Abundance of nodules, chemical and mineral compositions of nodules and sediments from the Central Pacific

The monograph considers facial conditions of ore-formation in the Central Equatorial Pacific, as well as lithostratigraphy and local variability of bottom sediments. Mineral composition of nodules, forms of occurrence of chemical elements in sediments and nodules, composition of interstitial waters, age of nodules, regularities and processes of ore formation in the radiolarian belt of the Pacific Ocean zone are also under consideration.

(Table 2) Concentrations of particulate chemical elements in waters of the Pechora Sea

Mineralogy of suspended matter from surface and bottom waters has been studied at two sites in the Barents Sea. Along with terrigenous minerals, particulate matter samples contain authigenic mineral phases of iron and manganese oxyhydroxides. Mn-feroxyhite, Fe-vernadite, goethite, and proto-ferrihydrite have been identified in samples from the surface waters, whereas birnessite and non-ferruginous vernadite have been found in samples from the bottom waters. Formation of suspended manganese minerals in the bottom waters is explained by an additional Mn supply from underlying reduced sediments during their early diagenesis and oxygen depletion in the near-bottom nepheloid layer. Bacteria are supposed to take part in the authigenic mineral formation.

Vertical variations in basic salt composition of interstitial waters from Pacific sediments

Basic chemical composition of interstitial water in sediments of the Northwestern Pacific along a profile from the continental shelf of the Japan Trench to the ocean bed is discussed. Transformation of interstitial water in sediments rich in organic matter on the continental shelf and at the bottom of the Japan Trench is indicated. Variation in the vertical direction of elementary constituents of interstitial salt solution and variations in certain biogenic elements permit to make conclusions concerning processes taking place in sediments during sedimentation and diagenesis. These processes cause both metamorphism of water and transformation of organic and mineral content of sediments.

Chemical composition of sediments and interstitial waters in the Gulf of California and Eastern Pacific

The book is devoted to study of diagenetic changes of organic matter and mineral part of sediments and interstitial waters of the Pacific Ocean due to physical-chemical and microbiological processes. Microbiological studies deal with different groups of bacteria. Regularities of quantitative distribution and the role of microorganisms in geochemical processes are under consideration. Geochemical studies highlight redox processes of the early stages of sediment diagenesis, alterations of interstitial waters, regularities of variations in chemical composition of iron-manganese nodules.

Chemistry of interstitial waters of ODP Leg 112 samples

Two distinct hydrogeochemical regimes currently dominate the Peruvian continental margin. One, in shallower water (150-450 m) shelf to upper-slope regions, is characterized by interstitial waters with strong positive chloride gradients with depth. The maximum measured value of 1043 mM chloride at Site 680 at ITS corresponds to a degree of seawater evaporation of ~2 times. Major ion chemistry and strontioum isotopic composition of the interstitial waters suggest that a subsurface brine that has a marine origin and is of pre-early Miocene "age," profoundly influences the chemistry and diagenesis of this shelf environment. Site 684 at ~9°S must be closest to the source of this brine, which becomes diluted with seawater and/or interstitial water as it flows southward toward Site 686 at ~13?S (and probably beyond) at a rate of approximately 3 to 4 cm/yr, since early Miocene time. The other regime, in deep water (3000-5000 m) middle to lower-slope regions, is characterized by interstitial waters with steep negative and nonsteady-state chloride gradients with depth. The minimum measured value of 454 mM chloride, at Site 683 at ITS, corresponds to ~20% dilution of seawater chloride The most probably sources of these low-chloride fluids are gas hydrate dissociation and mineral (particularly clay) dehydration reactions. Fluid advection is consistent with (1) the extent of dilution shown in the chloride profiles, (2) the striking nonsteady-state depth profiles of chlorides at Sites 683 and 688 and of 87Sr/86Sr ratios at Site 685, and (3) the temperatures resulting from an average geothermal gradient of 50°C/km and required for clay mineral dehydration reactions. Strontium isotope data reveal two separate fluid regimes in this slope region: a more northerly one at Sites 683 and 685 that is influenced by fluids with a radiogenic continental strontium signature, and a southerly one at Sites 682 and 688 that is influenced by fluids with a nonradiogenic oceanic signatures. Stratigraphically controlled fluid migration seems to prevail in this margin. Because of its special tectonic setting, Site 679 at ITS is geochemically distinct. The interstitial waters are characterized by seawater chloride concentrations to -200 mbsf and deeper by a significantly lower chloride concentration of about two-thirds of the value in seawater, suggesting mixing with a meteoric water source. Regardless of the hydrogeochemical regime, the chemistry and isotopic compositions of the interstitial waters at all sites are markedly modified by diagenesis, particularly by calcite and dolomite crystallization.

