Identification of Sudan III-(deoxy)-guanosine adducts formed in situ in a reaction with no catalyst

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Efeito da pressão em filmes finos de ZnO:Al por RF Magnetron sputtering reativo

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Tutaméia: labirinto de imagens e símbolos

Pós-graduação em Estudos Literários - FCLAR

Desenvolvimento de imunossensor impedimétrico para detecção do corante disperso Red 1

Pós-graduação em Química - IQ

Embryonic development and nourishment in the viviparous fish Poecilia vivipara (Cyprinodontiformes: Poeciliidae)

While viviparity confers protection to the embryos during gestation, it increases energetic costs for the mother, which acquires new relations to its offspring. Maternal-fetal transfer of nutrients can occur in different patterns: as lecithotrophy (nourished by yolk) or matrotrophy (nourished by the mother). The development of Poecilia vivipara embryos was described macroscopically and microscopically, and the form of nutritional provisioning was identified. Embryonic development was divided into three prefertilization and seven postfertilization stages. The first organ to appear is the notochord, followed by the nervous, digestive and cardiovascular systems, and then by muscles and eyes. Embryonic nutritional provisioning was lecithotrophic, with yolk persisting until the last developmental stages and rich in proteins and polysaccharides. This kind of embryonic nutrition confirms the pattern found in the family Poeciliidae.

Bioremediation of direct dyes in simulated textile effluents by paramorphogenic form of Aspergillus oryzae

Azo dyes are extensively used for coloring textiles, paper, food, leather, drink, pharmaceutical products, cosmetics and inks. The textile industry consumes the largest amount of azo dyes, and it is estimated that approximately 10 - 15% of dyes used for coloring textiles might be lost in waste streams. Almost all azo dyes are synthetic and resist biodegradation, however, they can be readly reduced by a number of chemical and biological reducing systems. Biological treatment is advantageous over physical and chemical method as result of its low cost and little disturbance to the environment. This research focuses on the utilization of Aspergillus oryzae, to remove some kinds of azo dyes from aqueous solutions. The fungi, physically induced in its paramorphogenic form (called, pellets), were used in the dyes biosorption studies with both non autoclave and autoclaved hyphas, at differents pH values. Thus the goals are the removal of dyes by biosorption and the decrease of its toxicity.

Biorremoção do corante acid blue 29, usando serragem (Pinus sp.) como biossorvente

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Efeitos fotocrômico e termocrômico em ormosils dopados com azobenzenos

The sol-gel process and the wide variety of alkoxides commercially available have facilitated the processing of various Organic-Inorganic Hybrid Materials. In general, the hybrids are excellents matrix to incorporate organic or inorganic dopants that presents photochromic, thermochromic, and halochromic effects and in some cases photorefractive effects. The GPTS-TEOS hybrid matrix when deposited in the form of film is very resistant, adherent, has excellent transparency in visible region and allows to be doped with various azo-dye and metal salts of unusual oxidation states. One of the main characteristics of the azo-dyes when immersed in some hybrid matrix , is the capacity to isomerizes through group Azo (-N = N-) would can be commutated between the Cis (Z) and Trans (E) configurations by means of light or heat. Our goal was through the sol-gel process to prepare hybrid films of GPTS-TEOS doped with azo-dyes Methyl Red and Disperse Red 1, and characterize them optically. The characterizations are performed using techniques of UV / Vis spectroscopy, to identify changes in the absorption band of azo-dyes in the presence of optical pumping, (photochromic effects), in function of temperature (thermochromic effect). These properties are of wide scientific and technological interest because they will contribute to the confection Smart Windows (windows sensible to light), temperature sensors monitored optically and also in the recording of amplitude and phase diffraction gratings

Estudo da fotoisomerização em filmes de polímero triacrilato dopado com azocorante disperse red 1

Triacrylate resins are widely used to fabricate 3D microstructures, photonic crystals and optical devices. These resins can be doped with photosensitive materials like Disperse Red 1 (DR1), an Azo dye that changes its molecular configuration from trans to cis (photoisomerisation) with variations in their optical absorption spectrum when irradiated with ultraviolet or visible light. The reversibility of this process is thermally activated and occurs when the molecule remains at dark. In this work was prepared a 1:1 mixture of ethoxylated-6-trimethylolpropane (SR499) and tris-2-hydroxyethyl-isocyanurate (SR368) triacrylate resins, plus photoinitiator Lucirin TPOL, forming a UV curable polymeric matrix doped with DR1. Thin films were deposited onto glass slides by spin-coating technique. The films showed photochromic effect when illuminated with a low power diode laser (450 nm and 50mW/cm2). This effect is reversible after sample is left in dark. Thermochromic effect was evaluated by optical absorption measurements in the range of 40 to 140oC, heating the samples in-situ

Morphology of Richards' gland in the swarm-founding wasp (Hymenoptera, Vespidae)

Richards' gland is known for the majority of Epiponini wasps, and despite few experimental evidences, the taxonomic distribution in swarm-founder species and the function of this gland remain rather unclear. This work presents a morphological description of Richards' gland in Protonectarina sylveirae. The gland is formed by a cluster of class 3 cells underneath the anterior margin of the fifth metasomal sternite, and a reservoir formed by the intersegmental membrane between the fourth and fifth metasomal sternites where the secretion can be stored. The secretory cells contain a branched end apparatus that carries the secretory products towards the duct cell. Externally, the cuticle of the sternite, where the duct cells penetrate, is characterized by modifications as scales with very numerous pores. The presence of Richards' gland according to the model proposed by Samacá et al. 2013 in Protonectarina corroborates the single origin of this gland in Epiponini. The occurrence of a Golgi apparatus and smooth endoplasmic reticulum suggests pheromone production.

Preliminary in vitro and ex vivo evaluation of afzelin, kaempferitrin and pterogynoside action over free radicals and reactive oxygen species

Biological activities of flavonoids have been extensively reviewed in literature. The biochemical profile of afzelin, kaempferitrin, and pterogynoside acting on reactive oxygen species was investigated in this paper. The flavonoids were able to act as scavengers of the superoxide anion, hypochlorous acid and taurine chloramine. Although flavonoids are naturally occurring substances in plants which antioxidant activities have been widely advertised as beneficial, afzelin, kaempferitrin, and pterogynoside were able to promote cytotoxic effect. In red blood cells this toxicity was enhanced, depending on flavonoids concentration, in the presence of hypochlorous acid, but reduced in the presence of 2,20 -azo-bis(2-amidinopropane) free radical. These flavonoids had also promoted the death of neutrophils, which was exacerbated when the oxidative burst was initiated by phorbol miristate acetate. Therefore, despite their well-known scavenging action toward free radicals and oxidants, these compounds could be very harmful to living organisms through their action over erythrocytes and neutrophils.

Avaliação da toxicidade do azocorante Acid Red 114 antes e após processo de biodegradação por meio de um consórcio de microorganismos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

TiO2/CuO films obtained by citrate precursor method for photocatalytic application

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Disperse Red 1 (textile dye) induces cytotoxic and genotoxic effects in mouse germ cells

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)