Siliceous components of Pliocene-Holocene sediments of the South Atlantic

The Pliocene-Holocene sediments recovered on ODP Leg 114 from Holes 699A, 701C, and 704B are the subject of a detailed investigation to interpret changes in the Oceanographic environment of the South Atlantic in the vicinity of the Polar Front Zone (PFZ). The cores sample sediments at shallow (Hole 704B, 2532 m), intermediate (Hole 699A, 3716 m), and basinal (Hole 701C, 4647 m) depths. Sites 699 and 704 come under the influence of the Antarctic Circumpolar Current (ACC) and Circumpolar Deep Water. It is possible that the upper reaches of Antarctic Bottom Water (AABW) may also affect Hole 699A. Site 701 is influenced by AABW. Closely spaced samples were analyzed for grain-size distribution, sand fraction components, biosiliceous microfossils, organic carbon, and water content. PFZ migrations are traced using changes in bulk sedimentaccumulation rates and the abundance of the diatoms Actiniscus ssp. and Genus et species indet. 1 Fenner (1991), as well as changes in sediment grain size and composition. Diatomaceous sediments of Gilbert age in Hole 699A indicate that the PFZ was positioned over this site, but during the Gauss it migrated north, bringing in less productive Antarctic Surface Water. All cores document a very gradual southerly movement of the PFZ throughout the Matuyama (with some sharp fluctuations of the northen PFZ border over Site 704 between 1.45 and 1.83 m.y.). This regressive shift culminated in the late Matuyama. The latest Matuyama to earliest Brunhes record in Hole 699A has been removed by a hiatus lasting from 1.0 to 0.6 m.y., which was probably caused by intensification of the deep-reaching ACC. The corresponding interval in Hole 704B, the shallowest core, contains evidence of winnowing. Sharp fluctuations of large amplitude and high frequency in the lithology of the sediments from Hole 704B in the eastern South Atlantic, starting at about 0.75 m.y. and characterizing the whole Brunhes Epoch, record the rapid movement of the northern border of the PFZ over the site. These reflect strong glacial/interglacial alternations in climate. To a lesser extent, lithologic fluctuations in Hole 701C reflect the same phenomenon, whereas in Hole 699A the lithology does not vary as dramatically.

Concentrations and accumulation rates of chemical elements and sediment components in sediments of central equatorial Pacific, DSDP data

Accumulation rates of Mg, Al, Si, Mn, Fe, Ni, Cu, Zn, opal, and calcium carbonate have been calculated from their concentrations in samples from equatorial Deep Sea Drilling Project sites. Maps of element accumulation rates and of Q-mode factors derived from raw data indicate that the flux of trace metals to equatorial Pacific sediments has varied markedly through time and space in response to changes in the relative and absolute influence of several depositional influences: biogenic, detrital, authigenic, and hydrothermal sedimentation. Biologically derived material dominates the sediment of the equatorial Pacific. The distributions of Cu and Zn are most influenced by surface-water biological activity, but Ni, Al, Fe, and Mn are also incorporated into biological material. All of these elements have equatorial accumulation maxima similar to those of opal and calcium carbonate at times during the past 50 m.y. Detritus distributed by trade winds and equatorial surface circulation contributes Al, non-biogenic Si, Fe, and Mg to the region. Detrital sediment is most important in areas with a small supply of biogenic debris and low bulk-accumulation rates. Al accumulation generally increases toward the north and east, indicating its continental source and distribution by the northeast trade winds. Maxima in biological productivity during middle Eocene and latest Miocene to early Pliocene time and concomitant well-developed surface circulation contributed toward temporal maxima in the accumulation rates of Cu, Zn, Ni, and Al in sediments of those ages. Authigenic material is also important only where bulk-sediment accumulation rates are low. Ni, Cu, Zn, and sometimes Mn are associated with this sediment. Fe is almost entirely of hydrothermal origin. Mn is primarily hydrothermal, but some is probably scavenged from sea water by amorphous iron hydroxide floes along with other elements concentrated in hydrothermal sediments, Ni, Cu, and Zn. During the past 50 m.y. all of these elements accumulated over the East Pacific Rise at rates nearly an order of magnitude higher than those at non-rise-crest sites. In addition, factor analysis indicates that some of this material is carried substantial distances to the west of the rise crest. Accumulation rates of Fe in basal metalliferous sediments indicate that the hydrothermal activity that supplied amorphous Fe oxides to the East Pacific Rise areas was most intense during middle Eocene and late Miocene to early Pliocene time.

