Thermal, mechanical and ionic conductive behaviour of gamma-radiation induced PEO/PVDF(SIN)-LiClO4 polymer electrolyte system

An effort has been made to modify the mechanical behaviour of our previously reported gel-type gamma-radiation crosslinked polyethylene oxide (PEO)-LiClO4 polymer electrolyte. A highly polar and gamma-radiation crosslinkable crystalline polymer, polyvinylidene fluoride (PVDF), was selected to blend with PEO and then subjected to gamma-irradiation in order to make an simultaneous interpenetrating network (SIN), which was used as a polymer host to impart stiffness to the plasticized system. Experimental results have shown that the presence of PVDF in the system, through gamma-radiation induced SIN formation, could not only give a rather high mechanical modulus of 10(7) Pa at ambient temperature, but also maintain the room temperature ionic conductivity at a high level (greater than 10(-4) S/cm). DSC, DMA and conductivity measurement techniques were used to examine the effects of blending, gamma-irradiation and plasticization on the variations of glass transition and melting endotherm, on the appearance of high elastic plateau and on the temperature dependence of ionic conductivity: In addition, it was found that, in contrast with the unplasticized system, the ionic conductivity mechanism of this gel-type electrolyte seems to conform to the Arrhenius model, suggesting that, as a result of the high degree of plasticization, the polymer chains act mainly as the skeleton of the networks or polymer cages to immobilize the liquid electrolyte solution, whereas the ionic species migrate as if they were in a liquid medium. (C) 1997 Elsevier Science Ltd.

gamma-Radiation damage to nylon 1010 containing neodymium oxide

A comparison of radiation damage to nylon 1010 (denoted nylon-a) and nylon 1010 containing neodymium oxide (Nd2O3) (denoted nylon-b) was made by DSC, WAXD, ESR and the determination of gel fractions. The results show that radiation damage to nylon-b is delayed, and radiation damage to nylon-a is more severe than that to nylon-b, due to the protection of the fold surface of the lamellae. Furthermore, the fact that the damage begins with the fold surface of the lamellae is confirmed. (C) 1996 Elsevier Science Limited

WAXD and SAXS study on gamma-radiation damage to polyamide-1010 crystal structure

In the present work we attempt to settle the controversy on the district wherein the radiation induced reaction preferentially occurs through examining the structural changes of the irradiated polyamide-1010 specimens on both the crystallographic and the supermolecular level by using WAXD and SAXS techniques. Experimental results indicated that the chain crosslinking and scission of the irradiated specimens occur mainly in the amorphous region and on the crystal surface (or interphase), and extend into the inner portion of the crystal with increasing radiation dose.

THE INFLUENCE OF GAMMA-RADIATION ON POLYAMIDE-1010 AGGREGATE STRUCTURES

The influence of gamma-radiation on polyamide 1010 aggregate structures and crystal damage were examined by using wide angle X-ray diffraction (WAXD) and small angle X-ray scattering (SAXS) techniques. The results revealed that some structural parameters of the aggregated state, the density differences and the degree of crystallinity W-c,W-x, essentially decreased with increasing radiation dose, but the specific surface O-s increased. Crosslinking and scission of irradiated polyamide 1010 samples occurred mainly in amorphous and interphase regions, and crystal damage and amorphization induced by gamma-radiation spread from the interphase and extended into the crystal phase with increasing radiation dose. This result also indicated that the (010) reflection with the hydrogen bond was more susceptible to the action of radiation.

GAMMA-RADIATION INDUCED CROSS-LINKED PEO-LICLO4 SOLID-ELECTROLYTE SYSTEM

Aimed at raising the room temperature ionic conductivity of PEO-based solid polymer electrolyte and considered that the ionic conduction preferentially occurs in the amorphous phase, we lightly crosslinked the high MW PEO through gamma-irradiation and further suppressed the residual crystallinity by plasticizing with propylene carbonate. By incorporating LiClO4 salt to the above described polymer host, the ambient (25 degrees C) ionic conductivity of the electrolyte system could reach as high as 6.8 X 10(-4) S/cm. As the electrolyte was a crosslinked system, it was mechanically self-supportable. Based on the preliminary results of the electrochemical performance of the secondary lithium battery, assembled by using this kind of solid electrolyte and polyaniline as positive electrode, it is realized that the electrolyte thus prepared is of high expectancy.

GAMMA-RADIATION DAMAGE TO POLYAMIDE-1010 CRYSTAL-STRUCTURE

Radiation effects on polyamide-1010 specimens having various states of aggregation were studied using wide angle X-ray diffraction, electron spin resonance, calorific and sol measurement techniques. Experimental results indicated that chain crosslinking

EFFECT OF GAMMA-RADIATION ON DYNAMIC VISCOELASTIC PROPERTIES AND THERMAL-BEHAVIOR FOR LDPE

The effect of gamma-radiation on dynamic viscoelastic properties and thermal behavior for low density polyethylene(LDPE) have been investigated. The store energy modulus (E) of the samples increased after radiation. The beta and alpha transition temperature shifted to higher temperature with increasing irradiation dose. The results of thermal analysis show that crystal melting temperature (Tm), enthalpy(DELTAHm) and crystal disapperance temperature(Td) for irradiated samples decreases with increasing of dose.

SOME CHEMICAL-CHANGES IN CHITOSAN INDUCED BY GAMMA-RAY IRRADIATION

Chitosan was subjected to gamma-ray irradiation in air. It was found that the -NH2 group is more sensitive to irradiation than the -NHCOCH3 group, and moreover, the hydroxyl group increases with increasing radiation dose while the C-O-C group decreases, but no evidence for carbonyl formation was observed.

