Electrochemical analysis of the performance of carbon supported Pd nanoparticles for direct formic acid fuel cells: from gold supported electrodes to catalyst-coated membranes

In this work carbon supported Pd nanoparticles were prepared and used as electrocatalysts for formic acid electrooxidation fuel cells. The influence of some relevant parameters such as the nominal Pt loading, the Nafion/total solids ratio as well as the Pd loading towards formic acid electrooxidation was evaluated using gold supported catalytic layer electrodes which were prepared using a similar methodology to that employed in the preparation of conventional catalyst coated membranes (CCM). The results obtained show that, for constant Pd loading, the nominal Pd loading and the Nafion percentage on the catalytic layer do not play an important role on the resulting electrocatalytic properties. The main parameter affecting the electrocatalytic activity of the electrodes seems to be the Pd loading, although the resulting activity is not directly proportional to the increased Pd loading. Thus, whereas the Pd loading is multiplied by a factor of 10, the activity is only twice which evidences an important decrease in the Pd utilization. In fact, the results obtained suggest the active layer is the outer one being clearly independent of the catalytic layer thickness. Finally, catalyst coated membranes with Pd catalyst loadings of 0.1, 0.5 and 1.2 mg cm-2 were also tested in a breathing direct formic acid fuel cell.

Subsidence activity maps derived from DInSAR data: Orihuela case study

A new methodology is proposed to produce subsidence activity maps based on the geostatistical analysis of persistent scatterer interferometry (PSI) data. PSI displacement measurements are interpolated based on conditional Sequential Gaussian Simulation (SGS) to calculate multiple equiprobable realizations of subsidence. The result from this process is a series of interpolated subsidence values, with an estimation of the spatial variability and a confidence level on the interpolation. These maps complement the PSI displacement map, improving the identification of wide subsiding areas at a regional scale. At a local scale, they can be used to identify buildings susceptible to suffer subsidence related damages. In order to do so, it is necessary to calculate the maximum differential settlement and the maximum angular distortion for each building of the study area. Based on PSI-derived parameters those buildings in which the serviceability limit state has been exceeded, and where in situ forensic analysis should be made, can be automatically identified. This methodology has been tested in the city of Orihuela (SE Spain) for the study of historical buildings damaged during the last two decades by subsidence due to aquifer overexploitation. The qualitative evaluation of the results from the methodology carried out in buildings where damages have been reported shows a success rate of 100%.

Gold Nanoparticles Supported on Polyacrylamide Containing a Phosphorus Ligand as an Efficient Heterogeneous Catalyst for Three-Component Synthesis of Propargylamines in Water

Gold nanoparticles supported on a polyacrylamide containing a phosphinite ligand have been synthesized and characterized using different techniques such as TEM, SEM, EDX, XPS, and solid UV analyses. The new material was successfully applied as a heterogeneous catalyst for the three-component A3 coupling of amines, aldehydes, and alkynes to give propargylamines. Reactions are performed in neat water at 80 °C with only 0.05 mol% catalyst loading. The heterogeneous catalyst is recyclable during seven consecutive runs with small decrease in activity.

Model of an Arizona gold mine.

no.1(1922)

Mining Districts, Victoria, Australia, ca. 1868 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Victoria mining districts, mining divisions & the gold fields, engraved by William Slight under the direction of R. Brough Smyth ; colored by Arthur Everett, August 1st, 1868. It was published by Dept of Mines ca. 1868. Scale [ca. 1:1,000,000].The image inside the map neatline is georeferenced to the surface of the earth and fit to the coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, cities and other human settlements, administrative boundaries, railroads, gold reefs, mining districts, telegraph lines, shoreline features, and more. Relief shown by hachures. Includes notes.This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Idaho city : queen of the gold camps /

Mode of access: Internet.

Gold fields of Nova Scotia,

Mode of access: Internet.

In richest Alaska and the gold fields of the Klondike : how they were found ... together with a history of this wonderful land from its discovery to the present day ... and practical information for gold seekers /

Mode of access: Internet.

A philosophical and practical essay on the gold and silver mines of Mexico and Peru : containing the nature of the ore, and the manner of working the mines, the qualities and use of quicksilver, the cleansing and refining these metals : with many useful observations concerning the assay of metals, the manner of conveying them to Europe, and remarks on the gold mines in Hungary, and those of Asia and Africa /

No Spanish ed. in: NUC pre-1956, BLC, Sabin, Palau y Dulcet (2nd ed.).

Gold!

Mode of access: Internet.

The exploring expedition to the Rocky Mountains, Oregon and California, to which is added a description of the physical geography of California, with recent notices of the gold region from the latest and most authentic sources /

Mode of access: Internet.

Preliminary report on Cape Nome gold region, Alaska, with maps and illustrations [microform].

On geology, resources, and population; with summary data on distances and rations.

The gold-mines of Midian and the ruined Midianite cities.

Mode of access: Internet.

Gold: its occurrence and extraction. Embracing the geographical and geological distribution and the mineralogical characters of gold-bearing rocks; the peculiar features and modes of working shallow placers, rivers, and deep leads; hydraulicing ... a bibliography of the subject; and a glossary of English and foreign technical terms.

Mode of access: Internet.

Statistics of mines and mining in the states and territories west of the Rocky Mountains; being the [1st-8th] annual report of Rossiter W. Raymond, U.S. commissioner of mining statistics

8th, 1875, 44th Cong., 1st sess., House ex. doc. no. 159