Stratospheric communication of El Nino teleconnections to European winter

The stratospheric role in the European winter surface climate response to El Niño–Southern Oscillation sea surface temperature forcing is investigated using an intermediate general circulation model with a well-resolved stratosphere. Under El Niño conditions, both the modeled tropospheric and stratospheric mean-state circulation changes correspond well to the observed “canonical” responses of a late winter negative North Atlantic Oscillation and a strongly weakened polar vortex, respectively. The variability of the polar vortex is modulated by an increase in frequency of stratospheric sudden warming events throughout all winter months. The potential role of this stratospheric response in the tropical Pacific–European teleconnection is investigated by sensitivity experiments in which the mean state and variability of the stratosphere are degraded. As a result, the observed stratospheric response to El Niño is suppressed and the mean sea level pressure response fails to resemble the temporal and spatial evolution of the observations. The results suggest that the stratosphere plays an active role in the European response to El Niño. A saturation mechanism whereby for the strongest El Niño events tropospheric forcing dominates the European response is suggested. This is examined by means of a sensitivity test and it is shown that under large El Niño forcing the European response is insensitive to stratospheric representation.

Sequence-selective assembly of tweezer-molecules on linear templates enables frameshift-reading of sequence information

Monomer-sequence information in synthetic copolyimides can be recognised by tweezer-type molecules binding to adjacent triplet-sequences on the polymer chains. In the present paper different tweezer-molecules are found to have different sequence-selectivities, as demonstrated in solution by 1H NMR spectroscopy and in the solid state by single crystal X-ray analyses of tweezer-complexes with linear and macrocyclic oligo-imides. This work provides clear-cut confirmation of polyimide chain-folding and adjacent-tweezer-binding. It also reveals a new and entirely unexpected mechanism for sequence-recognition which, by analogy with a related process in biomolecular information processing, may be termed "frameshift-reading". The ability of one particular tweezer-molecule to detect, with exceptionally high sensitivity, long-range sequence-information in chain-folding aromatic copolyimides, is readily explained by this novel process.

Application of a double bootstrap to investigation of determinants of technical efficiency of farms in Central Europe

The paper provides one of the first applications of the double bootstrap procedure (Simar and Wilson 2007) in a two-stage estimation of the effect of environmental variables on non-parametric estimates of technical efficiency. This procedure enables consistent inference within models explaining efficiency scores, while simultaneously producing standard errors and confidence intervals for these efficiency scores. The application is to 88 livestock and 256 crop farms in the Czech Republic, split into individual and corporate.