Depth integrated nitrogen fixation from the northern Benguela upwelling system during METEOR cruise M103/2

Nitrogen fixation data from the cruise number M103/2 with research vessel "Meteor" from 21.01.-11.02.2014 (second leg from Walvis Bay to Walvis Bay) in front of Namibia. Samples taken by CTD- rosette sampler from different depths and incubated in glass bottles (535 ml) at light intensities that resemble the in situ light intensities of the sampling depth after 15N2 gas was injected to the sample. After the incubation time of 24 hours, the complete bottle content was filtered onto a pre-combusted Whatman GF/F filter. Filters were frozen, transported to the institute on dry ice and measured in a mass spectrometer for Delta15N. The principle of the method was described by Montoya et al. (1996) and calculation was done according to their spread sheet. From the data of the single depths, the nitrogen fixation per square meter within the upper 40 m of the water column was calculated. The methods are described in detail in a paper submitted by Wasmund et al. in 2014 to be printed in 2015. Some results are surprisingly below zero. This occurs if the Delta15N of the blank is higher than the measurement after incubation. It indicates that no nitrogen fixation occurred. Due to natural variability, the variability of the nitrogen fixation data is high. In an overall estimate, also over several cruises, negative and positive values compensate more or less, suggesting that nitrogen fixation is insignificant in the waters in front of northern Namibia and southern Angola.

Cenozoic calcareous nannofossils in DSDP Leg 77 holes

Three of the six DSDP Leg 77 sites drilled in the western approaches to the Straits of Florida yielded thick sequences of Cenozoic sediment rich in calcareous nannofossils. Hiatuses are prominent in each of these continuously cored intervals. A prominent upper Oligocene hiatus, observed at each of these three sites, can be correlated to a large-scale "global" regression event. Other disconformable horizons present in the study area cannot be positively related to sealevel fluctuations and may be caused by a number of factors including local tectonic activity. Paleogene sections are generally marked by thick accumulations within the upper Oligocene Sphenolithus ciperoensis Zone and by a pronounced braarudosphaerid-holococcolith bloom recorded in the lower Oligocene and upper Eocene. This bloom is particularly well developed at Site 540. All samples examined contain abundant nannofossils. Preservation fluctuates throughout the sections from good to poor.

Porosity, permeability, trace elements, and carbon-oxygen isotopes at DSDP Hole 77-536

Talus deposits recovered from Site 536 show evidence of aragonite dissolution, secondary porosity development, and calcite cementation. Although freshwater diagenesis could account for the petrographic features of the altered talus deposits, it does not uniquely account for isotopic or trace-element characteristics. Also, the hydrologic setting required for freshwater alteration is not easily demonstrated for the Campeche Bank. A mixing-zone model does not account for the available trace-element data, but does require somewhat less drastic assumptions about the size of the freshwater lens. Although a seawater (bottom-water) alteration model requires no hydrologic difficulties, unusual circumstances are required to account for the geochemical characteristics of the talus deposits using this model.