Biodegradability of commercial and weathered diesel oils

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Radioactivity distribution in some Permian sediments from the Irati and Corumbatal formations of the Parana basin, southeastern Brazil

in the city of Limeira, southeastern Brazil, an important exposure of Permian sediments of the Parana basin was revealed by an open pit mine that exploits limestone for production of soil correction compounds and raw materials for the ceramic industry. The radioactivity of these sediments was investigated in some detail and the results provided a general view of the vertical distributions of uranium, thorium and potassium concentrations and of the element ratios U/K, U/Th and Th/K. In general, the concentrations of the main natural radioactive elements are low, with uranium being enriched in some limestone and shale levels. In addition the results showed that the U-238 series is in radioactive disequilibrium in many of the analyzed samples. Although the origin of the observed disequilibrium has not been investigated, the results suggest that it is due to weathering processes and water interaction with the rock matrix. (C) 2003 Elsevier Ltd. All rights reserved.

Hydrothermal rare earth elements mineralization in the Barra do Itapirapua carbonatite, southern Brazil: behaviour of selected trace elements and stable isotopes (C, O)

The Bura do Itapira pua carbonatite is located in southern Brazil and belongs to the Cretaceous Ponta Grossa alkaline-carbonatitic province related to the opening of the South Atlantic. The carbonatite complex is emplaced in Proterozoic granites and is mainly composed of plutonic magnesio- to ferrocarbonatite, with smaller amounts of subvolcanic magnesiocarbonatite. Hydrothermal alteration of the carbonatite has led to the formation of quartz, apatite, fluorite, rue earth fluorocarbonates, barite and sulfides in variable proportions. Trace element data, delta(13)C and delta(18)O are presented here, with the aim of better understanding the geochemical nature of hydrothermal alteration related to rare earth elements (REE) mineralization. The non-overprinted plutonic carbonatite shows the lowest REE contents, and its primitive carbon and oxygen stable isotopic composition places it in the field of primary igneous carbonatites. Two types of hydrothermally overprinted plutonic carbonatites can be distinguished based on secondary minerals and geochemical composition. Type I contains mainly quartz, rare earth fluorocarbonates and apatite as hydrothermal secondary minerals, and has steep chondrite normalized REE patterns, with Sigma(REE+Y) of up to 3 wt.% (i.e., two orders of magnitude higher than in fresh plutonic samples). In contrast, the Type II overprint contains apatite, fluorite and barite as dominant hydrothermal minerals, and is characterized by heavy REE enrichment relative to the fresh samples, with flat chondrite normalized REE patterns. Carbon and oxygen stable isotope ratios of Types I and II are elevated (delta(18)O + 8 to + 12 parts per thousand; delta(13)C - 6 to - 2 parts per thousand) relative to the fresh samples. Hydrothermally overprinted carbonatites exposed to weathering show even higher delta(18)O values (delta(18)O 13 to 25 parts per thousand) but no additional REE enrichment. The subvolcanic carbonatite has anomalously high delta(13)C of up to + 1 parts per thousand, which suggests crustal contamination through interaction with carbonate-bearing metasediments. (C) 1999 Elsevier B.V. B.V. All rights reserved.

Caracterização da matéria-prima cerâmica da Mina Tabajara (Limeira, SP)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Growth rates in modern speleothems from Santana Cave, Brazil, by the Pb-210-method

The Santana Cave is located at the Upper Ribeira Touristic State Park (PETAR-Parque Estadual Turistico do Alto Ribeira) in southern São Paulo State, Brazil. This paper describes Pb-210 activity concentration data in soda straw stalactites samples collected at Salao das Flores in Santana Cave that is a fossil tributary of the cave river. Non-expensive alpha counting following some analytical steps for extracting and depositing Pb-210 were used for providing the Pb-210 data. In the analyzed samples, Pb-210 values of increasingly older samples fitted an exponential curve, thus suggesting that the production of Pb-210 has been constant with time. Also, the near-ideal fit indicated that the growth was uniform and there was no break in the continuous growth. The soda straw growth rates were determined from the best fit to the exponential curve through the Pb-210 activity concentration. The results of the measurements allowed estimate a longitudinal rate corresponding to 1.3 mm/yr and a lateral rate of 0.01 mm/yr, which permitted calculate times of 70 years and 317-498 years for their formation, respectively. The lateral growth rate is compatible with values from studies of chemical weathering rates held under laboratory and natural conditions. (C) 2011 Elsevier Ltd. All rights reserved.

