Side illumination fluorescence emission characteristics from a dye doped polymer optical fiber under two-photon excitation.

Two-photon excited (TPE) side illumination fluorescence studies in a Rh6G-RhB dye mixture doped polymer optical fiber (POF) and the effect of energy transfer on the attenuation coefficient is reported. The dye doped POF is pumped sideways using 800 nm, 70 fs laser pulses from a Ti:sapphire laser, and the TPE fluorescence emission is collected from the end of the fiber for different propagation distances. The fluorescence intensity of RhB doped POF is enhanced in the presence of Rh6G as a result of energy transfer from Rh6G to RhB. Because of the reabsorption and reemission process in dye molecules, an effective energy transfer is observed from the shorter wavelength part of the fluorescence spectrum to the longer wavelength part as the propagation distance is increased in dye doped POF. An energy transfer coefficient is found to be higher at shorter propagation distances compared to longer distances. A TPE fluorescence signal is used to characterize the optical attenuation coefficient in dye doped POF. The attenuation coefficient decreases at longer propagation distances due to the reabsorption and reemission process taking place within the dye doped fiber as the propagation distance is increased.

Femtosecond pump-probe study of the spreading and recurrence of a vibrational wave packet in Na_2

The motion of a vibrational wave packet in the bound A(^1 \summe^+_u) electronic state of the sodium dimer is detected in a femtosecond pump/probe molecular beam experiment. For short times harmonic motion is seen in the total ion yield of Na^+_2 as a function of delay time between the two laser pulses. The spreading of the wave packet results in the loss of the periodic variation of the ion signal. For longer delay times (47 ps) the wave packet regains its initial form which is reflected in the revival structure of the Na^+_2 signal. Time-dependent quantum calculations reproduce the measured effects.

Entwicklung und Anwendung einer Kraftwerks- und Speichereinsatzoptimierung für die Untersuchung von Energieversorgungsszenarien mit hohem Anteil erneuerbarer Energien in Deutschland

