Calorimetric study and thermal analysis of berberine sulphate

The heat capacities of berberine sulphate [(C20H18NO4)(2)SO4.3H(2)O] were measured from 80 to 390 K by means of an automated adiabatic calorimeter. Smoothed heat capacities,{H-T-H-298.15} and {S-T-S-298.15} were calculated. The loss of crystalline water started at about 339.3+/-0.2 K, and its peak temperature was 365.8+/-0.6 K. The peak temperature of decomposition for berberine sulphate was at about 391.4+/-0.4 K by DSC curve. TG-DTG analysis of this material was carried out in temperature range from 310 to 970 K. TG and DSC curves show that there is no melting in the whole heating process.

Heat capacities and thermodynamic functions of p-chlorobenzoic acid

The heat capacities of p-chlorobenzoic acid were measured in the temperature range from 80 to 580 K by means of an automatic adiabatic calorimeter equipped with a small sample cell of internal volume of 7.4cm(3). The construction and procedures of the calorimetric system were described in detail. The performance of this calorimetric apparatus was evaluated by heat capacity measurements on alpha-Al2O3. The deviations of experimental heat capacities from the corresponding smoothed values lie within +/-0.28 per cent, while the inaccuracy is within +/-0.40 per cent, compared with the recommended reference data in the whole experimental temperature range. A fusion transition at T = 512.280 K was found from the C-p-T curve of p-chlorobenzoic acid. The enthalpy and entropy of the phase transition, as well as the thermodynamic functions {G((T)) - G((298.15))}, {H-(T) - H-(298.15)} and {S-(T) - S-298.15}, were derived from the heat capacity data. The mass fraction purity of p-chlorobenzoic acid sample used in the present calorimetric study was determined to be 0.99935 by fraction melting approach. (C) 2002 Elsevier Science Ltd. All rights reserved.

黄土高原地区耕作技术效益研究

黄土高原地区地形破碎 ,坡地所占比例大 ,水土流失严重。调查和试验表明 ,在坡耕地上 ,因地制宜地采取各种水土保持耕作技术措施 ,对改变坡面微地貌 ,减少水土流失 ,增加土壤抗蚀、蓄水、保土性能 ;培肥地力和提高作物产量 ,都具有显著作用。该文着重分析了效果明显的 8种耕作技术及其特征 ,供决策部门在制订规划时参考。

Characteristics in frequency domain by inductively coupled plasma atomic emission spectrometry with charge injection detection

The charactesistics of two-dimension spectra obtained by inductively coupled plasma atomic emission spectrometry (ICP-AES) with charge injection detection (CID) in frequency domain were studied in the present paper. The measurement spectra were Fourier transformed and the frequency distribution of the spectra was obtained. Results showed that the spectra in frequency domain could he divided into two parts:high frequency and low frequency signals. The later stood for measurement spectra and the former for background and noises. However, the high frequecny signals could not be smoothed simply to reduce noises because the background was deteriorated even though the spectral signal did not change significantly.

LEAST-SQUARES POLYNOMIAL SMOOTHING FOR INDUCTIVELY COUPLED PLASMA ATOMIC EMISSION-SPECTRA

The use of least-squres polynomial smoothing in ICP-AES is discussed and a method of points insertion into spectral scanning intervals is proposed in the present paper. Optimal FWHM/SR ratio can be obtained, and distortion of smoothed spectra can be avoided by use of the recommended method.

并联刨床刚度分析及实验研究

为了提高刨削加工能力,而采用考虑到并联机构的特点而提出了并联刨床的概念并对其进行了简单说明.采用对机床进行分解的方法对机床的各功能模块分别建立刚度模型,并利用变形线性叠加的原理对机床的并联部分刚度进行分析.采用有限元软件对机床的床身框架及平面约束机构部分的刚度进行分析.并以仿真和实验加工的方式进行了刚度特性研究.

