897 resultados para ASYMMETRIC ALLYLIC ALKYLATION


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We have investigated the isospin dependence of the neutron and proton (PF2)-P-3 superfluidity in isospin-asymmetric nuclear matter within the framework of the Brueckner-Hartree-Fock approach and the BCS theory. We show that the (PF2)-P-3 neutron and proton pairing gaps depend sensitively on isospin asymmetry of asymmetric nuclear matter. As the isospin asymmetry increases, the neutron (PF2)-P-3 superfluidity becomes stronger and the peak value of the neutron (PF2)-P-3 pairing gap increases rapidly. The isospin dependence of the proton (PF2)-P-3 superfluidity is shown to be opposite to the neutron one. The proton (PF2)-P-3 superfluidity becomes weaker at a higher asymmetry and it even vanishes at high enough asymmetries. At high asymmetries, the neutron (PF2)-P-3 superfluidity turns out to be much stronger than the proton one, implying that the neutron (PF2)-P-3 superfluidity is dominated in the highly asymmetric dense interior of neutron stars.

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We have developed the formula and the numerical code for calculating the rearrangement contribution to the single particle (s.p.) properties in asymmetric nuclear matter induced by three-body forces within the framework of the Brueckner theory extended to include a microscopic three-body force (TBF). We have investigated systematically the TBF-induced rearrangement effect on the s.p. properties and their isospin-behavior in neutron-rich nuclear medium. It is shown that the TBF induces a repulsive rearrangement contribution to the s.p. potential in nuclear medium. The repulsion of the TBF rearrangement contribution increases rapidly as a function of density and nucleon momentum. It reduces largely the attraction of the BHF s.p. potential and enhances strongly the momentum dependence of the s.p. potential at large densities and high-momenta. The TBF rearrangement effect on symmetry potential is to enhances its repulsion (attraction) on neutrons (protons) in dense asymmetric nuclear matter.

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The differential isospin-fractionation (IsoF) during the liquid-gas phase transition in dilute asymmetric nuclear matter is studied as a function of nucleon momentum. Within a self-consistent thermal model it is shown that the neutron/proton ratio of the gas phase becomes smaller than that of the liquid phase for energetic nucleons, although the gas phase is overall more neutron-rich. Clear indications of the differential IsoF consistent with the thermal model predictions are demonstrated within a transport model for heavy-ion reactions. Future comparisons with experimental data will allow us to extract critical information about the momentum dependence of the isovector strong interaction.

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The proton and neutron S-1(0), pairing gaps and their isospin dependence in isospin asymmetric nuclear matter have been studied by the isospin dependent Brueckner-Hartree-Fock approach and the BCS theory. We have focused on investigating and discussing the effect of three-body force. The calculated results indicate that as the isospin asymmetry increases, the density range of the S-1(0) neutron superfluidity is narrowed slightly and the maximum value of the neutron pairing gap increases 9 while the density domain for the proton superfluidity enlarges rapidly and the peak value of the proton gap decreases remarkably. The three-body force turns out to affect only weakly the neutron S-1(0) superfluidity and its isospin dependence, i. e., it leads to a small reduction of the neutron S-1(0) paring gap. However, the three-body force not only reduces largely the strength of the proton S-1(0) gaps at high densities in highly asymmetric nuclear matter but also suppresses strongly the density domain for the proton S-1(0) superfluidity phase.

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We investigate the S-1(0) neutron and proton superfluidity in isospin-asymmetric nuclear matter. We have concentrated on the isospin dependence of the pairing gaps and the effect of a microscopic three-body force. It is found that as the isospin asymmetry goes higher, the neutron S-1(0) superfluid phase shrinks gradually to a smaller density domain, whereas the proton one extends rapidly to a much wider density domain. The three-body force turns out to weaken the neutron S-1(0) superfluidity slightly, but it suppresses strongly the proton S-1(0) superfluidity at high densities in nuclear matter with large isospin asymmetry.