Calcite accumulation in the eastern equatorial Pacific

The eastern equatorial Pacific (EEP) is an important center of biological productivity, generating significant organic carbon and calcite fluxes to the deep ocean. We reconstructed paleocalcite flux for the past 30,000 years in four cores collected beneath the equatorial upwelling and the South Equatorial Current (SEC) by measuring ex230Th-normalized calcite accumulation rates corrected for dissolution with a newly developed proxy for "fraction of calcite preserved". This method produced very similar results at the four sites and revealed that the export flux of calcite was 30-50% lower during the LGM compared to the Holocene. The internal consistency of these results supports our interpretation, which is also in agreement with emerging data indicating lower glacial productivity in the EEP, possibly as a result of lower nutrient supply from the southern ocean via the Equatorial Undercurrent. However, these findings contradict previous interpretations based on mass accumulation rates (MAR) of biogenic material in the sediment of the EEP, which have been taken as reflecting higher glacial productivity due to stronger wind-driven upwelling.

Ages and geochemical and geophysical characteristics of sediment core MD99-2294, Lofoten Contourite Drift

A sediment core from the Lofoten Contourite Drift on the continental slope off Northern Norway, proximal to the former Vestfjorden-Trsnadjupet Ice Stream, details the development, variability and decline of marine margins of the northwestern Fennoscandian Ice Sheet during the time interval 25.3-14 cal ka BP, including the Last Glacial Maximum and onset of the deglaciation based on high-resolution IRD records. From the core interval between 25.3 and 17.7 cal ka BP we report data points with a mean time step of 10 years, between 17.7 cal ka BP and the Holocene time steps are typically 50 years. The core is divided into 7 informal ice-rafted debris (IRD) zones based on the variations in IRD including 7 major IRD maxima (A-G), inferred to represent periods of high iceberg production. Petrological identification reveals dominance of crystalline IRD (monocrystalline, plutonic and metamorphic rock fragments) accounting for 75-80% of total IRD assemblages, while sedimentary fragments generally account for 15-20%. The crystalline fragments (including eclogite and mangerite from a nearby terrestrial source) increase across the IRD peaks while the sedimentary fragments remain constant. This points to the importance of erosional products from icebergs originating from fast-flowing paleo-ice streams including the Vestfjorden-Trsnadjupet Ice Stream draining from the Fennoscandian mainland during the IRD maxima periods. Increased temperature of the adjacent surface water masses was probably an important external forcing factor on the Fennoscandian Ice Sheet behavior because some IRD maxima and plumite deposition from meltwater plumes post-date periods of increased sea surface temperatures. The peak IRD depositions occur in centennial and millennial time cycles (~200, 1030 and 3900 year) indicating some external forcing by solar variation. Both mechanisms could explain the observed synchronous instability of the northwestern Fennoscandian Ice Sheet to other European Ice Sheets.

