Capacidades infraestructurales y la construcción de sinergias estatales para el desarrollo. Buscando al "enraizamiento" en las políticas de promoción a los actores económico territoriales, en el Estado provincial de Santa Fe, de los '90

Partiendo de comprender la centralidad que adquiere la adopción, por parte de las estructuras estatales (en este caso las regionales), de la capacidad para penetrar en la sociedad y desarrollar un alto poder operativo a partir de nutrirse de las energías, conocimientos y recursos de esta. Realizamos un estudio sobre la existencia y calidad de esta que denominamos capacidad infraestructural, dentro de oficinas estratégicamente prioritarias del Estado provincial de Santa Fe, durante la década del ?90. Sobre estas oficinas, seleccionadas por encontrarse directamente vinculadas a la producción e implementación de políticas de desarrollo del sistema productivo industrial regional, veremos primero aquellas estrategias de vinculación encaradas por el Estado regional hacia la sociedad, evaluando dentro de los programas que implementa para ello, la existencia de instancias de participación conjunta con los actores territoriales directamente implicados, ya sea dentro de los objetivos originalmente formulados o como resultado de su desarrollo. Luego de esta mirada hacia el actor estatal, consideraremos al enraizamiento desde la visión de los propios actores institucionales y socioeconómicos implicados en las acciones más significativas realizadas por el Estado regional. Allí indagaremos especialmente el modo en que los actores territoriales perciben a los procesos de involucramiento y el impacto de las políticas encaradas, para la creación de condiciones institucionales y económicas favorables, verificando si estos actores reconocen en ellas un mecanismo de participación y actuación conjunta con el Estado

Las luchas estudiantiles en Santa Fe : Del Golpe de Onganía al primer paro nacional de la CGT de 1966

Fil: Bonavena, Pablo. Universidad Nacional de La Plata. Facultad de Humanidades y Ciencias de la Educación; Argentina.

Capacidades infraestructurales y la construcción de sinergias estatales para el desarrollo. Buscando al "enraizamiento" en las políticas de promoción a los actores económico territoriales, en el Estado provincial de Santa Fe, de los '90

Partiendo de comprender la centralidad que adquiere la adopción, por parte de las estructuras estatales (en este caso las regionales), de la capacidad para penetrar en la sociedad y desarrollar un alto poder operativo a partir de nutrirse de las energías, conocimientos y recursos de esta. Realizamos un estudio sobre la existencia y calidad de esta que denominamos capacidad infraestructural, dentro de oficinas estratégicamente prioritarias del Estado provincial de Santa Fe, durante la década del ?90. Sobre estas oficinas, seleccionadas por encontrarse directamente vinculadas a la producción e implementación de políticas de desarrollo del sistema productivo industrial regional, veremos primero aquellas estrategias de vinculación encaradas por el Estado regional hacia la sociedad, evaluando dentro de los programas que implementa para ello, la existencia de instancias de participación conjunta con los actores territoriales directamente implicados, ya sea dentro de los objetivos originalmente formulados o como resultado de su desarrollo. Luego de esta mirada hacia el actor estatal, consideraremos al enraizamiento desde la visión de los propios actores institucionales y socioeconómicos implicados en las acciones más significativas realizadas por el Estado regional. Allí indagaremos especialmente el modo en que los actores territoriales perciben a los procesos de involucramiento y el impacto de las políticas encaradas, para la creación de condiciones institucionales y económicas favorables, verificando si estos actores reconocen en ellas un mecanismo de participación y actuación conjunta con el Estado

Las luchas estudiantiles en Santa Fe : Del Golpe de Onganía al primer paro nacional de la CGT de 1966

Fil: Bonavena, Pablo. Universidad Nacional de La Plata. Facultad de Humanidades y Ciencias de la Educación; Argentina.

¡Una señora luz! : capitana de empresas románticas, la madona, la fe y la dama, uno no viene al mundo a pasear

Fondo Margaritainés Restrepo

De la reticencia en el contrato de seguro: un estudio sobre la inobservancia al principio de la buena fe contractual y sus consecuencias

42 p.

Chemical similarities between Galactic bulge and local thick disk red giants: O, Na, Mg, Al, Si, Ca, and Ti

Context. The formation and evolution of the Galactic bulge and its relationship with the other Galactic populations is still poorly understood. Aims. To establish the chemical differences and similarities between the bulge and other stellar populations, we performed an elemental abundance analysis of alpha- (O, Mg, Si, Ca, and Ti) and Z-odd (Na and Al) elements of red giant stars in the bulge as well as of local thin disk, thick disk and halo giants. Methods. We use high-resolution optical spectra of 25 bulge giants in Baade's window and 55 comparison giants (4 halo, 29 thin disk and 22 thick disk giants) in the solar neighborhood. All stars have similar stellar parameters but cover a broad range in metallicity (-1.5 < [Fe/H] < +0.5). A standard 1D local thermodynamic equilibrium analysis using both Kurucz and MARCS models yielded the abundances of O, Na, Mg, Al, Si, Ca, Ti and Fe. Our homogeneous and differential analysis of the Galactic stellar populations ensured that systematic errors were minimized. Results. We confirm the well-established differences for [alpha/Fe] at a given metallicity between the local thin and thick disks. For all the elements investigated, we find no chemical distinction between the bulge and the local thick disk, in agreement with our previous study of C, N and O but in contrast to other groups relying on literature values for nearby disk dwarf stars. For -1.5 < [Fe/H] < -0.3 exactly the same trend is followed by both the bulge and thick disk stars, with a star-to-star scatter of only 0.03 dex. Furthermore, both populations share the location of the knee in the [alpha/Fe] vs. [Fe/H] diagram. It still remains to be confirmed that the local thick disk extends to super-solar metallicities as is the case for the bulge. These are the most stringent constraints to date on the chemical similarity of these stellar populations. Conclusions. Our findings suggest that the bulge and local thick disk stars experienced similar formation timescales, star formation rates and initial mass functions, confirming thus the main outcomes of our previous homogeneous analysis of [O/Fe] from infrared spectra for nearly the same sample. The identical a-enhancements of thick disk and bulge stars may reflect a rapid chemical evolution taking place before the bulge and thick disk structures we see today were formed, or it may reflect Galactic orbital migration of inner disk/bulge stars resulting in stars in the solar neighborhood with thick-disk kinematics.

