Degradação enzimática de clorofenol em microrreator.

O microrreator faz parte de conjunto de dispositivos de uma nova e promissora tecnologia, que podem ser chamados de micro fabricados, atuante em campos como a da química, biológica, farmacêutica, engenharia química e biotecnologia. Trata-se de um dispositivo que possibilita reação química, tais como os reatores convencionais, mas com dimensões menores, com canais na escala micrométrica. A tecnologia de miniaturização de dispositivos para reações químicas vem se expandindo promovendo uma importante evolução, com microssistemas que abrange dispositivos mais eficazes, com configuração e geometrias específicas e menor consumo de energia, onde reações com elevadas taxas de transporte podem ser usadas para muitas finalidades diferentes, tais como, reações rápidas, mistura, reações sensíveis à temperatura, temperatura de homogeneização, ou até mesmo precipitação de nano partículas. Devido sua escala ser extremamente reduzida em relação à escala macro, oferecem um sistema que permite uma investigação do processo em um curto espaço de tempo, sendo muito útil para o rastreio de substratos, enzimas, condições de reação, bem como a determinação de parâmetros cinéticos. O presente trabalho teve por objetivo estudar a biodegradação enzimática de 2,4,6-Triclorofenol, com a utilização das enzimas Lacase e Soybean Peroxidase em microrreator da Syrris com volume de 250 ?l, que permite o estudo de cinéticas muito rápidas. Para as análises de degradação utilizou-se duas enzimas, a Lacase em concentrações de 0,05; 0,1 e 0,2 mg/ml; e a Soybean Peroxidase em concentrações de 0,0005; 0,001 e 0,002 mg/ml com a adição de Peróxido de Hidrogênio. Através dos ensaios realizados obteve-se dados experimentais da reação enzimática, possibilitando a verificação da taxa inicial de reação e sua cinética. Posteriormente, realizou-se as análises em simulação utilizando os dados experimentais, que através de um sistema de EDOs estimando inicialmente as constantes cinéticas k1, k2 e k3 usando a ferramenta ESTIMA, onde apresentaram duas respostas, uma resposta típica de mínimos quadrados, e a outra resposta que a velocidade inicial, que foi melhor representada pelos parâmetros obtidos. O método empregado na degradação do substrato, o microrreator mostrou-se eficiente, permitindo a detecção de baixo consumo de substrato para a determinação da taxa inicial, em curto tempo de residência. Perante os ensaios realizados com Lacase e Soybean Peroxidase, o microrreator é também um equipamento eficaz na repetitividade e na reprodutibilidade dos dados obtidos em diferentes concentrações.

Estudo numérico do efeito de blocagem hidrodinâmica em um túnel de cavitação sobre o escoamento ao redor de um submarino.

O projeto de submarinos é um tema que vem se desenvolvendo há muitos anos. No Brasil, vivemos um momento de pleno avanço na área, sendo encabeçado pela Marinha do Brasil com o desenvolvimento do primeiro submarino de propulsão nuclear brasileiro. No decorrer desse projeto, diversos estudos devem ser desenvolvidos, dentre eles, ensaios com modelos em escala, que serão realizados em um túnel de cavitação. Durante estes experimentos, espera-se que surjam diversas fontes de incerteza, que podem comprometer os resultados obtidos, destacando-se o efeito de blocagem hidrodinâmica. Nesse contexto, esta dissertação apresenta uma investigação do fenômeno de blocagem no modelo de submarino DARPA SUBOFF na seção de testes de um túnel de cavitação. Para isso, simulações tridimensionais de média de Reynolds (RANS) foram realizadas para o modelo de submarino posicionado no túnel (sob blocagem) e sob condição de águas profundas (referência), para diferentes ângulos de ataque e número de Reynolds (Re) constante. Coeficientes de força e momento hidrodinâmicos foram obtidos e os métodos de correção de blocagem clássico e WICS foram empregados para obter fatores que pudessem corrigir esses valores. A eficiência de cada método foi avaliada comparando os valores corrigidos com os de referência. Os resultados mostraram que ambos métodos de correção são eficientes na recuperação de coeficientes de força e momento hidrodinâmicos para razões de blocagem inferiores a 10%, mas ressalvas são feitas quanto à utilização de cada um desses métodos, sendo o método clássico indicado para o estudo de geometrias simples e o método WICS para modelos mais complexos. Paralelamente, a topologia do escoamento ao redor do submarino foi estudada através do método dos pontos críticos, para avaliar se a blocagem hidrodinâmica pode causar alterações nas estruturas presentes no escoamento. A análise topológica permitiu avaliar a evolução nas estruturas do escoamento para os ângulos de ataque e Re simulados. Foram capturadas as linhas de separação no corpo e avaliada sua relação com a tensão de cisalhamento ao longo do casco. A blocagem hidrodinâmica não causou alterações drásticas na topologia do escoamento.

On the development of advanced techniques for mixed-elastohydrodynamic lubrification modelling of journal and sliding bearing systems.