视觉伺服分类及其动态过程

对视觉伺服进行了综述性的介绍,系统地介绍了机器人视觉伺服控制的发展历史以及现状·从控制模型给出了视觉伺服控制系统的分类·针对两种最基本的分类方式基于位置的视觉伺服和基于图像的视觉伺服进行了重点介绍·对于视觉系统和图像特征的选取问题进行了讨论,此外还对视觉伺服系统的动态过程进行了分析,指出视觉系统的延时是目前伺服控制的研究所面临的最大问题·对未来视觉伺服研究的方向进行了总结·

基于输入和机械手扰动补偿的水下机器人控制实验研究

以搭建的自治水下机器人-机械手系统为对象,通过水池实验分析了载体分系统的响应特性。针对传统的反馈控制在载体控制中的不足,将输入补偿项和机械手扰动补偿项作为载体控制的前馈项,设计了水下机器人复合校正控制器。水池实验验证了方法的可行性和有效性。

一种基于知识的自然景物解释

利用我们研制成的基于知识的区域分析系统,我们对自然景物图象做了分析、解释。本文介绍:(1)图象初始分割;(2)图象特征提取;(3)规则集构造。这里,图象初始分割采用的是模糊域方法,它基于Fuzzy C-means 算法,并在此基础上修改了收敛准则,增加了迭代分割功能。图象特征分为主持征及从特征,它们建立在层次化的区域数据结构上。适合于区域分析的规则集已包括三类规则,它们不仅具有较强的知识表示能力,而且易于控制及利用。本文介绍针对包括天空、道路、树木、建筑物等物体的简单景物图象所做的解释实验,并给出了实验结果.

不同基板预热温度对激光金属沉积成形过程温度场的影响

为降低成形过程的热应力,抑制成形过程裂缝的产生,减小成形过程试样和基板的翘曲变形,激光金属沉积成形往往需要进行基板预热,因此研究不同基板预热温度对激光金属沉积成形过程温度场的影响具有非常重要的意义.根据有限元分析中的"单元生死"技术,利用APDL编程建立了基板预热对激光金属沉积成形过程温度场影响的三维多道多层数值模拟模型,详细分析了基板未预热和分别预热到200,300,400,500,600℃时对沉积成形过程温度场和温度梯度的影响.通过中国科学院沈阳自动化研究所自行研制的激光金属沉积成形系统和基板预热系统,在与模拟过程相同的参数下,利用镍基合金粉末在基板未预热和分别预热到300,400,500,560℃时进行了成形试验,试验结果跟数值模拟结果吻合较好.

基板预热对激光金属沉积成形过程热应力的影响

为降低沉积过程的热应力,抑制成形过程中裂缝的产生,研究基板预热对激光金属沉积成形(Laser metal deposition shaping,LMDS)过程热应力的影响具有非常重要的意义。根据有限元分析中的"单元生死"思想,利用APDL(ANSYS parametric design language)编程建立多道多层激光金属沉积成形过程的数值模拟模型,深入探讨基板未预热和预热到400℃时对成形过程热应力的影响。计算结果表明,基板预热到400℃可以显著降低成形过程中试样的热应力变化波动性,试样的Von Mises热应力最大值可降低10%左右,其中x方向热应力最大值可降低8.5%左右,z方向热应力最大值可降低8.1%左右。在与模拟过程相同的条件下,利用自行研制的激光金属沉积成形设备进行了成形试验,成形试验的结果与模拟结果基本吻合。

不同基板预热温度对激光金属沉积成形过程热应力影响的研究

研究不同基板预热温度对激光金属沉积成形过程热应力的影响,对于降低成形过程的热应力,抑制成形过程裂缝的产生,减小成形过程试样和基板的翘曲变形具有非常重要的意义。根据有限元分析中的"单元生死"技术,编程建立了基板预热对激光金属沉积成形过程热应力影响的三维多道多层数值模拟模型,详细分析了基板未预热和分别预热到200℃、300℃、400℃、500℃、600℃时对沉积成形过程VonMise’s热应力、X方向、Y方向以及Z方向热应力的影响。在与模拟过程相同的参数下,利用镍基合金粉末分别在基板未预热和分别预热到300℃、400℃、500℃、600℃时进行了成形试验,试验的结果跟数值模拟结果吻合较好。