Thermodynamic self-consistency issues related to the Cluster Variation Method: The case of the BCC Cr-Fe (Chromium-Iron) system

The Cluster Variation Method (CVM), introduced over 50 years ago by Prof. Dr. Ryoichi Kikuchi, is applied to the thermodynamic modeling of the BCC Cr-Fe system in the irregular tetrahedron approximation, using experimental thermochemical data as initial input for accessing the model parameters. The results are checked against independent data on the low-temperature miscibility gap, using increasingly accurate thermodynamic models, first by the inclusion of the magnetic degrees of freedom of iron and then also by the inclusion of the magnetic degrees of freedom of chromium. It is shown that a reasonably accurate description of the phase diagram at the iron-rich side (i.e. the miscibility gap borders and the Curie line) is obtained, but only at expense of the agreement with the above mentioned thermochemical data. Reasons for these inconsistencies are discussed, especially with regard to the need of introducing vibrational degrees of freedom in the CVM model. (C) 2008 Elsevier Ltd. All rights reserved.

Influence of Mg content on the microstructure and solid solution chemistry of Al-7%Si-Mg casting alloys during solution treatment

The solution treatment stage of the T6 heat-treatment of Al-7%Si-Mg foundry alloys influences microstructural features such as Mg2Si dissolution, and eutectic silicon spheroidisation and coarsening. Microstructural and microanalytical studies have been conducted across a range of Sr-modified Al-7%Si alloys, with an Fe content of 0.12% and Mg contents ranging from 0.3-0.7wt%. Qualitative and quantitative metallography have shown that, in addition to the above changes, solution treatment also results in changes to the relative proportions of iron-containing intermetallic particles and that these changes are composition-dependent. While solution treatment causes a substantial transformation of pi phase to beta phase in low Mg alloys (0.3-0.4%), this change is not readily apparent at higher Mg levels (0.6-0.7%). The pi to beta transformation is accompanied by a release of Mg into the aluminum matrix over and above that which arises from the rapid dissolution of Mg2Si. Since the level of matrix Mg retained after quenching controls an alloy's subsequent precipitation hardening response, a proper understanding of this phase transformation is crucial if tensile properties are to be maximised.

The microstructure of mechanically alloyed MoSi2 with Ni and Al additions

The effect of Ni and Al additions on grain boundary silica in mechanically alloyed and hot isostatically pressed (HTPed) MoSi2 was investigated. Mechanical alloying Mo and Si in the absence of Al produced finely dispersed silica within a fine grained structure. Mechanically alloyed and HIPed Mo and Si with Ni and Al partially transformed the silica to crystalline oxide phases, including Al2O3. An improvement in high temperature properties is not expected due to the retention of a grain boundary silica film. Rapid grain growth resulted during HIPing, possibly due to the formation of a Ni/Fe/Al liquid phase.

Mass balance characterisation of Al-7Si-Mg alloy microstructures as a function of solution treatment time

Mass balance calculations were performed to model the effect of solution treatment time on A356 and A357 alloy microstructures. Image analysis and electron probe microanalysis were used to characterise microstructures and confirm model predictions. In as-cast microstructures, up to 8 times more Mg is tied up in the pi-phase than in Mg2Si. The dissolution of pi is accompanied by a corresponding increase in the amount of beta-phase. This causes the rate of pi dissolution to be limited by the rate of beta formation. It is predicted that solution treatments of the order of tens of minutes at 540degreesC produce near-maximum T6 yield strengths, and that Mg contents in excess of 0.52 wt% have no advantage.

Novel neutral iron(II) isocyanide maleonitrile dithiolate [Fe(S2C2(CN)2)(t-BuNC) 4] compound

FeBr2 reacts with the S2C2(CN)22- ion (1:1 ratio) in the presence of an excess of t-BuNC in THF to give the mixed ligand [Fe(S2C2(CN)2)(t-BuNC) 4] compound. This neutral product with a formal oxidation state of two for the iron atom was characterized by conductivity measurements, and, i.r., Mössbauer, 13C and 1H n.m.r. spectroscopy. There is a Fe-C p back-donation strengthened towards isocyanide ligands, according to the data of 13C, 1H n.m.r. and Mössbauer spectroscopy.