Age determination of hornblende in ODP Site 188-1165 and DSDP Hole 28-268

Sediments from Ocean Drilling Program Site 1165 in the Indian Ocean sector of the Southern Ocean (off Prydz Bay) contain a series of layers that are rich in ice-rafted debris (IRD). Here we present evidence that IRD-rich layers at Site 1165 at 7, 4.8, and 3.5 Ma record short-lived, massive discharges of icebergs from Wilkes Land and Adélie Land, more than 1500 kilometers to the east of the depositional site. This distant source of icebergs is clearly defined by the presence of IRD hornblende grains with 40Ar/39Ar ages of 1200-1100 Ma and 1550-1500 Ma, ages that are not found on the East Antarctic continent in locations closer to Site 1165. This observation requires enormous amounts of detritus-carrying drifting icebergs, most likely in the form of large icebergs. These events probably reflect destabilization, surge, and break-up of ice streams on the Wilkes Land and Adélie Land margins of the East Antarctic Ice Sheet, in the vicinity of the low-lying Aurora and Wilkes Basins. They occurred under warming conditions, but each coast seems to have produced ice-rafting events independently, at different times. The data presented here constitute the first evidence of far-traveled icebergs from specific source areas around the East Antarctic perimeter. Launch of these icebergs may have happened during quite dramatic events, perhaps analogous to "Heinrich Events" in the North Atlantic.

Sea surface reconstruction of sediment cores off West Spitsbergen

Two sediment cores from the West Spitsbergen area, Euro-Arctic margin, MD99-2304 and MD99-2305, have been investigated for paleoceanographic proxies, including benthic and planktonic foraminifera, benthic foraminiferal stable isotopes and ice rafted debris. Core MD99-2304 is located on the upper continental margin, reflecting variations in the influx of Atlantic Water in the West Spitsbergen Current. Core MD99-2305 is located in Van Mijenfjord, picturing variations in tidewater glacier activity as well as fjord-ocean circulation changes. Surface water warmer than today, was present on the margin as soon as the Van Mijenfjord was deglaciated by 11,200 cal. years BP. Relatively warm water invaded the fjord bottom almost immediately after the deglaciation. A relatively warm early Holocene was followed by an abrupt cooling at 8800 cal. years BP on the continental margin. Another cooling in the fjord record, 8000-4000 cal. years BP, is documented by an increase in ice rafted debris and an increase in benthic foraminiferal delta18O. The IRD-record indicates that central Spitsbergen never was completely deglaciated during the Holocene. Relatively cool and stable conditions similar to the present were established about 4000 cal. years BP.

Biogenic sedimentation of DSDP Site 85-574

The equatorial Pacific is an important part of the global carbon cycle and has been affected by climate change through the Cenozoic (65 Ma to present). We present a Miocene (12-24 Ma) biogenic sediment record from Deep Sea Drilling Project (DSDP) Site 574 and show that a CaCO3 minimum at 17 Ma was caused by elevated CaCO3 dissolution. When Pacific Plate motion carried Site 574 under the equator at about 16.2 Ma, there is a minor increase in biogenic deposition associated with passing under the equatorial upwelling zone. The burial rates of the primary productivity proxies biogenic silica (bio-SiO2) and biogenic barium (bio-Ba) increase, but biogenic CaCO3 decreases. The carbonate minimum is at ~17 Ma coincident with the beginning of the Miocene climate optimum; the transient lasts from 18 to 15 Ma. Bio-SiO2 and bio-Ba are positively correlated and increase as the equator was approached. Corg is poorly preserved, and is strongly affected by changing carbonate burial. Terrestrial 232Th deposition, a proxy for aeolian dust, increases only after the Site 574 equator crossing. Since surface production of bio-SiO2, bio-Ba, and CaCO3 correlate in the modern equatorial Pacific, the decreased CaCO3 burial rate during the Site 574 equator crossing is driven by elevated CaCO3 dissolution, representing elevated ocean carbon storage and elevated atmospheric CO2. The length of the 17 Ma CaCO3 dissolution transient requires interaction with a 'slow' part of the carbon cycle, perhaps elevated mantle degassing associated with the early stages of Columbia River Basalt emplacement.

Lithogenic sediment deposition of 7 sediment cores from the Pacific Southern Ocean

Dust deposition in the Southern Ocean constitutes a critical modulator of past global climate variability, but how it has varied temporally and geographically is underdetermined. Here, we present data sets of glacial-interglacial dust-supply cycles from the largest Southern Ocean sector, the polar South Pacific, indicating three times higher dust deposition during glacial periods than during interglacials for the past million years. Although the most likely dust source for the South Pacific is Australia and New Zealand, the glacial-interglacial pattern and timing of lithogenic sediment deposition is similar to dust records from Antarctica and the South Atlantic dominated by Patagonian sources. These similarities imply large-scale common climate forcings such as latitudinal shifts of the southern westerlies and regionally enhanced glaciogenic dust mobilization in New Zealand and Patagonia.

