Occurrence of Cu and Cr in the sedimentary humic substances and pore water from a typical sugar cane cultivation area in São Paulo, Brazil

Purpose: The purpose of this paper is to study the interactions of sedimentary humic substances (SHS) from a sugarcane cultivation area with Cu(II) and Cr(III) and to evaluate the occurrence of these metals in the pore water and SHS. Materials and methods: For this study, the northwestern region of the State of São Paulo, Brazil, which is considered the region with the highest production of sugar cane in the state, was selected. Samples of sediment were collected from four sampling sites in the Preto, Turvo, and Grande rivers. The SHS and pore water were extracted from the sediment using the method suggested by the International Humic Substances Society and centrifugation, respectively. The complexing capacity (CC) of the SHS for Cu(II) and Cr(III) was determined by individually titrating these metals with an ultrafiltration system using tangential flow. The total concentrations of Cr and Cu were determined for the pore water, sediments, and humic substances with graphite furnace atomic absorption spectrometry and Zeeman background correction after an acid digestion, according to the methods described in US EPA Method 3050B. Results and discussion: The SHS from a site in the Turvo River, which is typically cultivated with sugarcane, possessed the highest concentration of Cu bound to SHS (25.0%), the largest CC (0.63 mmol Cu g-1 HS) and the highest concentration of this metal in the pore water (1.38 mg Cu Kg-1 sed.). For Cr, the SHS collected from a location on the Preto River dam had the largest CC (0.90 mmol Cr g-1 HS) and the lowest Cr content in the pore water (0.29 mg Cr Kg-1 sed.), indicating that there was an inverse relationship between the CC and the concentration of metal available in the pore water. Conclusions: Sedimentary humic substances might be one of the regulatory factors controlling the availability of Cu and Cr in the sediments found in a typical region that has been planted with sugarcane. Distinct behaviors were observed between the two elements investigated; higher CC and a larger fraction of Cu(II) were found in the pore water of samples originating from sugarcane crops. The opposite behavior was observed for the Cr(III) species. © 2013 Springer-Verlag Berlin Heidelberg.

Anthropogenic influences on Cd, Cr,Cu, Ni, Pb and Zn concentrations in soils and sediments in a watershed with sugar cane crops at São Paulo State, Brazil

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

The enzymatic recalcitrance of internodes of sugar cane hybrids with contrasting lignin contents

The recalcitrance in grasses varies according to cell type and maturation. The origin of the recalcitrance in different regions from sugar cane internodes with varied lignin contents was evaluated. The efficiency of enzymatic hydrolysis was correlated with the chemical, micromorphological and microspectrophotometric characteristics of the samples. The internodes of three sugar cane hybrids were dissected into four different fractions. The outermost fraction and the rind were the most recalcitrant regions, whereas the pith-rind interface and the pith were less recalcitrant. Cellulose conversion reached 86% after 72h of enzymatic digestion of the pith from the hybrid with the lowest lignin content. There was an inversely proportional correlation between the area occupied by vascular bundles and the efficiency of cellulose hydrolysis. High cellulose and low lignin or hemicellulose contents enhanced the efficiency of enzymatic hydrolysis of the polysaccharides. The critical evaluation of the results permitted to propose an empirical parameter for predicting cellulose conversion levels that accounts for the positive effect of high cellulose and low lignin plus hemicellulose and the detrimental effect of abundant vascular bundles. The cellulose conversion levels fit well to this calculated parameter, following a second order polynomial with an r2 value of 0.96. © 2013 Elsevier B.V.

Thiametoxam em cana-de-açúcar manejada com maturadores

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Seletividade de diclosulam, tryfloxisulfuron-sodium e ametryne a variedades de cana-de-açúcar

Pós-graduação em Agronomia (Agricultura) - FCA

Sucessão de culturas e adubação nitrogenada em cana soca: efeitos nos atributos químicos do solo, na produtividade e na qualidade da cultura

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Efeito residual do calcário e da escória de siderurgia na primeira soqueira da cultura da cana-de-açúcar

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Resposta da soqueira de cana-de-açúcar a aplicação de potássio sob o sistema de cultivo conservacionista e seus efeitos na fisiologia da planta

Pós-graduação em Agronomia (Ciência do Solo) - FCAV

Sugar cane variety research for the Caribbean

Includes bibliography

Research on sugar-cane and rice

Analiza la estructura de la industria azucarera en Trinidad y Tabago, sus politicas y funciones, sus programas de investigacion y objetivos. Presenta un sumario de los proyectos en curso para 1983- 84 y los efectos de los proyectos de investigacion sobre la productividad de cultivos distintos de los del azucar de cana.

Dose ótima econômica de nitrogênio em cana-de-açúcar aplicada via fertirrigação por gotejamento

Pós-graduação em Agronomia (Energia na Agricultura) - FCA

Caña de azúcar, producción de alcohol y los intereses de las transnacionales en Brasil = Sugar cane, alcohol production and the interests of transnational corporations in Brazil

Incluye Bibliografía

Sistemas de manejo em colheita e cultivo associados à adubação nitrogenada da cana-de-açúcar: aspectos qualiquantitativos da produção

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)