Pb-210 and composition data of near-surface sediments and interstitial waters evidencing anthropogenic inputs in Amazon River mouth, Macapa, Brazil

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Podzolization as a deferralitization process: dynamics and chemistry of ground and surface waters in an Acrisol-Podzol sequence of the upper Amazon Basin

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Gênese de solos derivados de rochas ultramáficas serpentinizadas no sudoeste de Minas Gerais

Os solos derivados de rochas serpentinizadas ou serpentinitos constituem um grupo especial de solos em toda superfície terrestre. de caráter ultramáfico, ou seja, rochas com mais de 70 % de minerais máficos (ferromagnesianos), os serpentinitos apresentam uma mineralogia pobre em sílica e escassa em Al, sendo, no entanto, muito enriquecida em Mg. São poucos os estudos sobre a morfologia, mineralogia, gênese e classificação dos solos desenvolvidos de tais rochas. em ambiente tropical úmido no sudoeste de Minas Gerais, na zona do greenstone belt do Morro de Ferro, em superfícies geomórficas jovens, três perfis de solos representativos dessa paisagem sobre rochas serpentinizadas foram caracterizados por meio de descrições macro e micromorfológicas, análises granulométricas, químicas e por mineralogia de raios X das frações argila e silte. Complementarmente, para acompanhamento da alteração geoquímica dos horizontes do solo, foram feitas microanálises das seções delgadas por EDRX. Os solos foram classificados como Chernossolo Háplico Férrico típico, Cambissolo Háplico eutroférrico léptico e Neossolo Regolítico eutrófico típico e, embora situados num clima que favorece o rápido intemperismo, do ponto de vista morfológico e mineralógico, mostraram-se similares aos solos derivados de rochas serpentinizadas das regiões subtropicais e temperada. No processo de formação de solo, a evolução da trama segue a seguinte seqüência: alteração da rocha ® trama frâgmica ® trama porfírica com cavidades ® trama porfírica aberta por coalescência de cavidades. O processo de argiluviação é evidente e se dá em dois estádios distintos: argiluviação primária, que ocorre nas fendas e cavidades que se formam por alteração de rocha, e argiluviação secundária, verificada na porosidade mais aberta e evoluída da coalescência das cavidades. Os solos apresentam mineralogia pouco comum para solos tropicais, com presença de minerais primários de fácil decomposição até mesmo na fração argila, com destaque para o talco, clorita trioctaedral e ocorrência limitada de tremolita, sendo esta última abundante na fração silte. Óxidos de Fe, caulinita e os interestratificados de clorita-esmectita e de clorita-vermiculita completam a assembléia mineralógica. A tendência de evolução é para B textural ou para B nítico com mineralogia 1:1 e alto conteúdo de óxidos de Fe. Nas fases iniciais de alteração, os alteromorfos já apresentam composição química similar aos agregados do solo, com forte perda de Mg, Ca e Si e acúmulo relativo de Al e Fe. Nas três situações estudadas, ocorreu um rejuvenescimento superficial por erosão diferencial, que acumulou material grosseiro e removeu os finos, contribuindo para o incremento da relação textural.

Variabilidade espacial do pH, Ca, Mg e V% do solo em diferentes formas do relevo sob cultivo de cana-de-açúcar

Em uma paisagem natural, os solos apresentam uma ampla variação dos atributos químicos, tanto vertical como horizontal, resultante da interação dos diversos fatores de formação envolvidos. Este trabalho foi desenvolvido em Guariba-SP, com o objetivo de avaliar a variabilidade espacial do pH, cálcio (Ca), magnésio (Mg) e saturação por bases (V%) em um Latossolo Vermelho eutroférrico sob cultivo de cana-de-açúcar, utilizando-se métodos da estatística clássica, análise geoestatística e técnica de interpolação de dados, com a finalidade de observar padrões de ocorrência destes atributos na paisagem. No terço inferior da encosta, após análise detalhada da variação do gradiente do declive, caracterizaram-se dois compartimentos (I e II), sob os quais os solos foram amostrados nos pontos de cruzamento de uma malha, com intervalos regulares de 50m, perfazendo um total de 206 pontos, nas profundidades de 0,0-0,2m e 0,6-0,8m. Os maiores alcances foram observados na profundidade de 0,0-0,2m para todos os atributos estudados, com exceção do cálcio que apresentou comportamento inverso, refletindo os efeitos do maior grau de intemperismo e do manejo na variabilidade natural dos solos. Pequenas variações, nas formas do relevo, condicionam variabilidade diferenciada para os atributos químicos.

Propriedades reológicas de matérias-primas do Pólo Cerâmico de Santa Gertrudes provenientes da Formação Corumbataí (região de Rio Claro, SP)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Variabilidade espacial da textura de um latossolo sob cultivo de citros

O relevo influencia a variabilidade da textura, uma vez que condiciona o tempo de exposição dos materiais à ação do intemperismo. Neste trabalho, desenvolvido no município de Gavião Peixoto (SP), objetivou-se caracterizar a variabilidade espacial da textura de um Latossolo Vermelho distrófico sob cultivo de citros. A encosta foi dividida em três segmentos: topo, meia encosta e encosta inferior. O solo foi amostrado em malha, com intervalos regulares de 50 m, perfazendo o total de 332 pontos em uma área de 83,5 ha, nas profundidades de 0,0-0,2 m e 0,6-0,8 m. Os dados foram submetidos à análise estatística descritiva e geoestatística (modelagem de semivariogramas e mapas de krigagem). O comportamento espacial da textura de latossolos está diretamente relacionado com as formas do relevo neste estudo, que controla o sentido dos fluxos de água superficial e subsuperficial. O conceito de homogeneidade da distribuição de argila no perfil dos latossolos é uma informação que pode ser ajustada pelo conhecimento do padrão espacial dessa distribuição em diferentes formas do relevo.

