998 resultados para 283-1


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Anhydrite occurs in veins in hydrothermally altered basalts recovered from Hole 504B during Leg 83 of the Deep Sea Drilling Project. Sulfur isotopic data indicate that the anhydrites formed from fluids with sulfur isotopic compositions similar to seawater sulfate. Anhydrite probably formed as a pulse of relatively unreacted seawater was heated when it entered a relatively hot hydrothermal system containing evolved fluids. Reheating and continued evolution of the system followed anhydrite deposition. Preservation of anhydrite in Hole 504B was probably favored by the high temperatures and by the low permeability that resulted from the sealing of cracks with secondary minerals. Evidence also indicates that anhydrite was partly replaced by laumontite and prehnite at relatively high temperatures, and possibly by calcite at lower temperatures.

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Thesis (Master's)--University of Washington, 2016-06

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The adsorption and reaction of ethanol over Pt{1 1 1} has been investigated by Fast XPS and TPD. Ethanol adsorbs molecularly at 100 K, with a saturation coverage of 0.44 ML giving rise to C 1s components with binding energies of 283.7 eV (CH3–) and 284.8 eV (–H2COH). Ethanol multilayers desorb above 150 K, while ∼60% of the monolayer desorbs intact above 200 K in competition with decomposition pathways. Reaction initially proceeds via progressive dehydrogenation to form a metastable acetyl intermediate with components at 283.5 eV (CH3–) and 285.2 eV (-C=O), which in turn undergoes decarbonylation above 250 K to chemisorbed CO and methyl groups. A significant fraction of the latter are hydrogenated above 270 K, desorbing as CH4, with the remainder further decomposing to liberate H2 and surface CHx moeities.