Properties of amorphous carbon-silicon alloys deposited by a high plasma density source

The addition of silicon to hydrogenated amorphous carbon can have the advantageous effect of lowering the compressive stress, improving the thermal stability of its hydrogen, and maintaining a low friction coefficient up to high humidity. Most experiments to date have been on hydrogenated amorphous carbon-silicon alloys (a-C1-xSix:H) deposited by rf plasma enhanced chemical vapor deposition. This method gives alloys with sizeable hydrogen content and only moderate hardness. Here we use a high plasma density source known as the electron cyclotron wave resonance source to prepare films with higher sp3 content and lower hydrogen content. The composition and bonding in the alloys is determined by x-ray photoelectron spectroscopy, Rutherford backscattering, elastic recoil detection analysis, visible and ultraviolet (UV) Raman spectroscopy, infrared spectroscopy, and x-ray reflectivity. We find that it is possible to produce relatively hard, low stress, low friction, almost humidity insensitive a-C1-xSix:H alloys with a good optical transparency and a band gap well over 2.5 eV. The friction behavior and friction mechanism of these alloys are studied and compared with that of a-C:H, ta-C:H, and ta-C. We show how UV Raman spectroscopy allows the direct detection of Si-C, Si-Hx, and C-Hx vibrations, not seen in visible Raman spectra. © 2001 American Institute of Physics.

Chemical sputtering of ta-C: Implications for the deposition of carbon nitride

The majority of attempts to synthesize the theoretically predicted superhard phase β-C3N4 have been driven towards the use of techniques which maximize both the carbon sp3 levels and the amount of nitrogen incorporated within the film. However, as yet no attempt has been made to understand the mechanism behind the resultant chemical sputter process and its obvious effect upon film growth. In this work, however, the chemical sputtering process has been investigated through the use of an as-deposited tetrahedrally bonded amorphous carbon film with a high density nitrogen plasma produced using an rf-based electron cyclotron wave resonance source. The results obtained suggested the presence of two distinct ion energy dependent regimes. The first, below 100 eV, involves the chemical sputtering of carbon from the surface, whereas the second at ion energies in excess of 100 eV exhibits a drop in sputter rate associated with the subplantation of nitrogen within the carbon matrix. Furthermore, as the sample temperature is increased there is a concomitant decrease in sputter rate suggesting that the rate is controlled by the adsorption and desorption of additional precursor species rather than the thermal desorption of CN. A simple empirical model has been developed in order to elucidate some of the primary reactions involved in the sputter process. Through the incorporation of various previously determined experimental parameters including electron temperature, ion current density, and nitrogen partial pressure the results indicated that molecular nitrogen physisorbed at the ta-C surface was the dominant precursor involved in the chemical sputter process. However, as the physisorption enthalpy of molecular nitrogen is low this suggests that activation of this molecular species takes place only through ion impact at the surface. The obtained results therefore provide important information for the modeling and growth of high density carbon nitride. © 2001 American Institute of Physics.

Properties of a-C:H films deposited from a methane electron cyclotron wave resonant plasma

An electron cyclotron wave resonant methane plasma discharge was used for the high rate deposition of hydrogenated amorphous carbon (a-C:H). Deposition rates of up to ∼400 Å/min were obtained over substrates up to 2.5 in. in diameter with a film thickness uniformity of ∼±10%. The deposited films were characterised in terms of their mass density, sp3 and hydrogen contents, C-H bonding, intrinsic stress, scratch resistance and friction properties. The deposited films possessed an average sp3 content, mass density and refractive index of ∼58%, 1.76 g/cm3 and 2.035 respectively.Mechanical characterisation indicated that the films possessed very low steady-state coefficients of friction (ca. 0.06) and a moderate shear strength of ∼141 MPa. Nano-indentation measurements also indicated a hardness and elastic modulus of ∼16.1 and 160 GPa respectively. The critical loads required to induce coating failure were also observed to increase with ion energy as a consequence of the increase in degree of ion mixing at the interface. Furthermore, coating failure under scratch test conditions was observed to take place via fracture within the silicon substrate itself, rather than either in the coating or at the film/substrate interface. © 2003 Elsevier B.V. All rights reserved.

Methane chemistry involved in a low-pressure electron cyclotron wave resonant plasma discharg

A low-pressure methane plasma generated by electron cyclotron wave resonance was characterized in terms of electron temperature, plasma density and composition. Methane plasmas were commonly used in the deposition of hydrogenated amorphous carbon thin films. Little variation in the plasma chemistry was observed by mass spectrometry measurements of the gas phase with increasing electron temperature. The results show that direct electron-impact reactions exert greater influence on the plasma chemistry than secondary ion-neutral reactions.