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We study the heat conduction of two nonlinear lattices joined by a weak harmonic link. When the system reaches a steady state, the heat conduction of the system is decided by the tunneling heat flow through the weak link. We present an analytical analysis by the combination of the self-consistent phonon theory and the heat tunneling transport formalism, and then the tunneling heat flow can be obtained. Moreover, the nonequilibrium molecular dynamics simulations are performed and the simulations results are consistent with the analytical predictions.

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In this Letter, we conduct an extensive study of the two-segment Frenkel-Kontorova model. We show that the rectification effect of the heat flux reported in recent literature is possible only in the weak interfacial coupling limit. The rectification effect will be reversed when the properties of the interface and the system size change. These two types of asymmetric heat conduction are governed by different mechanisms though both are induced by nonlinearity. An intuitive physical picture is proposed to interpret the reversal of the rectification effect. Since asymmetric heat conduction depends critically on the properties of the interface and the system size, it is probably not an easy task to fabricate a thermal rectifier or thermal diode in practice.

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We have investigated the equation of state (EOS) and single particle (s.p.) properties of asymmetric nuclear matter within the framework of the Brueckner-Bethe-Goldstone approach. We have discussed particularly the effect of microscopic three-body forces (TBF). It is shown that the TBF affects significantly the predicted properties of nuclear matter at high densities.

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We have investigate the nucleon superfluidity in asymmetric nuclear matter and neutron star matter by using the Brueckner-Hartree-Fock approach and the BCS theory. We have predicted the isospin-asymmetry dependence of the nucleon superfluidity in asymmetric nuclear matter and discussed particularly the effect of microscopic three-body forces. It has been shown that the three-body force leads to a strong suppression of the proton S-1(0) superfluidity in beta -stable neutron star matter. Whereas the microscopic three-body force is found to enhance remarkably the (PF2)-P-3 neutron superfluidity in neutron star matter and neutron stars.

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The in medium nucleon-nucleon (N N) cross sections in isospin asymmetric nuclear matter at various densities are investigated in the frame work of Brueckner-Hartree-Fock theory with the Bonn B two-body nucleon-nucleon inter action supplemented with a new version microscopic three-body force (TBF). The TBF depresses the amplitude of cross sections at high density region. At low densities, the proton-proton and neutron-neutron cross sections decrease while the proton-neutron one increases as the asymmetry increases. But the sensitivity of the N N cross sections to the isospin a symmetry are reduced with the increasing density.

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The production of ethylbenzene from the alkylation of dilute ethylene in fee off-gases with benzene has been commercialized in China over a newly developed catalyst composed of ZSM-5/ZSM-11 co-crystallized zeolite. The duration of an operation cycle of the commercial catalyst could be as long as 180 days. The conversion of ethylene could attain higher than 95%, while the amount of coke deposited on the catalyst was only about 10 wt.%. Thermogravimetry (TG) was used to study the coking behavior of the catalyst during the alkylation of fee off-gas with benzene to ethylbenzene. Based on effects of reaction time, reaction temperature, reactants and products on coking during the alkylation process, it is found that the coking rate during the alkylation procedure follows the order: ethylbenzene > ethylene > propylene > benzene for single component, and benzene-ethylene > benzene-propylene for bi-components under the same reaction condition. Furthermore, the coking kinetic equations for benzene-ethylene, benzene-propylene and ethylbenzene were established. (C) 2003 Elsevier B.V. All rights reserved.

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MCM-22 zeolite with mid-strong acidity and openings of 10-membered ring channels may obtain a high catalytic activity and selectivity for alkylation of toluene with methanol. The acidic sites, for catalyzing alkylation of toluene with methanol, are weaker than that for catalyzing toluene disproportionation. Compared with silicon as a modifier, modification of MCM-22 with La(NO3)(3) is a promising way to improve the catalytic selectivity of para-xylene. In addition, the experimental results also clearly indicate the characteristics of MCM-22 structure consisting of large intracrystalline cages, some of which may locate on surface of MCM-22. (C) 2004 Elsevier B.V. All rights reserved.