STUDY ON GAMMA-RADIATION INDUCED LAMELLAR DAMAGE MECHANISM OF POLY(VINYLIDENE FLUORIDE)

This paper studies gamma-radiation induced lamellar damage mechanism of poly(vinylidene fluoride), using wide angle X-ray diffraction (WAXD), differential scanning calorimetry (DSC), electronic paramagnetic resonance (EPR) and gel fraction determination. We believe that it is ''lamellae core damage'' rather than ''lamellae surface damage'' that results in the decrease of the crystallinity.

RADIATION EFFECTS ON CRYSTALLINE POLYMERS .1. GAMMA-RADIATION-INDUCED CROSS-LINKING AND STRUCTURAL CHARACTERIZATION OF POLYETHYLENE OXIDE

By using WAXD, DSC and gel fraction determination techniques, the mechanism of radiation crosslinking of polyethylene oxide (PEO) was explored, and the dependence of aggregated state on the chemical reaction and physical structure was also discussed. It was found that just like other semi-crystalline polymers, the state of aggregation of the specimen has a profound influence on the radiation effects on PEO. On the contrary, the crystalline structure of the specimen is severely affected with the increase in radiation dose and eventually amorphortized when subjected to an extremely high radiation dose.

CHARACTERIZATION OF GAMMA-IRRADIATED CRYSTALLINE POLYMER .3. THERMAL-BEHAVIOR OF GAMMA-IRRADIATED POLYAMIDE-1010

Thermal behaviour of gamma-irradiated plain PA1010 and PA1010 containing different amounts of difunctional cross-linking agent BMI was investigated. In DSC endo- and exotherm, it was found that during irradiation, the presence of BMI markedly changes the melting and crystallisation characteristics of PA1010. A supposition that the network of BMI-containing specimens is rather loose in structure was proposed to explain the discrepancy in thermal behaviour between these two kinds of specimens. The supposition was further ascertained by the less brittleness in mechanical property of specimens containing BMI. Besides, the complexity of the thermal behaviour of gamma-irradiated PA1010 was discussed and attributed mainly to the increase in sigma-e, the fold surface free energy of chain fold crystals.

CHARACTERIZATION OF GAMMA-RADIATION CROSS-LINKED CRYSTALLINE POLYMERS BY CRYSTALLIZATION TEMPERATURE

The effect of gamma-radlatlon on plain crystalline polymers and crystalline polymers containing different amounts of difunctional monomer both in vacuum and in air at room temperature has been investigated with DSC. It was found that the crystallization temperature T_c of crosslinked sample measured on DSC at a constant cooling rate decreases with increasing radiation dose. The difference between T_c before and after crosslinking (T_(c_0)-T_(c_R)) is linearly related to the radiation dose for plain polymer....

Isolation, properties and spatial site analysis of gamma subunits of B-phycoerythrin and R-phycoerythrin

Polysiphonia urceolata R-phycoerythrin and Porphyridium cruentum B-phycoerythrin were degraded with proteinaseK, and then the nearly native gamma subunits were isolated from the reaction mixture. The process of degradation of phycoerythrin with proteinaseK showed that the gamma subunit is located in the central cavity of (alpha beta)(6) hexamer of phycoerythrin. Comparative analysis of the spectra of the native phycoerythrin, the phycoerythrin at pH 12 and the isolated gamma subunit showed that the absorption peaks of phycoerythrobilins on alpha or beta subunit are at 535 nm (or 545 nm) and 565 nm, the fluorescence emission maximum at 580 nm; the absorption peak of phycoerythrobilins on the isolated gamma subunit is at 589 nm, the fluorescence emission peak at 620 nm which overlaps the absorption maximum of C-phycocyanin and perhaps contributes to the energy transfer with high efficiency between phycoerythrin and phycocyanin in phycobilisome; the absorption maximum of phycourobilin on the isolated gamma subunit is at 498 nm, which is the same as that in native phycoerythrin, and the fluorescence emission maximum at 575 nm.

Bromophenols coupled with methyl gamma-ureidobutyrate and bromophenol sulfates from the red alga Rhodomela confervoides

Four new bromophenols C-N coupled with methyl gamma-ureidobutyrate (1-4), a phenylethanol bromophenol (5), and three phenylethanol sulfate bromophenols (6-8) have been isolated from polar fractions of an ethanolic extract of the red alga Rhodomela confervoides. On the basis of spectroscopic evidence including HRMS and 2D NMR data, the structures of the new compounds were determined as methyl N'-(2,3-dibromo-4,5-dihydroxybenzyl)-gamma-ureidobutyrate (1), methyl N,N'-bis(2,3-dibromo-4,5-dihydroxybenzyl)-gamma-ureidobutyrate (2), methyl N'-[3-bromo-2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]-gamma-ureidobutyrate (3), methyl N'-(2,3-dibromo-4,5-dihydroxybenzyl)-A7-[3-bromo2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxybenzyl]-gamma-ureidobutyrate (4), 2,3-dibromo-4,5-dihydroxyphenylethanol (5), 2,3-dibromo-4,5-dihydroxyphenylethanol Sulfate (6), 3-bromo-4,5-dihydroxyphenylethanol sulfate (7), and 3-bromo2-(2,3-dibromo-4,5-dihydroxybenzyl)-4,5-dihydroxyphenylethanol sulfate (8). The cytotoxicity of all compounds was evaluated against several human cancer cell lines including human colon cancer (HCT-8), hepatoma (Bel7402), stomach cancer (BGC-823), lung adenocarcinoma (A549), and human ovarian cancer (A2780). Among them, the phenylethanol and the phenylethanol sulfate bromophenols (5-8) showed moderate cytotoxicity against all tested cell lines.