Maximizing the Localized Relaxation: The Origin of the Outstanding Oxygen Storage Capacity of kappa-Ce2Zr2O8

Pretty vacant: The excellent oxygen storage capacity (OSC) of ?-Ce2Zr2O8 (see picture; Ce gray, Zr green, O red) is shown to be a result of its unique structural features; after removing oxygen atoms, the structural relaxation is local (vacancy shown in brown), and both the localized structural relaxation and the number of localized structural relaxations are maximized.

Transcending cultural differences: the role of language in migrants' integration

This research seeks to contribute to current debates on migration by examining the role of language in the process of migrants’ integration. It will consider how migrant workers living in an area with little history of international immigration navigate their way within a new destination to cope with language difference. The paper is based on empirical research (interviews and focus groups) conducted in Northern Ireland, an English speaking region with a small proportion of Irish-English bilinguals (10.3 percent of population had some knowledge of Irish in the 2001 Census). Much of the research to date, while acknowledging the importance of culture and language for migrants’ positive integration, has only begun to unpack the way in which cultural difference such as language is dealt with at an individual, family or societal level. Several themes emerge from the research including the significance of social and civil structures and the role of individual agents as new culture is created through the celebration of difference.

Phonons, Instabilities and Origin of Polarization in KDP Crystals

The -phonons of KH2PO4 (KDP) and its deuterated analog DKDP are studied via first-principles linear response calculations. The paraelectric phase shows two instabilities. One for a z-polarized mode, which leads to the spontaneous polarization Ps of the ferroelectric phase. The other corresponds to a two-fold degenerate xy-polarized mode. Other phonons are analyzed, which couple to the ferroelectric one at large amplitudes and are relevant for the ferroelectric transition. We show that Ps is mainly of electronic nature, since it arises mostly from an off-diagonal component of the Born effective charge tensor of H, with minor contribution from P atoms displacements.

Origin of Low CO2 Selectivity on Platinum in the Direct Ethanol Fuel Cell

Calculated answer: First-principles calculations have been applied to calculate the energy barrier for the key step in CO formation on a Pt surface (see picture; Pt blue, Pt atoms on step edge yellow) to understand the low CO2 selectivity in the direct ethanol fuel cell. The presence of surface oxidant species such as O (brown bar) and OH (red bar) led to an increase of the energy barrier and thus an inhibition of the key step. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim

Beyond the Sign. Henri Meschonnic's Poetics of Rhythm and Continuum. Towards an Anthropological Theory of Language

Basing the conception of language on the sign represents also an obstacle to the awareness of certain elements of human life, especially to a full understanding of what language or art do, Henri Meschonnic’s poetics of the continuum and of rhythm criticizes the sign based on Benveniste’s terms of rhythm and discourse, developing an anthropology of language. Rhythm, for Meschonnic, is no formal metrical but a semantic principle, each time unique and unforeseeable. As for Humboldt, his starting point is not the word but the ensemble of speech; language is not ergon but energeia. The poem then is not a literary form but a process of transformation that Meschonnic defines as the invention of a form of life by a form of language and vice versa. Thus a poem is a way of thinking and rhythm is form in movement. The particular subject of art and literature is consequently not the author but a process of subjectivation – this is the contrary of the conception of the sign. By demonstrating the limits of the sign, Meschonnic’s poetics attempts to thematize the intelligibility of presence. Art and literature raise our awareness of this element of human life we cannot grasp conceptually. This poetical thinking is a necessary counterforce against all institutionalization.

Genomic insights into the origin of parasitism in the emerging plant pathogen Bursaphelenchus xylophilus.

Bursaphelenchus xylophilus is the nematode responsible for a devastating epidemic of pine wilt disease in Asia and Europe, and represents a recent, independent origin of plant parasitism in nematodes, ecologically and taxonomically distinct from other nematodes for which genomic data is available. As well as being an important pathogen, the B. xylophilus genome thus provides a unique opportunity to study the evolution and mechanism of plant parasitism. Here, we present a high-quality draft genome sequence from an inbred line of B. xylophilus, and use this to investigate the biological basis of its complex ecology which combines fungal feeding, plant parasitic and insect-associated stages. We focus particularly on putative parasitism genes as well as those linked to other key biological processes and demonstrate that B. xylophilus is well endowed with RNA interference effectors, peptidergic neurotransmitters (including the first description of ins genes in a parasite) stress response and developmental genes and has a contracted set of chemosensory receptors. B. xylophilus has the largest number of digestive proteases known for any nematode and displays expanded families of lysosome pathway genes, ABC transporters and cytochrome P450 pathway genes. This expansion in digestive and detoxification proteins may reflect the unusual diversity in foods it exploits and environments it encounters during its life cycle. In addition, B. xylophilus possesses a unique complement of plant cell wall modifying proteins acquired by horizontal gene transfer, underscoring the impact of this process on the evolution of plant parasitism by nematodes. Together with the lack of proteins homologous to effectors from other plant parasitic nematodes, this confirms the distinctive molecular basis of plant parasitism in the Bursaphelenchus lineage. The genome sequence of B. xylophilus adds to the diversity of genomic data for nematodes, and will be an important resource in understanding the biology of this unusual parasite.

