Oxygen and carbon isotopes for foraminifers at DSDP Leg 73 Holes

We carried out oxygen and carbon isotope studies on monospecific foraminifer samples from DSDP Sites 522, 523, and 524 of Leg 73 in the central South Atlantic Ocean. The oxygen isotope ratios show a warming of 2 to 3 °C in bottom water and 5°C in surface water during the Paleocene and early Eocene. The carbon isotope values indicate strong upwelling during the early Eocene. The 1% increase in the d18O values of benthic and planktonic foraminifers at Site 523 in the later middle Eocene we ascribe to changes in the pattern of the evaporation and precipitation. The changes may be due to the worldwide Lutetian transgression. The oxygen ratios for the benthic and planktonic foraminifers indicate a cooling at the Eocene/Oligocene transition. The maximum temperature drop (5°C for benthic and 3°C for planktonic foraminifers) is recorded slightly beyond the Eocene/Oligocene boundary and took place over an interval of about 100,000 yr. The pattern of currents in the Southern Hemisphere was mainly structured by a precursor of the subtropical convergence during the Paleocene to late Eocene. The cooling at the Eocene/Oligocene transition led to drastic changes in the circulation pattern, and a precursor of the Antarctic convergence evolved.

Calculated surface water paleotemperatures for the lower Pliocene at DSDP Site 18-173 from the California continental slope (Table I)

The oxygen isotope record of the planktonic foraminifera Globigerina bulloides and Neogloboquadrina pachyderma from Pliocene and early Pleistocene sediments at both DSDP site 173 and the Centerville Beach section in California suggests a large influx of isotopically light water in this area during late Pliocene and early Pleistocene time. Salinity may have been reduced by as much as 2 to 4 ?. Surface sea water paleotemperatures for the lower Pliocene range from 9.5°C to 15.5°C. The oxygen isotope record of the benthonic genus Uvigerina shows little variation indicating environmental stability at depth. At DSDP site 173 the small variation in Uvigerina is due to variation in the oxygen isotopic composition of the oceans as glaciers waxed and waned. At the Centerville Beach section the oxygen isotopic composition of Uvigerina reflects the gradual shoaling of the Humboldt Basin. Carbon and oxygen isotope ratios in G. bulloides and N. pachyderma are inversely correlated at the 95% confidence level. This may indicate that the oxygen and carbon isotopic composition of foraminifera are influenced by the same factors. On the other hand, the inverse correlation may be due to metabolic fractionation. No correlation was found between oxygen and carbon isotopic composition in Uvigerina.

Age profiles and isotopes d18O and d13C in Globigerina angiporoides and Oridorsalis umbonatus at DSDP Site 90-593 and Holes 12-111, 29-277 and 90-592

The late Eocene through earliest Miocene stable-isotope composition of southwest Pacific microfossils has been examined in a traverse of high-quality sedimentary sequences ranging from subantarctic (DSDP Site 277) through temperate regions (DSDP Sites 592 and 593). Changes in oxygen-isotope values, measured in benthic and planktonic foraminifers, document the Oligocene development and strengthening of latitudinal thermal zonation from water masses with broad temperature gradients during the Eocene to the steeper gradients and more distinct latitudinally distributed surface water-mass belts of the Neogene. The oxygen-isotope records can be divided into three intervals: late Eocene, early Oligocene, and middle to late Oligocene. Each interval represents a successive stage in the evolution of latitudinal thermal gradients between subantarctic and temperate regions in the Southern Hemisphere. During the late Eocene, oxygen-isotope values at subantarctic Site 277 were similar to those at temperate Sites 592 and 593. The isotope values suggest that, although the inferred paleotemperatures at Site 277 are slightly cooler on average than those at the temperate sites, there is no evidence for a major thermal boundary between the regions at this time. All three sites record the well-known oxygen-isotope enrichment of about 1 per mil in both planktonic and benthic foraminifers in close association with the Eocene/Oligocene boundary. In contrast to the earliest Oligocene enrichments in the planktonic and benthic oxygen-isotope composition at Site 277, more northern Sites 592 and 593 exhibit a depletion through the early-middle Oligocene. This documents the beginning of thermal segregation as subantarctic waters cooled relative to those at temperate latitudes. During the Oligocene, this surface-water differentiation continued, as measured by planktonic d18O values. The oxygen-isotope records of the benthic foraminifers also began to diverge in the earliest Oligocene. The most enriched oxygen-isotope values in all records cluster in the middle Oligocene, marked by oscillating episodes of enrichments >0.5 per mil occurring most prominently in the subantarctic record of Site 277. These values can be interpreted as recording either the coldest oceanic temperatures of the Paleogene and/or accumulations of Antarctic ice. After this interval, latitudinal thermal differentiation developed rapidly during the middle Oligocene, especially in the surface waters which actually warmed in temperate areas. If the enriched Oligocene oxygen-isotope values indicate that ice had accumulated, this ice must have disappeared by the early Miocene, when depleted oxygen-isotope values suggest very warm conditions. The data presented in this chapter document the progressive increase of latitudinal temperature gradients from the late Eocene through the late Oligocene. This pattern of increasing isotopic offset between latitudinally distributed southwest Pacific sites is linked to the establishment and strengthening of the Circum-Antarctic Current, previously considered to have developed during the middle to late Oligocene. The intensification of this current system progressively decoupled the warm subtropical gyres from cool polar circulation, in turn leading to increased Antarctic glaciation.