Sulfur in bottom sediments and intersitial waters of the Gulf of California

The book is devoted to study of diagenetic changes of organic matter and mineral part of sediments and interstitial waters of the Pacific Ocean due to physical-chemical and microbiological processes. Microbiological studies deal with different groups of bacteria. Regularities of quantitative distribution and the role of microorganisms in geochemical processes are under consideration. Geochemical studies highlight redox processes of the early stages of sediment diagenesis, alterations of interstitial waters, regularities of variations in chemical composition of iron-manganese nodules.

Sedimentology, mineral magnetism, andoxygen isotope stratigraphy of ODP Hole 133-819A

To investigate late Quaternary paleoclimatic and paleoceanographic change in the sedimentary record, preserved on the Australian Continental Margin during the late Quaternary, core material was collected from Ocean Drilling Program, Leg 133, Site 819. An expanded sequence of late Quaternary, rhythmically bedded, predominantly hemipelagic sediments were recovered from Hole 819A. The foraminiferal d18O record preserved at Hole 819A suggests that the late Quaternary section is incomplete. Both benthic and planktonic d18O stratigraphies can be traced tentatively downcore to stage 6 at about 32.5 mbsf, where a major hiatus occurs. At this level, a slump detachment surface has been identified (Shipboard Scientific Party, 1991). This slump has removed marine oxygen isotope stages 7 to 13. Below 32.5 mbsf, continuous correlation can be achieved in the planktonic d18O curve, with existing deep-sea foraminiferal oxygen isotope stratigraphies from stage 14 through stage 28. The major hiatus at 32.5 mbsf marks the position of a significant change in the character of the sedimentation at Site 819. Sediments below 32.5 mbsf, relative to those above 32.5 mbsf, are characterized by less variation in mean particle size; lower percentages of carbonate content in the coarse fraction (>63 µm); a stronger relationship between the percentage of fine fraction and magnetic mineral concentration, and lower foraminiferal abundances. Above the hiatus, large fluctuations in mean particle size occurred, which have been interpreted to be the result of high foraminiferal abundances. Early highstands show high terrigenous influx in the fine fraction above the hiatus. This is the opposite of the general idea of high terrigenous influx during lowstands of sea level on siliciclastic dominated continental margins. We are far from understanding the origin of this material and further investigation will be required (see also Glenn et al., this volume). All our records, except the planktonic foraminiferal oxygen isotope record, indicate that the major hiatus marks the position of a significant change in the environment at Site 819. The planktonic foraminiferal d18O record suggests that environmental change occurred prior to the formation of the hiatus (i.e., near the Brunhes/Matuyama [B/M] boundary). The interval between the B/M boundary and the hiatus represents a transitional period between two different patterns of ocean circulation. Throughout most of the lower part of the sequence, Site 819 was at a shallow-water depth and local oceanographic conditions were dominated by sluggish Subtropical Central Water (SCW) flow. However, near the B/M boundary, ocean circulation patterns intensified, reflecting a worldwide change in paleoenvironment. Enhanced ocean circulation patterns were possibly aided by tectonic subsidence. During this period Site 819 became progressively more under the influence of Antarctic Intermediate Water (AAIW), than SCW. In the upper part of the sequence at Hole 819 A, we see a continuation of the pattern of oceanographic reorganization suggested during stages 21 through 14. Intensification of the subsurface oceanographic circulation was also accompanied by the progressive wedging southward of surface waters associated with the East Australian Current (EAC). The change in the nature of the records in the lower and upper parts of the sequence at Site 819 are thought to reflect perturbations by the orbital eccentricity cycle.