Podzolization as a deferralitization process: a study of an Acrisol-Podzol sequence derived from Palaeozoic sandstones in the northern upper Amazon Basin

Morphological, geochemical and mineralogical studies were carried out in a representative soil catena of the low-elevation plateaux of the upper Amazon Basin to interpret the steps and mechanisms involved in the podzolization of low-activity clay soils. The soils are derived from Palaeozoic sandstones. They consist of Hydromorphic Podzols under tree savannah in the depressions of the plateaux and predominantly of Acrisols covered by evergreen forest elsewhere.Incipient podzolization in the uppermost Acrisols is related to the formation of organic-rich A and Bhs horizons slightly depleted in fine-size particles by both mechanical particle transfer and weathering. Weathering of secondary minerals by organic acids and formation of organo-metallic complexes act simultaneously over short distances. Their vertical transfer is limited. Selective dissolution of aluminous goethite, then gibbsite and finally kaolinite favour the preferential cheluviation of first Fe and secondly Al. The relatively small amount of organo-metallic complexes produced is related to the quartzitic parent materials, and the predominance of Al over Fe in the spodic horizons is due to the importance of gibbsite in these low-activity clay soils.Morphologically well-expressed podzols occur in strongly iron-depleted topsoils of the depression. Mechanical transfer and weathering of gibbsite and kaolinite by organic acids is enhanced and leads to residual accumulation of sands. Organo-metallic complexes are translocated in strongly permeable sandy horizons and impregnate at depth the macro-voids of embedded soil and saprolite materials to form the spodic Bs and 2BCs horizons. Mechanical transfer of black particulate organic compounds devoid of metals has occurred later within the sandy horizons of the podzols. Their vertical transfer has formed well-differentiated A and Bh horizons. Their lateral removal by groundwater favours the development of an albic E horizon. In an open and waterlogged environment, the general trend is therefore towards the removal of all the metals that have initially accumulated as a response to the ferralitization process and have temporarily been sequestrated in organic complexes in previous stages of soil podzolization.

The U-isotopes modeling in aquifers from Pocos de Caldas plateau, Brazil

U-modeled groundwater residence times were estimated by changes in U-234/U-238 activity ratio (AR) and U content of groundwaters from Pocos de Caldas city situated at the Pocos de Caldas alkaline massif, Brazil. The estimated ages are more realistic than others generated by the use of hydraulic conductivity data and available information about the weathering rate of rocks in the plateau. The U-234/U-238 AR and reciprocal of the dissolved U-content data also defined a ternary plot that allowed the calculation of the relative volume of three source waters for the mixed water. Such U-isotopes modeling for mixing calculations indicated that the dominant phase (68%) in the mixture is thermal.

ENHANCEMENT OF U-234 IN SPRINGWATERS OF AGUAS-DA-PRATA, SAO-PAULO, BRAZIL

Springwater samples were collected at Aguas da Prata, an important spa in São Paulo State, Brazil. The U-238 and U-234 isotopes were evaluated for Platina, Paiol, Villela, Prata-Radioativa, Prata-Nova, Boi, Vitoria, and Prata-Antiga springs. An inverse logarithmic correlation was found between U-234/U-238 activity ratio and Rn-222 content of the studied waters, which was related to different solution mechanisms of Rn-222 and U-234 nuclides at the rock-water interface. A linear correlation also exists between the U-234/U-238 activity ratios of the studied waters and total dissolved solids, ionic strength, CO2 partial pressure, and index of base exchange, which indicates that the enhancement of U-234 in solution increases with the degree of weathering in the aquifers, A higher U-234/U-238 activity ratio was found to be directly related to a higher value of dissolution rate.

Mineralogy and forms of potassium in red yellow latosol of a guava (Psidium guajava) tree orchard

A trial was conducted during 1994-95 to study the effect of potassium fertilization on a guava (Psidium guajava L.) culture for 3 years. The control plots (without K) showed fruit production and potassium exportation that did not agree with the levels obtained by chemical analysis of the soil. Physical, chemical, mineralogic and morphologic analyses were performed on the red yellow latosol to identify minerals able to supply potassium, with emphasis on the fact that guava trees have a considerably widespread root system. The results obtained confirmed the presence of minerals in this soil that can supply potassium to the trees through weathering. Feldspars were identified in the silt fraction and micas in the clay fraction by X-ray diffractometry. The determination of total potassium revealed that the silt fraction of the soil had the largest absolute amounts of potassium, followed by clay. However, in view of its greater content, clay was the fraction that contributed most to the total amounts of potassium detected.