In dieser Arbeit wurde ein gemischt-ganzzahliges lineares Einsatzoptimierungsmodell für Kraftwerke und Speicher aufgebaut und für die Untersuchung der Energieversorgung Deutschlands im Jahre 2050 gemäß den Leitstudie-Szenarien 2050 A und 2050 C ([Nitsch und Andere, 2012]) verwendet, in denen erneuerbare Energien einen Anteil von über 85 % an der Stromerzeugung haben und die Wind- und Solarenergie starke Schwankungen der durch steuerbare Kraftwerke und Speicher zu deckenden residualen Stromnachfrage (Residuallast) verursachen. In Szenario 2050 A sind 67 TWh Wasserstoff, die elektrolytisch aus erneuerbarem Strom zu erzeugen sind, für den Verkehr vorgesehen. In Szenario 2050 C ist kein Wasserstoff für den Verkehr vorgesehen und die effizientere Elektromobilität hat einen Anteil von 100% am Individualverkehr. Daher wird weniger erneuerbarer Strom zur Erreichung desselben erneuerbaren Anteils im Verkehrssektor benötigt. Da desweiteren Elektrofahrzeuge Lastmanagementpotentiale bieten, weisen die Residuallasten der Szenarien eine unterschiedliche zeitliche Charakteristik und Jahressumme auf. Der Schwerpunkt der Betrachtung lag auf der Ermittlung der Auslastung und Fahrweise des in den Szenarien unterstellten ’Kraftwerks’-parks bestehend aus Kraftwerken zur reinen Stromerzeugung, Kraft-Wärme-Kopplungskraftwerken, die mit Wärmespeichern, elektrischen Heizstäben und Gas-Backupkesseln ausgestattet sind, Stromspeichern und Wärmepumpen, die durch Wärmespeicher zum Lastmanagment eingesetzt werden können. Der Fahrplan dieser Komponenten wurde auf minimale variable Gesamtkosten der Strom- und Wärmeerzeugung über einen Planungshorizont von jeweils vier Tagen hin optimiert. Das Optimierungsproblem wurde mit dem linearen Branch-and-Cut-Solver der software CPLEX gelöst. Mittels sogenannter rollierender Planung wurde durch Zusammensetzen der Planungsergebnisse für überlappende Planungsperioden der Kraftwerks- und Speichereinsatz für die kompletten Szenariojahre erhalten. Es wurde gezeigt, dass der KWK-Anteil an der Wärmelastdeckung gering ist. Dies wurde begründet durch die zeitliche Struktur der Stromresiduallast, die wärmeseitige Dimensionierung der Anlagen und die Tatsache, dass nur eine kurzfristige Speicherung von Wärme vorgesehen war. Die wärmeseitige Dimensionierung der KWK stellte eine Begrenzung des Deckungsanteils dar, da im Winter bei hoher Stromresiduallast nur wenig freie Leistung zur Beladung der Speicher zur Verfügung stand. In den Berechnungen für das Szenario 2050 A und C lag der mittlere Deckungsanteil der KWK an der Wärmenachfrage von ca. 100 TWh_th bei 40 bzw. 60 %, obwohl die Auslegung der KWK einen theoretischen Anteil von über 97 % an der Wärmelastdeckung erlaubt hätte, gäbe es die Beschränkungen durch die Stromseite nicht. Desweiteren wurde die CO2-Vermeidungswirkung der KWK-Wärmespeicher und des Lastmanagements mit Wärmepumpen untersucht. In Szenario 2050 A ergab sich keine signifikante CO2-Vermeidungswirkung der KWK-Wärmespeicher, in Szenario 2050 C hingegen ergab sich eine geringe aber signifikante CO2-Einsparung in Höhe von 1,6 % der Gesamtemissionen der Stromerzeugung und KWK-gebundenen Wärmeversorgung. Das Lastmanagement mit Wärmepumpen vermied Emissionen von 110 Tausend Tonnen CO2 (0,4 % der Gesamtemissionen) in Szenario A und 213 Tausend Tonnen in Szenario C (0,8 % der Gesamtemissionen). Es wurden darüber hinaus Betrachtungen zur Konkurrenz zwischen solarthermischer Nahwärme und KWK bei Einspeisung in dieselben Wärmenetze vorgenommen. Eine weitere Einschränkung der KWK-Erzeugung durch den Einspeisevorrang der Solarthermie wurde festgestellt. Ferner wurde eine untere Grenze von 6,5 bzw. 8,8 TWh_th für die in den Szenarien mindestens benötigte Wasserstoff-Speicherkapazität ermittelt. Die Ergebnisse dieser Arbeit legen nahe, das technisch-ökonomische Potential von Langzeitwärmespeichern für eine bessere Integration von KWK ins System zu ermitteln bzw. generell nach geeigneteren Wärmesektorszenarien zu suchen, da deutlich wurde, dass für die öffentliche Wärmeversorgung die KWK in Kombination mit Kurzzeitwärmespeicherung, Gaskesseln und elektrischen Heizern keine sehr effektive CO2 -Reduktion in den Szenarien erreicht. Es sollte dabei z.B. untersucht werden, ob ein multivalentes System aus KWK, Wärmespeichern und Wärmepumpen eine ökonomisch darstellbare Alternative sein könnte und im Anschluss eine Betrachtung der optimalen Anteile von KWK, Wärmepumpen und Solarthermie im Wärmemarkt vorgenommen werden.

IRP Poster - Side-effects in Software Transactional Memory

Poster for IRP project 'Side-effects in Software Transactional Memory: Extending Deuce with TwilightSTM'

WAIS Seminar:Evaluating the Cognitive Side of Information Interaction

Abstract In this talk, I'll focus on the work we've been doing on evaluating the cognitive side of dealing with information resources and increasingly complex user interfaces. While we can build increasingly powerful user interfaces, they often come at the cost of simple design and ease of use. I'll describe two specific studies: 1) work on the ORCHID project focused on measuring mental workload during tasks using fNIRS (a blood-oxygen-based brain scanner), and 2) a evaluation metric for measuring how much people learn during tasks. Together these provide advances towards understanding the cognitive side of information interaction, in working towards building better tools for users.