Complex sociogenetic organization and the origin of unrelated workers in a eusocial sweat bee, Lasioglossum malachurum

Sweat bees (Halictidae) exhibit great interspecific and intraspecific diversity in their social organisation, yet there is remarkably little information on the sociogenetic organisation of any species. Lasioglossum malachurum is a eusocial sweat bee with an annual lifecycle that exhibits considerable variation in its social organisation across its wide geographic range from northern to southern Europe. We collected all adults from 31 L. malachurum nests at Eichkogl, Austria, near the latitudinal centre of its distribution, and genotyped 148 workers using 5 highly variable microsatellite loci developed for this species. Nests were often queenless (48% of nests) during the second phase of worker activity, when colonies were provisioning the sexual brood. Pedigree reconstruction and estimates of nestmate genetic relatedness demonstrated that nests often (32% of nests) contained alien workers, probably as a result of worker drifting from their natal to a foreign nest. Queen effective mating frequency was variable (harmonic mean m(e) = 1.24), but sometimes high (maximum 2.7). These data demonstrate that nests of L. malachurum do not have a classical eusocial sociogenetic organisation (monogyny, monandry) and thereby pose a challenge to exclusively relatedness based arguments for the evolution of eusociality in the taxon.

ON THE ORIGIN OF NH IN DIFFUSE INTERSTELLAR CLOUDS

The observation by Meyer & Roch of NH in the interstellar clouds towards zeta Per and HD 27778 cannot be explained with conventional gas-phase chemistry models. A simple non-equilibrium model for the zeta Per cloud, which incorporates the grain-surface production of NH and OH or, alternatively, NH3 and H2O, is able to reproduce the abundances of all observed species (except CH+) quite accurately. Moreover, chemical models which include grain-surface reactions can reproduce the observed abundance not only of NH but also of CN, which is efficiently formed at low temperatures, initiated by the reaction of NH with C+. Pure gas-phase models and cloud interface models, in which NH and CH+ are formed in a warm and tenuous environment, fail to explain the observed high abundance of CN. Hence the observation of NH in zeta Per and HD 27778 provides evidence for the presence of grain-surface reactions leading to molecules other than H-2. It is predicted that NH2 and NH3 should have abundances not much below that of NH if NH3 instead of NH is formed on grains. With or without surface reactions, the column densities of H2O and C2H are expected to be about 10(13) cm-2, and these molecules may be detectable in the zeta Per cloud.

The Origin of Type I Spicule Oscillations

We use images of high spatial and temporal resolution, obtained with the Rapid Oscillations in the Solar Atmosphere instrument at the Dunn Solar Telescope, to reveal how the generation of transverse waves in Type I spicules is a direct result of longitudinal oscillations occurring in the photosphere. Here we show how pressure oscillations, with periodicities in the range of 130–440 s, manifest in small-scale photospheric magnetic bright points, and generate kink waves in the Sun’s outer atmosphere with transverse velocities approaching the local sound speed. Through comparison of our observations with advanced two-dimensional magnetohydrodynamic simulations, we provide evidence for how magnetoacoustic oscillations, generated at the solar surface, funnel upward along Type I spicule structures, before undergoing longitudinal-to-transverse mode conversion into waves at twice the initial driving frequency. The resulting kink modes are visible in chromospheric plasma, with periodicities of 65–220 s, and amplitudes often exceeding 400 km. A sausage mode oscillation also arises as a consequence of the photospheric driver, which is visible in both simulated and observational time series. We conclude that the mode conversion and period modi?cation is a direct consequence of the 90? phase shift encompassing opposite sides of the photospheric driver. The chromospheric energy ?ux of these waves are estimated to be ˜3 × 105 W m-2, which indicates that they are suf?ciently energetic to accelerate the solar wind and heat the localized corona to its multi-million degree temperatures.