Synthesis and electrochemical characteristics of lanthanide complexes with 2-nitro-5,10,15,20-tetraphenylporphyrin and acetylacetonate

Four lanthanide complexes with 2-nitro-5,10,15,20-tetraphenylporphyrin and acetylacetonate were prepared and characterized by elemental analyses, LR, UV-Visible,H-1 NMR, XPS and molar conductance. The redox properties of the lutetium complex with 2-nitro-5,10,15,20-tetraphenylporphyrin and acetylacetonate in dichloromethane were studied by cyclic voltammetry.

人体血浆中15种超痕量稀土元素的电感耦合等离子体质谱法测定

本文用电感耦合等离子体质谱法测定了人体血浆中的稀土元素。在优化的条件下 ,以内标法测得的各种纯水溶液的检测限在 0 .7(Eu)～ 5 .4(Gd) ng·L- 1范围内。研究了 K,Na,Ca,Fe等基体元素对稀土测定的影响。以 In为内标元素补偿样品基体效应以及灵敏度飘移。比较了直接稀释、HNO3- H2 O2 消解及 HNO3-HCl O4消解 3种样品处理方法 ,用 1% HNO3直接稀释样品可满足轻稀土元素的定量分析要求 ,方法的定量测定下限≤ 1μg·L- 1。

The crystal structure and supramolecular chain of [La(NO3)(3)(OH2)(2)(phen)]center dot 15-crown-5

[La(NO3)(3)(OH2)(2)(phen)]. 15-crown-5 is hexagonal, P6(5), with a = 10.955(2), c = 43.769(9) Angstrom, and D-calc = 1.668 g cm(-3) for Z = 6. In the complex, two nitrogen atoms (from phen) and eight oxygen atoms (six from three bidentate nitrate anions and two from water molecules) are coordinated to the central La(III) ion, forming a coordination polyhedron which is approximately a bicapped square antiprism. The coordinated water molecules donate hydrogen bonds to the oxygen atoms of the crown ether, forming polymeric hydrogen bonded chains which wrap helically along the unit cell direction c.

Miscibility, crystallization, and morphology studies of thermosetting polyimide PMR-15/PEK-C blends

Miscibility, crystallization, and mechanical properties of blends of thermosetting polyimide PMR-15 and phenolphthalein poly(ether ketone) (PEK-C) were examined. With the exception of the 90/10 blend, which has two glass transition peaks, all the blends with PMR-15 less than 90 wt % are miscible in the amorphous state according to DMA results. Addition of PEK-C hindered significantly the crystallization of PMR-15, indicating that there must exist some kind of interaction between molecular chains of PMR-15 and those of PEK-C. The semi-IPN system of PMR-15/PEK-C blends exhibits good toughness. Two distinct microphases, interweaving at the phase boundaries, were found in the PMR-15/PEK-C 60/40 blend. The toughness effect of the blends is discussed in terms of the interface adhesion between the two distinct phases and the domain sizes of the phases. The relation between miscibility and toughness of the blends was investigated. (C) 1996 John Wiley & Sons, Inc.

Preparation and crystal structures of LaCl3(15-crown-5) and [LaCl2(phen)(H2O)(2)(mu-Cl)](2)center dot(15-crown-5)center dot MeCN

LaCl3(15-crown-5), I was prepared by the reaction of LaCl(3)nH(2)O with 15-crown-5 and bipy (2,2'-bipyridyl). [LaCl2(phen)(H2O)(2)(mu-Cl)](2) .(15-crown-5). MeCN, II, was crystallized from a mixture of LaC1(3) . nH(2)O, phen (1,10-phenanthroline) and 15-crown-5 in MeOH/MeCN, Crystal structures of these two complexes have been determined by X-ray methods. The La(III) ion in I is coordinated by three Cl anions and five oxygen atoms of a crown ether. The two metal ions in II are bridged by two Cl anions and the crown ligand is hydrogen-bonded to the coordinated water molecules to form polymeric... crown/cation/cation/crown... chains.