Empregabilidade e side-bets: uma realidade dos estudantes universitários do mestrado

O conceito de empregabilidade tem sido crucial nos dias de hoje devido às mudanças que têm ocorrido na sociedade em geral. É imprescindível conhecer o este conceito bem como as transformações que têm ocorrido à volta dele e principalmente quais os seus antecedentes. Partindo da ideia que existe um investimento na procura de emprego, os side-bets foram considerados antecedentes da empregabilidade. O presente estudo teve como objectivo estudar a relação de antecedência dos side-bets com a percepção da empregabilidade, num contexto universitário, nomeadamente dos estudantes do mestrado. Os resultados permitiram concluir que os side-bets são antecedentes da empregabilidade. Contudo foram identificadas várias limitações que permitem encontrar estudos futuros bastante interessantes. Foram discutidas as implicações do presente estudo

The dark side of the Mediterranean : expression of fear from the inquisition to the present

Inside the stones of its most famous buildings, Évora keeps mysteries and secrets which constitute the most hidden side of its cultural identity. A World Heritage site, this town seems to preserve, in its medieval walls, a precious knowledge of the most universal and ancient human emotion: fear. Trying to transcend many of its past and future fears, some of its historical monuments in Gothic style were erected against the fear of death, the most terrible of all fears, which the famous inscription, in the Bones Chapel of the Church of São Francisco, insistently reminds us, through the most disturbing words: “Nós ossos que aqui estamos pelos vossos esperamos”. If the first inquisitors worked in central Europe (Germany, northern Italy, eastern France), later the centres of the Inquisition were established in the Mediterranean regions, especially southern France, Italy, Portugal, and Spain. Consequently, the roots of fear in Évora are common to other towns, where the Inquisition developed a culture of fear, through which we can penetrate into the dark side of the Mediterranean, where people were subjected to the same terrifying methods of persecution and torture. This common geographical and historical context was not ignored by one of the most famous masters of American gothic fiction, Edgar Allan Poe. Through the pages of The Pit and the Pendulum, readers get precise images of the fearful instruments of terror that were able to produce the legend that has made the first grand inquisitor, Tomas de Torquemada, a symbol of ultimate cruelty, bigotry, intolerance, and religious fanaticism, which unfortunately are still the source of our present fears in a time when religious beliefs can be used again as a motif of war and destruction. As Krishnamurti once suggested, only a fundamental realization of the root of all fear can free our minds.

Synthesis and characterization of thermally stable second-order nonlinear optical side-chain polyimides containing thiazole and benzothiazole push-pull chromophores

Push-pull nonlinear optical (NLO) chromophores containing thiazole and benzothiazole acceptors were synthesized and characterized. Using these chromophores a series of second-order NLO polyimides were Successfully prepared from 4,4'-(hexafluoroisopropylidene) diphthalic anhydride (6FDA), pyromellitic dianhydride (PMDA) and 3,3'4,4'-benzophenone tetracarboxylic dianhydride (BTDA) by a standard condensation polymerization technique. These polyimides exhibit high glass transition temperatures ranging from 160 to 188 degrees C. UV-vis spectrum of polyimide exhibited a slight blue shift and decreases in absorption due to birefringence. From the order parameters, it was found that chromophores were aligned effectively. Using in situ poling and temperature ramping technique, the optical temperatures for corona poling were obtained. It was found that the optimal temperatures of polyimides approach their glass transition temperatures. These polyimides demonstrate relatively large d(33) values range between 35.15 and 45.20 pm/V at 532 nm. (C) 2008 Elsevier B.V. All rights reserved.