Thorium and uranium isotopes in upper Pleistocene sediments of the Baffin Bay

Concentrations and activity ratios of uranium and thorium isotopes (234U/238U, 230Th/232Th) were determined at about 5-m intervals through the composite top 22-m sequence of Ocean Drilling Program (ODP) Hole 645 in Baffin Bay and, in the Labrador Sea, at 1-m intervals through the top 11 m of Core 84-030-003 (TWC and P) collected by the Hudson during a preliminary survey of Site 647, and also at about 2-m intervals through the composite top 22-m sequence of Hole 646. In the Labrador Sea, surficial sediments show unsupported 230Th having a 230Th/234U activity ratio of about 3. At Site 647, a regular decrease in the 230Th/232Th activity ratio was observed downcore from about 1.2 (at 1 mbsf) to about 0.4 (at ~8 mbsf), through a sequence spanning over 18O stages 2 through 8. The correlative thorium/uranium chronology and 18O stratigraphy indicate relatively constant sedimentation rates throughout the sequence. At Site 646, down Greenland slope, and at Site 645, in Baffin Bay, highly variable uranium and thorium concentrations and isotopic ratios were observed in relation to highly variable sedimentation rates. As a whole, the lower-excess observed in Baffin Bay records is indicative of very high absolute sedimentation rates in comparison with those of the Labrador Sea. These rates are confirmed by the 18O-stratigraphy and a few AMS 14C controls on handpicked foraminifers. At both Labrador Sea sites, a clear indication of an initial 230Th-excess (over the 230Th-rain from the water column) was found.

Stable Isotope composition of particulate organic matter and fauna in a deep Mediterranean cold-water coral bank

Cold-water corals (CWC) are frequently reported from deep sites with locally accelerated currents that enhance seabed food particle supply. Moreover, zooplankton likely account for ecologically important prey items, but their contribution to CWC diet remains unquantified. We investigated the benthic food web structure of the recently discovered Santa Maria di Leuca (SML) CWC province (300 to 1100 m depth) located in the oligotrophic northern Ionian Sea. We analyzed stable isotopes (delta13C and delta15N) of the main consumers (including ubiquitous CWC species) exhibiting different feeding strategies, zooplankton, suspended particulate organic matter (POM) and sedimented organic matter (SOM). Zooplankton and POM were collected 3 m above the coral colonies in order to assess their relative contributions to CWC diet. The delta15N of the scleractinians Desmophyllum dianthus, Madrepora oculata and Lophelia pertusa and the gorgonian Paramuricea cf. macrospinawere consistent with a diet mainly composed of zooplankton. The antipatharian Leiopathes glaberrima was more 15N- depletedthan other cnidarians, suggesting a lower contribution of zooplankton to its diet. Our delta13C data clearly indicate that the benthic food web of SML is exclusively fuelled by carbon of phytoplanktonic origin. Nevertheless, consumers feeding at the water sediment interface were more 13C-enriched than consumers feeding above the bottom (i.e. living corals and their epifauna). This pattern suggests that carbon is assimilated via 2 trophic pathways: relatively fresh phytoplanktonic production for 13C-depleted consumers and more decayed organic matter for 13C-enriched consumers. When the delta13C values of consumers were corrected for the influence of lipids (which are significantly 13C-depleted relative to other tissue components), our conclusions remained unchanged, except in the case of L. glaberrima which could assimilate a mixture of zooplankton and resuspended decayed organic matter.

Neodymium isotopes in benthic foraminifera from the South Atlantic

Records of the past neodymium (Nd) isotope composition of the deep ocean can resolve ambiguities in the interpretation of other tracers. We present the first Nd isotope data for sedimentary benthic foraminifera. Comparison of the epsilon-Nd of core-top foraminifera from a depth transect on the Cape Basin side of the Walvis Ridge to published seawater data, and to the modern dissolved SiO2- epsilon-Nd trend of the deep Atlantic, suggests that benthic foraminifera represent a reliable archive of the deep water Nd isotope composition. Neodymium isotope values of benthic foraminifera from ODP Site 1264A (Angola Basin side of the Walvis Ridge) from the last 8 Ma agree with Fe-Mn oxide coatings from the same samples and are also broadly consistent with existing fish teeth data for the deep South Atlantic, yielding confidence in the preservation of the marine Nd isotope signal in all these archives. The marine origin of the Nd in the coatings is confirmed by their marine Sr isotope values. These important results allow application of the technique to down-core samples. The new epsilon-Nd datasets, along with ancillary Cd/Ca and Nd/Ca ratios from the same foraminiferal samples, are interpreted in the context of debates on the Neogene history of North Atlantic Deep Water (NADW) export to the South Atlantic. In general, the epsilon-Nd and delta13C records are closely correlated over the past 4.5 Ma. The Nd isotope data suggest strong NADW export from 8 to 5 Ma, consistent with one interpretation of published delta13C gradients. Where the epsilon-Nd record differs from the nutrient-based records, changes in the pre-formed delta13C or Cd/Ca of southern-derived deep water might account for the difference. Maximum NADW-export for the entire record is suggested by all proxies at 3.5-4 Ma. Chemical conditions from 3 to 1 Ma are totally different, showing, on average, the lowest NADW export of the record. Modern-day values again imply NADW export that is about as strong as at any stage over the past 8 Ma.