Técnica de separação de cor para fotocoagulação com luz solar concentrada

Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para obtenção do grau de Mestre em Engenharia Biomédica

Módulo fotovoltaico com seguimento da posição solar

Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para obtenção do grau de Mestre em Engenharia Electrotécnica e de Computadores

How market power affects the behaviour of a pumped storage hydro unit in the day-ahead electricity market?

The integration of large amounts of wind energy in power systems raises important operation issues such as the balance between power demand and generation. The pumped storage hydro (PSH) units are seen as one solution for this issue, avoiding the need for wind power curtailments. However, the behavior of a PSH unit might differ considerably when it operates in a liberalized market with some degree of market power. In this regard, a new approach for the optimal daily scheduling of a PSH unit in the day-ahead electricity market was developed and presented in this paper, in which the market power is modeled by a residual inverse demand function with a variable elasticity. The results obtained show that increasing degrees of market power of the PSH unit correspond to decreasing levels of storage and, therefore, the capacity to integrate wind power is considerably reduced under these circumstances.

Análise do efeito de implementação de armazenamento térmico em banco de gelo e armazenamento elétrico em baterias Sódio-Enxofre (NaS) sobre o custo de exploração de edifícios de serviços

Trabalho Final de Mestrado para obtenção do grau de Mestre em Engenharia Mecânica

Growth of the [110] oriented TiO2 nanorods on ITO substrates by sputtering technique for dye-sensitized solar cells

TiO2 films have been deposited on ITO substrates by dc reactive magnetron sputtering technique. It has been found that the sputtering pressure is a very important parameter for the structure of the deposited TiO2 films. When the pressure is lower than 1 Pa, the deposited has a dense structure and shows a preferred orientation along the [101] direction. However, the nanorod structure has been obtained as the sputtering pressure is higher than 1 Pa. These nanorods structure TiO2 film shows a preferred orientation along the [110] direction. The x-ray diffraction and the Raman scattering measurements show both the dense and the nanostructure TiO2 films have only an anatase phase, no other phase has been obtained. The results of the SEM show that these TiO2 nanorods are perpendicular to the ITO substrate. The TEM measurement shows that the nanorods have a very rough surface. The dye-sensitized solar cells (DSSCs) have been assembled using these TiO2 nanorod films prepared at different sputtering pressures as photoelectrode. And the effect of the sputtering pressure on the properties of the photoelectric conversion of the DSSCs has been studied.

Sistemas de bombagem de água utilizando energia solar fotovoltaica

Trabalho Final de Mestrado para obtenção do grau de Mestre em Engenharia Mecânica

Electrochemical response of 70Co-30Ni highly branched 3D-dendritic structures for charge storage electrodes

A 70Co-30Ni dendritic alloy was produced on stainless steel by pulse electrodeposition in the cathodic domain, and oxidized by potential cycling. X-ray diffraction (XRD) identified the presence of two phases and scanning electron microscopy (SEM) evidenced an open 3D highly branched dendritic morphology. After potential cycling in 1 M KOH, SEM and X-ray photoelectron spectroscopy (XPS) revealed, respectively, the presence of thin nanoplates, composed of Co and Ni oxi-hydroxides and hydroxides over the original dendritic film. Cyclic voltammetry tests showd the presence of redox peaks assigned to the oxidation and reduction of Ni and Co centres in the surface film. Charge/discharge measurements revealed capacity values of 121 mAh g(1) at 1 mA cm(2). The capacity retention under 8000 cycles was above 70%, stating the good reversibility of these redox materials and its suitability to be used as charge storage electrodes. Electrochemical impedance spectroscopy (EIS) spectra, taken under different applied bias, showed that the capacitance increased when the electrode was fully oxidized and decreased when the electrode was reduced, reflecting different states-of-charge of the electrode. (C) 2015 Elsevier Ltd. All rights reserved.

Fabrication of electrochemically reduced graphene oxide/cobalt oxide composite for charge storage electrodes

Electrochemically-reduced graphene oxide (Er-GO) and cobalt oxides (CoOx) were co-electrodeposited by cyclic voltammetry, from an electrolyte containing graphene oxide and cobalt nitrate, directly onto a stainless steel substrate to produce composite electrodes presenting high charge storage capacity. The electrochemical response of the composite films was optimized by studying the parameters applied during the electrodeposition process, namely the number of cycles, scan rate and ratio between GO/Co(NO3)(2) concentrations in the electrolyte. It is shown that, if the appropriate conditions are selected, it is possible to produced binder-free composite electrodes with improved electrochemical properties using a low-cost, facile and scalable technique. The optimized Er-GO/CoOx developed in this work exhibits a specific capacitance of 608 F g(-1) at a current density of 1 A g(-1) and increased reversibility when compared to single CoOx. (C) 2015 Elsevier B.V. All rights reserved.

Sensor de direcção luminosa para seguimento solar

Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa para a obtenção do grau de Mestre em Engenharia Electrotécnica e de Computadores

Optimal generation scheduling of wind-CSP systems in day-ahead electricity markets

This paper presents a coordination approach to maximize the total profit of wind power systems coordinated with concentrated solar power systems, having molten-salt thermal energy storage. Both systems are effectively handled by mixed-integer linear programming in the approach, allowing enhancement on the operational during non-insolation periods. Transmission grid constraints and technical operating constraints on both systems are modeled to enable a true management support for the integration of renewable energy sources in day-ahead electricity markets. A representative case study based on real systems is considered to demonstrate the effectiveness of the proposed approach. © IFIP International Federation for Information Processing 2015.