Provision of information about drug side-effects to patients

To make informed decisions about taking medicinal drugs, people need accurate information about side-effects. A European Union guideline now recommends use of qualitative descriptions for five bands of risk, ranging from very rare (affecting < 0·01% of the population), to very common (>10%). We did four studies of more than 750 people, whom we asked to estimate the probability of having a side-effect on the basis of qualitative and quantitative descriptions. Our results showed that qualitative descriptions led to gross overestimation of risk. Until further work is done on how patients taking the drugs interpret these terms, the terms should not be used in drug information leaflets.

Communicating information about medication side effects: effects on satisfaction, perceived risk to health, and intention to comply

Previous research has shown that people's evaluations of explanations about medication and their intention to comply with the prescription are detrimentally affected by the inclusion of information about adverse side effects of the medication. The present study (Experiment 1) examined which particular aspects of information about side effects (their number, likelihood of occurrence, or severity) are likely to have the greatest effect on people's satisfaction, perception of risk, and intention to comply, as well as how the information about side effects interacts with information about the severity of the illness for which the medication was prescribed. Across all measures, it was found that manipulations of side effect severity had the greatest impact on people's judgements, followed by manipulations of side effect likelihood and then number. Experiments 2 and 3 examined how the severity of the diagnosed illness and information about negative side effects interact with two other factors suggested by Social Cognition models of health behaviour to affect people's intention to comply: namely, perceived benefit of taking the prescribed drug, and the perceived level of control over preventing or alleviating the side effects. It was found that providing people with a statement about the positive benefit of taking the medication had relatively little effect on judgements, whereas informing them about how to reduce the chances of experiencing the side effects had an overall beneficial effect on ratings.

Is 15 per cent very common? Informing people about the risks of medication side effects

Objectives - To assess the general public's interpretation of the verbal descriptors for side effect frequency recommended for use in medicine information leaflets by a European Union (EU) guideline, and to examine the extent to which differences in interpretation affect people's perception of risk and their judgments of intention to comply with the prescribed treatment. Method - Two studies used a controlled empirical methodology in which people were presented with a hypothetical, but realistic, scenario about visiting their general practitioner and being prescribed medication. They were given an explanation that focused on the side effects of the medicine, together with information about the probability of occurrence using either numerical percentages or the corresponding EU verbal descriptors. Interpretation of the descriptors was assessed. In study 2, participants were also required to make various judgments, including risk to health and intention to comply. Key findings - In both studies, use of the EU recommended descriptors led to significant overestimations of the likelihood of particular side effects occurring. Study 2 further showed that the "overestimation" resulted in significantly increased ratings of perceived severity of side effects and risk to health, as well as significantly reduced ratings of intention to comply, compared with those for people who received the probability information in numerical form. Conclusion - While it is recognised that the current findings require replication in a clinical setting, the European and national authorities should suspend the use of the EU recommended terms until further research is available to allow the use of an evidence-based approach.

Evaluating explanations about drug prescriptions: effects of varying the nature of information about side effects and its relative position in explanations

This study evaluates computer-generated written explanations about drug prescriptions that are based on an analysis of both patient and doctor informational needs. Three experiments examine the effects of varying the type of information given about the possible side effects of the medication, and the order of information within the explanation. Experiment 1 investigated the effects of these two factors on people's ratings of how good they consider the explanations to be and of their perceived likelihood of taking the medication, as well as on their memory for the information in the explanation. Experiment 2 further examined the effects of varying information about side effects by separating out the contribution of number and severity of side effects. It was found that participants in this study did not “like” explanations that described severe side effects, and also judged that they would be less likely to take the medication if given such explanations. Experiment 3 therefore investigated whether information about severe side effects could be presented in such a way as to increase judgements of how good explanations are thought to be, as well as the perceived likelihood of adherence. The results showed some benefits of providing additional explanatory information.