改进叠前深度偏移的计算效率＆叠前高分辨率成像

An high-resolution prestack imaging technique of seismic data is developed in this thesis. By using this technique, the reflected coefficients of sheet sands can be gained in order to understand and identify thin oil reservoirs. One-way wave equation based migration methods can more accurately model seismic wave propagation effect such as multi-arrivals and obtain almost correct reflected energy in the presence of complex inhomogeneous media, and therefore, achieve more superiorities in imaging complex structure. So it is a good choice to apply the proposed high-resolution imaging to the presatck depth migration gathers. But one of the main shorting of one-way wave equation based migration methods is the low computational efficiency, thus the improvement on computational efficiency is first carried out. The method to improve the computational efficiency of prestack depth migration is first presented in this thesis, that is frequency-dependent varying-step depth exploration scheme plus a table-driven, one-point wavefield interpolation technology for wave equation based migration methods; The frequency-dependent varying-step depth exploration scheme reduces the computational cost of wavefield depth extrapolation, and the a table-driven, one-point wavefield interpolation technology reconstructs the extrapolated wavefield with an equal, desired vertical step with high computational efficiency. The proposed varying-step depth extrapolation plus one-point interpolation scheme results in 2/3 reduction in computational cost when compared to the equal-step depth extrapolation of wavefield, but gives the almost same imaging. The frequency-dependent varying-step depth exploration scheme is presented in theory by using the optimum split-step Fourier. But the proposed scheme can also be used by other wave equation based migration methods of the frequency domain. The proposed method is demonstrated by using impulse response, 2-D Marmousi dataset, 3-D salt dataset and the 3-D field dataset. A method of high-resolution prestack imaging is presented in the 2nd part of this thesis. The seismic interference method to solve the relative reflected coefficients is presented. The high-resolution imaging is obtained by introducing a sparseness- constrained least-square inversion into the reflected coefficient imaging. Gaussian regularization is first imposed and a smoothed solution is obtained by solving equation derived from the least-square inversion. Then the Cauchy regularization is introducing to the least-square inversion , the sparse solution of relative reflected coefficients can be obtained, that is high-resolution solution. The proposed scheme can be used together with other prestack imaging if the higher resolution is needed in a target zone. The seismic interference method in theory and the solution to sparseness-constrained least-square inversion are presented. The proposed method is demonstrated by synthetic examples and filed data.

地震波模拟：非规则网格离散的数值解法、吸收边界及其实际应用

This dissertation presents a series of irregular-grid based numerical technique for modeling seismic wave propagation in heterogeneous media. The study involves the generation of the irregular numerical mesh corresponding to the irregular grid scheme, the discretized version of motion equations under the unstructured mesh, and irregular-grid absorbing boundary conditions. The resulting numerical technique has been used in generating the synthetic data sets on the realistic complex geologic models that can examine the migration schemes. The motion equation discretization and modeling are based on Grid Method. The key idea is to use the integral equilibrium principle to replace the operator at each grid in Finite Difference scheme and variational formulation in Finite Element Method. The irregular grids of complex geologic model is generated by the Paving Method, which allow varying grid spacing according to meshing constraints. The grids have great quality at domain boundaries and contain equal quantities of nodes at interfaces, which avoids the interpolation of parameters and variables. The irregular grid absorbing boundary conditions is developed by extending the Perfectly Matched Layer method to the rotated local coordinates. The splitted PML equations of the first-order system is derived by using integral equilibrium principle. The proposed scheme can build PML boundary of arbitrary geometry in the computational domain, avoiding the special treatment at corners in a standard PML method and saving considerable memory and computation cost. The numerical implementation demonstrates the desired qualities of irregular grid based modeling technique. In particular, (1) smaller memory requirements and computational time are needed by changing the grid spacing according to local velocity; (2) Arbitrary surfaces and interface topographies are described accurately, thus removing the artificial reflection resulting from the stair approximation of the curved or dipping interfaces; (3) computational domain is significantly reduced by flexibly building the curved artificial boundaries using the irregular-grid absorbing boundary conditions. The proposed irregular grid approach is apply to reverse time migration as the extrapolation algorithm. It can discretize the smoothed velocity model by irregular grid of variable scale, which contributes to reduce the computation cost. The topography. It can also handle data set of arbitrary topography and no field correction is needed.

Structural Saliency: The Detection of Globally Salient Structures Using a Locally Connected Network

Certain salient structures in images attract our immediate attention without requiring a systematic scan. We present a method for computing saliency by a simple iterative scheme, using a uniform network of locally connected processing elements. The network uses an optimization approach to produce a "saliency map," a representation of the image emphasizing salient locations. The main properties of the network are: (i) the computations are simple and local, (ii) globally salient structures emerge with a small number of iterations, and (iii) as a by-product of the computations, contours are smoothed and gaps are filled in.