Nitrogen incorporation into tetrahedral hydrogenated amorphous carbon

Structural changes induced by the incorporation of nitrogen into ta-C : H films have been studied by Electron Energy Loss Spectroscopy, X-Ray Photoelectron Spectroscopy, Fourier Transformed Infrared Spectroscopy and Ultraviolet-Visible Spectroscopy. ta-C:H films have been synthesised using a low pressure Electron Cyclotron Wave Resonance (ECWR) source which provides a plasma beam with a high degree of ionisation and dissociation. Nitrogen was incorporated by adding N2 to the C2H2 plasma used for the deposition of ta-C : H films. The N/C atomic ratio in the films rises rapidly until the N2/C2H2 gas ratio reaches three, and then increases more gradually, while the deposition rate decreases steeply. Chemical sputtering of the forming films and the formation of molecular nitrogen within the films limit the maximum nitrogen content to about N/C = 0.6. For low nitrogen content the films retain their diamond-like properties, however as N/C atomic ratio increases, a polymeric-like material is formed, with >C=N- structures and terminating C=N and NH groups that decrease the connectivity of the network.

Hydrogen content estimation of hydrogenated amorphous carbon by visible Raman spectroscopy

In the present study, we report the hydrogen content estimation of the hydrogenated amorphous carbon (a-C:H) films using visible Raman spectroscopy in a fast and nondestructive way. Hydrogenated diamondlike carbon films were deposited by the plasma enhanced chemical vapor deposition, plasma beam source, and integrated distributed electron cyclotron resonance techniques. Methane and acetylene were used as source gases resulting in different hydrogen content and sp2/sp3 fraction. Ultraviolet-visible (UV-Vis) spectroscopic ellipsometry (1.5-5 eV) as well as UV-Vis spectroscopy were provided with the optical band gap (Tauc gap). The sp2/sp3 fraction and the hydrogen content were independently estimated by electron energy loss spectroscopy and elastic recoil detection analysis-Rutherford back scattering, respectively. The Raman spectra that were acquired in the visible region using the 488 nm line shows the superposition of Raman features on a photoluminescence (PL) background. The direct relationship of the sp2 content and the optical band gap has been confirmed. The difference in the PL background for samples of the same optical band gap (sp2 content) and different hydrogen content was demonstrated and an empirical relationship between the visible Raman spectra PL background slope and the corresponding hydrogen content was extracted. © 2004 American Institute of Physics.

Experiments and Lagrangian simulations on the formation of droplets in continuous mode

Experimental and computational studies on the dynamics of millimeter-scale cylindrical liquid jets are presented. The influences of the modulation amplitude and the nozzle geometry on jet behavior have been considered. Laser Doppler anemometry (LDA) was used in order to extract the velocity field of a jet along its length, and to determine the velocity modulation amplitude. Jet shapes and breakup dynamics were observed via shadowgraph imaging. Aqueous solutions of glycerol were used for these experiments. Results were compared with Lagrangian finite-element simulations with good quantitative agreement. © 2011 The American Physical Society.

Experiments and Lagrangian simulations on the formation of droplets in drop-on-demand mode

The creation and evolution of millimeter-sized droplets of a Newtonian liquid generated on demand by the action of pressure pulses were studied experimentally and simulated numerically. The velocity response within a model, large-scale printhead was recorded by laser Doppler anemometry, and the waveform was used in Lagrangian finite-element simulations as an input. Droplet shapes and positions were observed by shadowgraphy and compared with their numerically obtained analogues. © 2011 American Physical Society.

Jet diameters and velocity profiles in continuous ink-jets

Theoretical predictions of the diameters of continuous ink-jets downstream of long nozzles are generalized to include the important cases of ink-jet fluids and shorter nozzles where the velocity profile at the nozzle exit is undeveloped (non-parabolic). Comparisons of the new predictions with experiments and simulations are made for fairly long nozzles with tapered profiles and short nozzles with conical profiles; experimental and simulated profiles are also compared downstream of the nozzle exit for both industrial and large scale ink-jet print heads. Precise measurements of the un-modulated jet diameters downstream of the nozzle exit can set really useful limits to the possible shapes of the flow profile right at the nozzle exit, and in particular allow some assessment of the axial velocity gradients and fluid shear rates at the nozzle exit where direct speed measurement is usually impractical. Simulations allow further study of the relaxation of the velocity profile downstream of the nozzle exit, and are reported for both un-modulated and modulated CIJ jetting. Implications of this work include speeding up CIJ simulations, absolute calibration of the applied CIJ system modulation, and the likely magnitude of dynamic surface tension effects on observed CIJ satellite speeds.