Estudo e análise das centrais híbridas de energias renováveis

Com o aumento do preço da eletricidade e o fim dos combustíveis fósseis, associados à necessidade de Portugal reduzir a sua dependência energética do exterior, provoca a necessidade urgente de apostar nas energias renováveis. Perante este cenário, e assumindo que o custo da fatura energética, é para as empresas portuguesas um fator cada vez mais determinante para serem competitivas, devido aos aumentos consecutivos da energia nos últimos anos, bem como, a subida do imposto de valor acrescentado (IVA) de 6% para 23%. Outro aspeto importante é a eficiência energética como instrumento para reduzir os consumos de eletricidade. Com estas duas medidas: utilização de energias renováveis e o aumento da eficiência energética, são extremamente importantes para a redução da produção dos gases de efeito estufa (GEE). Consequentemente, as empresas terão de investir na produção da própria energia a partir de fontes renováveis, de modo a proporcionar um desenvolvimento sustentável, associado à redução da fatura energética. Esta dissertação propõe o dimensionamento de um sistema híbrido composto por tecnologia fotovoltaica e eólica, com e sem armazenamento de energia em baterias, adequado para reduzir uma parte dos consumos de uma empresa enquadrada no sector dos plásticos. O dimensionamento deste sistema, foi efetuado com recurso à caracterização dos consumos da empresa através da recolha de dados e leituras no local da instalação. Paralelamente, foi efetuada uma pesquisa em diversos fabricantes, de modo a identificar qual o sistema mais indicado a adotar, considerando painéis fotovoltaicos, turbinas eólicas, inversores e baterias. Com base nos dados recolhidos na empresa e referentes ao potencial eólico e solar para o distrito do Porto, em conjunto com as características técnicas dos equipamentos selecionados, foi delineado o sistema híbrido utilizando para o efeito um software de simulação e otimização de sistemas híbridos, denominado Hybrid Optimization Model for Eletric Renewable (HOMER). São apresentadas várias simulações para as diversas configurações escolhidas e estudos comparativos entre si, com o objetivo de reduzir o consumo de eletricidade da rede. Adicionalmente, foram realizadas duas configurações apenas com tecnologia fotovoltaica, de modo a efetuar uma análise comparativa entre um sistema híbrido e outro apenas com uma fonte renovável. Os resultados apresentados focaram-se no desempenho diário, mensal e anual, bem como, a produção individual de cada tecnologia evidenciada. Por último, procedeu-se ao estudo da viabilidade técnico-económica das configurações.

Preparation and characterization of dye-sensitized TiO2 nanorod solar cells

TiO2 nanorodswere prepared by DC reactive magnetron sputtering technique and applied to dye-sensitized solar cells (DSSCs). The length of the TiO2 nanorods was varied from 1 μm to 6 μm. The scanning electronmicroscopy images showthat the nanorods are perpendicular to the substrate. Both the X-ray diffraction patterns and Raman scattering results show that the nanorods have an anatase phase; no other phase has been observed. (101) and the (220) diffraction peaks have been observed for the TiO2 nanorods. The (101) diffraction peak intensity remained constant despite the increase of nanorod length, while the intensity of the (220) diffraction peak increased almost linearly with the nanorod length. These nanorods were used as the working electrodes in DSSCs and the effect of the nanorod length on the conversion efficiency has been studied. An optimumphotoelectric conversion efficiency of 4.8% has been achieved for 4 μm length nanorods.

Solar Intensity Forecasting using Artificial Neural Networks and Support Vector Machines

This paper presents several forecasting methodologies based on the application of Artificial Neural Networks (ANN) and Support Vector Machines (SVM), directed to the prediction of the solar radiance intensity. The methodologies differ from each other by using different information in the training of the methods, i.e, different environmental complementary fields such as the wind speed, temperature, and humidity. Additionally, different ways of considering the data series information have been considered. Sensitivity testing has been performed on all methodologies in order to achieve the best parameterizations for the proposed approaches. Results show that the SVM approach using the exponential Radial Basis Function (eRBF) is capable of achieving the best forecasting results, and in half execution time of the ANN based approaches.

A contribuição de um sistema solar térmico no desempenho energético do edifício solar XXI

Dissertação apresentada na Faculdade de Ciências e Tecnologia da Universidade Nova de Lisboa Para a obtenção do Grau de Mestre em Energia e Bioenergia

Effects of storage, processing and proteolytic digestion on microcystin-LR concentration in edible clams

Accumulation of microcystin-LR (MC-LR) in edible aquatic organisms, particularly in bivalves, is widely documented. In this study, the effects of food storage and processing conditions on the free MC-LR concentration in clams (Corbicula fluminea) fed MC-LR-producing Microcystisaeruginosa (1 × 105 cell/mL) for four days, and the bioaccessibility of MC-LR after in vitro proteolytic digestion were investigated. The concentration of free MC-LR in clams decreased sequentially over the time with unrefrigerated and refrigerated storage and increased with freezing storage. Overall, cooking for short periods of time resulted in a significantly higher concentration (P < 0.05) of free MC-LR in clams, specifically microwave (MW) radiation treatment for 0.5 (57.5%) and 1 min (59%) and boiling treatment for 5 (163.4%) and 15 min (213.4%). The bioaccessibility of MC-LR after proteolytic digestion was reduced to 83%, potentially because of MC-LR degradation by pancreatic enzymes. Our results suggest that risk assessment based on direct comparison between MC-LR concentrations determined in raw food products and the tolerable daily intake (TDI) value set for the MC-LR might not be representative of true human exposure.