Sea surface temperature estimation for the last 70 ka from IODP Site 306-U1313

During the six Heinrich Events of the last 70 ka episodic calving from the circum-Atlantic ice sheets released large numbers of icebergs into the North Atlantic. These icebergs and associated melt-water flux are hypothesized to have led to a shutdown of Atlantic Meridional Overturning Circulation (AMOC) and severe cooling in large parts of the Northern Hemisphere. However, due to the limited availability of high-resolution records the magnitude sea surface temperature (SST) changes related to the impact of Heinrich Events on the mid-latitude North Atlantic is poorly constrained. Here we present a record of UK37'-based SSTs derived from sediments of Integrated Ocean Drilling Project (IODP) Site U1313, located at the southern end of the ice-rafted debris (IRD)-belt in the mid-latitude North Atlantic (41°N). We demonstrate that all six Heinrich Events are associated with a rapid warming of surface waters by 2 to 4°C in a few thousand years. The presence of IRD leaves no doubt about the simultaneous timing and correlation between rapid surface water warming and Heinrich Events. We argue that this warming in the mid-latitude North Atlantic is related to a northward expansion of the subtropical gyre during Heinrich Events. As a wide-range of studies demonstrated that in the central IRD-belt Heinrich Events are associated with low SSTs, these results thus identify an anti-phased (seesaw) pattern in SSTs during Heinrich Events between the mid-latitude (warm) and northern North Atlantic (cold). This highlights the complex response of surface water characteristics in the North Atlantic to Heinrich Events that is poorly reproduced by fresh water hosing experiments and challenges the widely accepted view that within the IRD-belt of the North Atlantic Heinrich Events coincide with periods of low SSTs.

Organic sedimentation of ODP Sites 124-767 and 124-768

This study relates the organic sedimentation characteristics to the lithostratigraphic successionsthat were observed at Site 767 (Celebes Sea) and Site 768 (Sulu Sea) during ODP Leg 124. It is based on the total organic carbon content (TOC) of the sediments, on the petrographictype and maturity of the organic matter, and on the TOC accumulation rates calculated for the lithostratigraphic units. In the Celebes and Sulu Seas sediments, the organic matter is mainly of terrestrial origin with the highest concentrations and TOC accumulation rates occurring in the middle Miocene turbiditic sequences that correspond to a major compressive event between the Philippine Mobile Belt and the Palawan, Cagayan, and Sulu Ridges. Petrographic analysis of the Eocene and lower Miocene organic matter in the Celebes Sea shows that it consists only of highly degraded terrestrial particles. This observation and the very low TOC accumulation rates indicate poor conditions for organic carbon preservation during this open-ocean phase of the Celebes Basin formation. The organic matter, either of marine or terrestrial origin, is much better preserved in the younger sediments, suggesting physico-chemical changes in the depositional environment. Because of the dilution phenomena by turbidites, it is difficult to observe the progressive improvement of the organic matter preservation throughout the turbiditic series. The same change in preservation is broadly observed in the Sulu Sea from the early Miocene (rapid opening phase of the basin with massive pyroclastic deposits) to the present.