Concentrations of phosphates and silicon in near-bottom and interstitial waters of the Baltic Sea

Fine structure of vertical distributions of phosphorus and silicon in near-bottom layers and interstitial waters is studied in different regions of the Baltic Sea (Gulf of Finland, Bornholm area, Gotland trench). Data obtained are used to calculate fluxes of mineral forms of phosphorus and silicon in exchange processes between sediments and the near-bottom water layer. Depending on sediment types, values of nutrient fluxes vary from 9.8 to 632.6 µg-at/m**2/day for phosphorus and from 232.4 to 1881.1 µg-at/m**2/day for silicon. Fluxes calculated for different regions are compared.

Sulfur compounds in bottom sediments and interstitial waters of the Pacific Ocean to the east of Japan

In near-shore Pacific bottom sediments to the east of Japan unusually high content of free H2S ocurs. H2S resulting from bacterial reduction of sulfates from interstitial waters has a number of derivatives; pyrite dominates among them. Contents of other derivatives of H2S: sulfide sulfur and organic sulfur do not exceed 0,01%, content of organic sulfur does not exceed 0.1%. Due to reduction content of sulfates can reduce to 0,03% S. Capacity of the process of sulfate reduction, estimated by sum of all reduced forms of S - derivatives of H2S, is a function of organic matter content in sediments. Ability of bottom sediments to accumulate free H2S depends on content of reactive forms of Fe. Spatial distribution of reduced forms of S in the studied sediments is considered.

Composition of interstitial waters from sediments of the Gulf of California

The book is devoted to study of diagenetic changes of organic matter and mineral part of sediments and interstitial waters of the Pacific Ocean due to physical-chemical and microbiological processes. Microbiological studies deal with different groups of bacteria. Regularities of quantitative distribution and the role of microorganisms in geochemical processes are under consideration. Geochemical studies highlight redox processes of the early stages of sediment diagenesis, alterations of interstitial waters, regularities of variations in chemical composition of iron-manganese nodules.

Concentrations of rare earth elements in pore waters of IODP Holes 323-U1345A and 323-U1345B

We studied the diagenetic behavior of rare earth elements (REEs) in a highly productive passive margin setting of the Bering Sea Slope. Site U1345 was drilled during the Integrated Ocean Drilling Program Expedition 323 at a water depth of 1008 m currently in the center of an oxygen minimum zone. Pore water concentrations of fourteen REEs were determined down to ~ 140 meters below the seafloor (mbsf). The REE concentrations were higher in the pore water than the deep seawater, indicating that there was significant liberation from the sediments during diagenesis. There was a major peak at ~ 10 mbsf that was more pronounced for the heavy REE (HREE); this peak occurred below the sulfate-methane transition zone (6.3 mbsf) and coincided with high concentrations of dissolved iron and manganese. At ~ 2 mbsf, there was a minor peak in REE and Mn contents. Below ~ 40 mbsf, the REE concentration profiles remained constant. The Ce anomaly was insignificant and relatively constant (PAAS-normalized Ce/Ce = 1.1 ± 0.2) throughout the depth profile, showing that the Ce depleted in seawater was restored in the pore water. HREE-enrichment was observed over the entire 140 m except for the upper ~ 1 m, where a middle REE (MREE)-bulge was apparent. REE release in shallow depths (2-4 mbsf) is attributed to the release of light REEs (LREEs) and MREEs during the organoclastic reduction of Mn oxides in anoxic sediments. The high HREE concentrations observed at ~ 10 mbsf can be attributed to the reduction of Fe and Mn minerals tied to anaerobic oxidation of methane or, less significantly, to ferromagnesian silicate mineral weathering. The upward diffusion flux across the sediment-water interface was between 3 (for Tm) and 290 (for Ce) pmol/m**2/y.