L trifluoroacetic acid. Using ribose as the internal standard, the monosaccharide derivatives, obtained with 1-Phenyl-3-methyl-5-pyrazolone (PMP), were separated by reverse-phase HPLC using a gradient elution process, and monitored by ultraviolet detection at 245 nm. In the concentration range of 0.1-2.0 mmol/L, the peak area of each monosaccharide had a good linear relationship with its concentration (r(2)> 0.998). The average recoveries of mannose, rhamnose, glucuronic acid, glucose, galactose, xylose, and fucose were 86.2%, 95.1%, 62.5%, 102.0%, 94.8%, 66.6%, and 105.1%, respectively. This method was accurate and had good reproducibility and could be used to determine the monosaccharide contents of fucoidans.

3-Methyl-5-phenyl-1-(3-phenylisoquinolin-1-yl)-1H-pyrazole

The title compound, C25H19N3, is composed of an aryl-substituted pyrazole ring connected to an aryl-substituted isoquinoline ring system with a dihedral angle of 52.7 (1)degrees between the pyrazole ring and the isoquinoline ring system. The dihedral angle between the pyrazole ring and the phenyl ring attached to it is 27.4 (1)degrees and the dihedral angle between the isoquinoline ring system and the phenyl ring attached to it is 19.6 (1)degrees.

Ueber das 1-phenyl-2-propyl-3-methyl-5-pyrazolon.

Thesis (doctoral)--

3,3,6,6-Tetramethyl-9-phenyl-3,4,5,6-tetrahydro-9H-xanthene-1,8(2H,7H)-dione

In the title compound, C23H26O3, the three six-membered rings of the xanthene system are non-planar, having total puckering amplitudes, QT, of 0.443 (2), 0.202 (2) and 0.449 (2) Å. The central ring adopts a boat conformation and the outer rings adopt sofa conformations. The crystal structure is stabilized by van der Waals interactions.

Uber 1-Ortho und Paratolyl-3-Methyl-5-Aminopyrazol und die entsprechenden Iminopyrine /

Thesis (doctoral)--Universitat Rostock, 1906.

Ueber das 1 phenyl-, 3 ma=ethyl-, 4 amino-, 5 chlorpyrazol.

Thesis (doctoral)--