Comportamiento de variables de crecimiento y rendimiento en maiz (Zea mays L.) var. NB-6 bajo practicas de fertilizacion, organica y convencional en la Finca El Plantel 2007-2008

El presente trabajo de investigación se estableció entre los meses de Noviembre 2007-Marzo 2008, bajo sistema de riego en la estación experimental El Plantel propiedad de la Universidad Nacional Agraria (UNA), ubicada en el km 42 ½ de la carretera Tipitapa–Masaya, municipio de Tisma en las coordenadas 12 o 07’ 3.84’’ latitud norte y 86 o 05’ 26.085’’ longitud oeste a una altura de 200 msnm. Con el objetivo de comparar el crecimiento y rendimiento del cultivo maíz, variedad NB-6, se establecierondos tratamientos, con prácticas de manejo convencional y orgánico, el tamaño de la parcela experimental fué de 432m2 (16 m x 27 m) y el tamaño de cada parcela útil fue de 46.8 m2 (6 m x 7.8 m), en ambos manejos. Las variables evaluadas fueron; altura de planta, diámetro de tallo, número de hojas, área foliar, longitud de mazorca, diámetro de mazorca, número de hileras por mazorca, número de granos por hileras, número de granos por mazorca, peso de mil granos y rendimiento. Los datos fueron analizados con el programa estadístico SAS versión 9.1, año 2006; realizando comparaciones de medias para cada variable en las dos prácticas de manejo. Los resultados muestran que no hubo diferencia significativa para las variables de crecimiento, tomadas en momentos diferentes. Se encontró diferencia significativa para las variables de rendimiento; longitud de la mazorca y diámetro de la mazorca. El manejo orgánico obtuvo los mayores rendimientos con un total de 3869.78kgha-1, seguido del manejo convencional con 3060.29 kgha-1.

Sapientia, 2005, Vol. LX, nº 217 (número completo)

Contenido: El tratamiento de la providencia general de Dios en Santo Tomás de Aquino / Gabriel Delgado – Sobre el ente posible y necesario en Tomás de Aquino / Alberto Berro – El apogeo del nominalismo escolástico y la imposibilidad de la metafísica / Mario Enrique Sacchi – La psicologia de Nietzsche e il suo influsso nella Psicoanalisi / Martín F. Echavarría – Ernst Cassirer: de la tragedia a la ambivalencia de la cultura (parte II) / Amán Rosales Rodríguez – Conocimiento y respuesta al valor. Enfoque fenomenológico axiológico de von Hildebrand / Elizabeth Da Dalt de Mangione -- Heidegger, Aristóteles y la Escolástica / Silvana Filippi – Los “juicios directos” y la probabilidad. Introducción al concepto de probabilidad según John Maynard Keynes / Marcelo Luis Imperiale – Generalis Relativitatis Theoria: geometria et philosophia / Ramiro Délio Borges de Meneses – El arte de gobernar. Nota sobre Michel Foucault a 20 años de su muerte -- Bibliografía

La ciencia económica después de la crisis mundial

I am delighted to be here this evening. This is my first visit to Argentina and I am honored to be invited by the Catholic University of Argentina. I will talk about the world crisis from a Keynesian point of view, and my lecture will be divided into three parts: why did it start?; what should we be doing about it?; and what steps can we take to prevent something like this from happening again. So I will deal with “origin”, “recovery” and “reform”. Because of the speed of the recovery in this part of the world my diagnosis and prescriptions might at first glance seem less relevant to Argentina and Latin America than to Europe and the United States. But Latin America’s recovery is mainly based on rising commodity prices and commodity prices are, partly determined by what happens to the rest of the world. In a globalized world each country fate is bound up with the fate of its neighbors. Bringing about a global recovery, therefore, is in the interest of all, whether in South America or Southern Europe.

La burbuja inmobiliaria americana

Resumen: Axel Leijonhufvud, economista reconocido internacionalmente por sus trabajos sobre la literatura de John Maynard Keynes y el keynesianismo (Leijonhufvud, 1968), ofreció su lectura de la crisis subprime de 2008, reconociendo que la misma encaja más con la teoría austríaca del ciclo económico de Ludwig von Mises y Friedrich Hayek, que con el marco teórico keynesiano. En este artículo ofrecemos evidencia para tal afirmación.