Radiocarbon dates, accumulation rates, d13C and July temperature of profiles obtained from Selwyn and Misaw Lake, subarctic Canada

The rapid warming of arctic regions during recent decades has been recorded by instrumental monitoring, but the natural climate variability in the past is still sparsely reconstructed across many areas. We have reconstructed past climate changes in subarctic west-central Canada. Stable carbon and oxygen isotope ratios (d13C, d18O) were derived from a single Sphagnum fuscum plant component; alpha-cellulose isolated from stems. Periods of warmer and cooler conditions identified in this region, described in terms of a "Mediaeval Climatic Anomaly" and "Little Ice Age" were registered in the temperature reconstruction based on the d13C record. Some conclusions could be drawn about wet/dry shifts during the same time interval from the d18O record, humification indices and the macrofossil analysis. The results were compared with other proxy data from the vicinity of the study area. The amplitude of the temperature change was similar to that in chironomid based reconstructions, showing c. 6.5 ±2.3 °C variability in July temperatures during the past 6.2 ka.

Stable isotope and geochemical record of ODP Hole 124-769A

Deep marine late Pleistocene sediments from Ocean Drilling Program Sulu Sea Site 769 contain a high-resolution record of paleoceanographic change in this strongly monsoonal climatic setting in the tropical western Pacific. Detailed time series of planktonic foraminifer (G.ruber; white variety) d18O, d13C, and bulk CaCO3 mass accumulation rate (MAR) were generated, spanning the last 750 k.y. Sedimentation rates in this portion of the record average 8.5 cm/k.y., and vary from 4 to 16 cm/k.y. Cross spectral analysis of the d18O and d13C time-series demonstrate that each contains increased variance at the primary orbital periodicities. The d18O record shows strong variability in the precessional-band and closely correlates with the SPECMAP d18O record and other high-resolution records. The dominance of a 23-k.y cycle in the d18O record agrees with other studies of the monsoon system in the Indian Ocean that have documented the importance of precessional insolation as a monsoon-forcing mechanism. In addition, d13C is strongly coherent, with d18O at a period of 41 k.y (obliquity), suggesting a connection between surface water CO2 chemistry in the Sulu Sea and high- latitude climatic change. The d18O and d13C time-series both contain increased spectral variance at a period of 30 k.y. Although the source of 30-k.y. variability is unknown, other studies have documented late Pleistocene Pacific Oceanographic variability with a period of 30 k.y. Major- and trace-metal analyses were performed on a second, less-detailed sample series to independently assess paleoproductivity changes and bottom-water conditions through time. Glacial periods are generally times of increased calcium carbonate and copper accumulation. The positive association between these independent indicators of paleoproductivity suggests an increase in productivity in the basin during most glacial episodes. Changing bottom-water redox conditions were also assessed using the geochemical data. Low concentrations of molybdenum throughout the record demonstrate that bottom waters at this site were never anoxic during the last 750 k.y. The bioturbated character of the sediments agrees with this interpretation.

Benthic foraminiferal accumulation rates of the late Pliocene-Pleistocene in the northern Indian Ocean

During the late Pliocene-middle Pleistocene, 63 species of elongate, bathyal-upper abyssal benthic foraminifera (Extinction Group = Stilostomellidae, Pleurostomellidae, some Nodosariidae) declined in abundance and finally disappeared in the northern Indian Ocean (ODP Sites 722, 758), as part of the global extinction of at least 88 related species at this time. The detailed record of withdrawal of these species differs by depth and geography in the Indian Ocean. In northwest Indian Ocean Site 722 (2045 m), the Extinction Group of 54 species comprised 2-15% of the benthic foraminiferal fauna in the earliest Pleistocene, but declined dramatically during the onset of the mid-Pleistocene Transition (MPT) at 1.2-1.1 Ma, with all but three species disappearing by the end of the MPT (~0.6 Ma). In northeast Indian Ocean Site 758 (2925 m), the Extinction Group of 44 species comprised 1-5% of the benthic foraminiferal fauna at ~3.3-2.6 Ma, but declined in abundance and diversity in three steps, at ~2.5, 1.7, and 1.2 Ma, with all but one species disappearing by the end of the MPT. At both sites there are strong positive correlations between the accumulation rate of the Extinction Group and proxies indicating low-oxygen conditions with a high organic carbon input. In both sites, there was a pulsed decline in Extinction Group abundance and species richness, especially in glacial periods, with some partial recoveries in interglacials. We infer that the glacial declines at the deeper Site 758 were a result of increased production of colder, well-ventilated Antarctic Bottom Water (AABW), particularly in the late Pliocene and during the MPT. The Extinction Group at shallower water depths (Site 722) were not impacted by the deeper water mass changes until the onset of the MPT, when cold, well-ventilated Glacial North Atlantic Intermediate Water (GNAIW) production increased and may have spread into the Indian Ocean. Increased chemical ventilation at various water depths since late Pliocene, particularly in glacial periods, possibly in association with decreased or more fluctuating organic carbon flux, might be responsible for the pulsed global decline and extinction of this rather specialised group of benthic foraminifera.