15个乙烯-乙烯基化合物共聚物的取代基参数

本文应用取代基参数(SCS)方法处了15个EV共聚物的~(12)C NMR谱.它们是:(1)乙烯-α-烯烃共聚物,即乙烯-丙烯共聚物.乙烯-丁烯-1共聚物,乙烯-4-甲基-1-戊烯共聚物,乙烯-己烯-1共聚物和乙烯-辛烯-1共聚物;(2)乙烯-含氧乙烯基共聚物,即乙烯-甲基丙烯酸N,N-二甲基胺乙酯共聚物,乙烯-丙烯酸甲酯共聚物.乙烯-丙烯酸共聚物,乙烯-乙酸乙烯酯,乙烯-乙烯醇,乙烯-氧化碳共聚物(ECO)(?)乙烯-卤代乙烯共聚物及其它EV共聚物,即乙烯-氯化乙烯共聚物(包含氯化聚乙烯),乙烯-溴化乙烯共聚物,乙烯-苯乙烯共聚物(包含氢化丁二烯-苯乙烯共聚物)和乙烯-丙烯腈共聚物、得到了15种取代基的SCS参数.

稀土冠醚配合物的研究XX．Schiff碱型双冠醚N，N’－对苯二甲亚基双（4’－氨基苯并－15－冠－5）稀土配合物的合成和性质

合成了一种Ｓｃｈｉｆｆ碱型双冠醚Ｎ，Ｎ’－对苯二甲亚基双（４’－氨基苯并－１５－冠－５）及其稀土硝酸盐的固体配合物，通过元素分析、摩尔电导、ＩＲ、ＵＶ、１ＨＮＭＲ和热分析等对其性质作了表征与比较。

STRUCTURE OF [LA(NO3)(3)(OH2)(2)(OHME)(BIPY)].15-CROWN-5

[La(NO3)(3)(OH2)(2)(OHMe)(bipy).15-crown-5 is monoclinic, P2(1)/n, with a = 11.239(6), b = 19.302(7), c = 14.458(8) Angstrom, beta = 92.47(5)degrees, and D-calc = 1.63 g cm(-3) for Z = 4. In the complex, two nitrogen atoms (from bipy) and nine oxygen atom

5，10，15，20－四（对－山嵛酸乙酯－α－氧代苯基）卟啉LB膜结构研究

５，１０，１５，２０－四（对－山嵛酸乙酯－α－氧代苯基）卟啉ＬＢ膜结构研究王海水，曾广赋，谷淑珍，席时权（中国科学院长春应用化学研究所长春１３００２２）利用ＬＢ膜技术将分子组装成有序的分子单层或多层体系，研究膜内分子间相互作用和分子的结构，对了解结构...

5,10,15,20-四(对-乙酯苯基)卟啉LB膜的结构

对卟啉类化合物LB膜的结构、电性质和气敏性的研究已见报道。本文利用膜天平和UV-Vis分光光度计研究了标题化合物在气-液界面上的成膜特性、分子间相互作用和LB膜的结构。5,10,15,20-四(对-乙酯苯基)卟啉(TPEPP)由5,10,15,20-四(对-氰苯基)卟啉和乙醇酯化得到。元素分析测定值与计算值相符。λ(CHCl_3,nm):421,515,550,590,645;ν(KBr压

仲碳伯胺萃取铈(Ⅳ)机理的~1H,~(15)N核磁共振谱研究

仲碳伯胺N_(1923)萃取铈(Ⅳ)的~1H,~(15)N-NMR研究表明,在萃取铈(Ⅳ)时也同时萃取H_2O和H_2SO_4进入有机相,当铈(Ⅳ)浓度较高时,铈(Ⅳ)与N_(1923)生成配合物。

原子吸收光谱法测定人参中15个微量元素

本文研究了火焰原子吸收,石墨炉原子吸收,结合基体改进剂和平台技术,测定了人参中Pb、Ca、Co、Ni、Cr、Ba、K、Na、Cd、Mg、Fe、Cu、Zu、Mn、Sr等十五个微量元素,结果满意。

Pr_xLa_(1-x)P_5O_(15)晶体的荧光动力学研究

本文利用 Pr~(3+)离子在 Pr_xLa_(1-x)P_5O_(14)晶体中的光谱性质和能级,在考虑~3P_o-~1D_2和~3H_4-~3H_6,~1D_2-~1D_4和~3H_4-~3F_4两个能级对交叉弛豫的情况下,详细研究了 Pr~(3+)离子的荧光动力学过程,给出了~3P_o,~1D_2和~1G_4能级的荧光发射规律。