Eolian deposition on the Ontong Java Plateau

The record of eolian deposition on the Ontong Java Plateau (OJP) since the Oligocene (approximately 33 Ma) has been investigated using dust grain size, dust flux, and dust mineralogy, with the goal of interpreting the paleoclimatology and paleometeorology of the western equatorial Pacific. Studies of modern dust dispersal in the Pacific have indicated that the equatorial regions receive contributions from both the Northern Hemisphere westerly winds and the equatorial easterlies; limited meteorological data suggest that low-altitude westerlies could also transport dust to OJP from proximal sources in the western Pacific. Previous studies have established the characteristics of the grain-size, flux, and mineralogy records of dust deposited in the North Pacific by the mid-latitude westerlies and in the eastern equatorial Pacific by the low-latitude easterlies since the Oligocene. By comparing the OJP records with the well-defined records of the mid-latitude westerlies and the low-latitude easterlies, the importance of multiple sources of dust to OJP can be recognized. OJP dust is composed of quartz, illite, kaolinite/chlorite, plagioclase feldspar, smectite, and heulandite. Mineral abundance profiles and principal components analysis (PCA) of the mineral abundance data have been used to identify assemblages of minerals that covary through all or part of the OJP record. Abundances of quartz, illite, and kaolinite/chlorite covary throughout the interval studied, defining a mineralogical assemblage supplied from Asia. Some plagioclase and smectite were also supplied as part of this assemblage during the late Miocene and Pliocene/Pleistocene, but other source areas have supplied significant amounts of plagioclase, smectite, and heulandite to OJP since the Oligocene. OJP dust is generally coarser than dust deposited by the Northern Hemisphere westerlies or the equatorial easterlies, and it accumulates more rapidly by 1-2 orders of magnitude. These relationships indicate the importance of the local sources on dust deposition at OJP. The grain-size and flux records of OJP dust do not exhibit most of the events observed in the corresponding records of the Northern Hemisphere westerlies or the equatorial easterlies, because these features are masked by the mixing of dust from several sources at OJP. The abundance record of the Asian dust assemblage at OJP, however, does contain most of the features characteristic of dust flux by means of the Northern Hemisphere westerlies, indicating that the paleoclimatic and paleometeorologic signal of a particular source area and wind system can be preserved in areas well beyond the region dominated by that source and those winds. Identifying such a signal requires "unmixing" the various dust assemblages, which can be accomplished by combining grain-size, flux, and mineralogic data.

Glacial-interglacial bioproductivity of the Mexican Margin

Sedimentary accumulation of biogenic components (organic carbon, opal, and biogenic barium) on the northwestern Mexican margin declined during every glacial interval of the past 140 kyr, indicating decreases in upwelling-induced productivity during cold periods. The glacial-interglacial contrasts in upwelling on this margin are attributed to reversals in land-ocean thermal contrast, the waxing and waning of the Laurentide Ice Sheet, and consequent responses of the western hemisphere wind fields. This scenario is consistent with three independent lines of evidence: terrestrial paleoclimatic data, general circulation model results, and our marine records. This pattern of glacial-interglacial variability in upwelling off NW Mexico is opposite to that observed in other low-latitude and midlatitude upwelling areas, such as the eastern equatorial Pacific. These results add to a growing pool of observations that the response of oceanic upwelling to glacial climatic forcing has been regionally variable.