The present thesis is focused on the development of a thorough mathematical modelling and computational solution framework aimed at the numerical simulation of journal and sliding bearing systems operating under a wide range of lubrication regimes (mixed, elastohydrodynamic and full film lubrication regimes) and working conditions (static, quasi-static and transient conditions). The fluid flow effects have been considered in terms of the Isothermal Generalized Equation of the Mechanics of the Viscous Thin Films (Reynolds equation), along with the massconserving p-Ø Elrod-Adams cavitation model that accordingly ensures the so-called JFO complementary boundary conditions for fluid film rupture. The variation of the lubricant rheological properties due to the viscous-pressure (Barus and Roelands equations), viscous-shear-thinning (Eyring and Carreau-Yasuda equations) and density-pressure (Dowson-Higginson equation) relationships have also been taken into account in the overall modelling. Generic models have been derived for the aforementioned bearing components in order to enable their applications in general multibody dynamic systems (MDS), and by including the effects of angular misalignments, superficial geometric defects (form/waviness deviations, EHL deformations, etc.) and axial motion. The bearing exibility (conformal EHL) has been incorporated by means of FEM model reduction (or condensation) techniques. The macroscopic in fluence of the mixedlubrication phenomena have been included into the modelling by the stochastic Patir and Cheng average ow model and the Greenwood-Williamson/Greenwood-Tripp formulations for rough contacts. Furthermore, a deterministic mixed-lubrication model with inter-asperity cavitation has also been proposed for full-scale simulations in the microscopic (roughness) level. According to the extensive mathematical modelling background established, three significant contributions have been accomplished. Firstly, a general numerical solution for the Reynolds lubrication equation with the mass-conserving p - Ø cavitation model has been developed based on the hybridtype Element-Based Finite Volume Method (EbFVM). This new solution scheme allows solving lubrication problems with complex geometries to be discretized by unstructured grids. The numerical method was validated in agreement with several example cases from the literature, and further used in numerical experiments to explore its exibility in coping with irregular meshes for reducing the number of nodes required in the solution of textured sliding bearings. Secondly, novel robust partitioned techniques, namely: Fixed Point Gauss-Seidel Method (PGMF), Point Gauss-Seidel Method with Aitken Acceleration (PGMA) and Interface Quasi-Newton Method with Inverse Jacobian from Least-Squares approximation (IQN-ILS), commonly adopted for solving uid-structure interaction problems have been introduced in the context of tribological simulations, particularly for the coupled calculation of dynamic conformal EHL contacts. The performance of such partitioned methods was evaluated according to simulations of dynamically loaded connecting-rod big-end bearings of both heavy-duty and high-speed engines. Finally, the proposed deterministic mixed-lubrication modelling was applied to investigate the in fluence of the cylinder liner wear after a 100h dynamometer engine test on the hydrodynamic pressure generation and friction of Twin-Land Oil Control Rings.

Tecnologia CAM aplicada no fabrico por fresagem de componentes mecânicos : caracterização do processo de fresagem e dos componentes produzidos

Na fase inicial desta Dissertação foi realizada uma revisão abordando as operações por corte de arranque de apara mais comuns, considerando-se que estas seriam o torneamento, a furação mecânica e a fresagem, sendo esta última operação abordada de uma forma mais detalhada, uma vez que esta operação será o tema central de estudo neste trabalho. Realizou-se também um estudo mais elaborado sobre alguns fundamentos de fresagem como a maquinagem concordante e discordante, fatores que influenciam no acabamento final da maquinagem, diâmetro efetivo de corte para uma ferramenta de topo esférico, flexão da ferramenta, entre outros. Temas como o CAD-CAM, CNC e Engenharia Inversa foram também particularizados neste trabalho, pois o conhecimento destes assuntos por parte do leitor seriam importantes para a compreensão do trabalho posteriormente desenvolvido. Na parte seguinte deste trabalho foi realizada uma parte experimental. Um primeiro trabalho foi desenvolvido com base numa geometria a duas dimensões, onde foi necessária a realização das geometrias no software AUTOCAD® e posterior utilização do MASTERCAM® para criar os ciclos de maquinagem e, para um segundo trabalho, desta vez com base numa geometria a três dimensões, utilizou-se o SOLID-WORKS® para extração da Bucha e Cavidade e o MASTERCAM® para criar os ciclos de maquinagem. Ambos os trabalhos foram produzidos no Centro de maquinagem existente no Departamento de Engenharia Mecânica do Instituto Superior de Engenharia de Coimbra.

Análise de balística externa de um projétil de calibre 155 mm

O objetivo desta Dissertação é propor uma geometria para um projétil de combate a incêndios. É utilizado o código de volume finito Star - CCM+R para calcular forças e momentos que atuam no projétil e é criado um código no MathematicaR para definir as caraterísticas da trajetória. O PRODASV 3 R é utilizado de modo a verificar e validar os modelos implementados. Inicialmente, o procedimento adotado consistiu em criar uma metodologia completa para uma munição existente que permitisse ser verificada e validada com a literatura disponível. Foi realizada uma extensa caraterização aerodinâmica através de CFD, a fim de se estabelecer o comportamento das forças e momentos que atuam nos projéteis e assim fornecer os dados necessários para o modelo 6 DOF. As forças e momentos dependem do ângulo de ataque. Concluiu-se que a cinta de travamento, a cinta de guiamento e o efeito de Coriolis eram desprezáveis quando comparados com os resultados obtidos. Na fase seguinte foram testadas seis geometrias diferentes, variando-se o comprimento e o nariz. Definiu-se para este projétil um a velocidade inicial de 100m/s, 10kg, concluindo-se que o comprimento total seria de 697,1mm e perfil semiesférico, com capacidade para transportar 7,5 dm3 no interior. Foram realizados testes com vento para avaliar a estabilidade em voo, e o software e processo de análise desenvolvido neste trabalho estão disponíveis, sendo um contributo para o projeto FIREND.

Análise da formulação em Monte Carlo dos pacotes de energia multiespectrais aplicada a meios constituídos por vapor d'água

The Monte Carlo method is accurate and is relatively simple to implement for the solution of problems involving complex geometries and anisotropic scattering of radiation as compared with other numerical techniques. In addition, differently of what happens for most of numerical techniques, for which the associated simulations computational time tends to increase exponentially with the complexity of the problems, in the Monte Carlo the increase of the computational time tends to be linear. Nevertheless, the Monte Carlo solution is highly computer time consuming for most of the interest problems. The Multispectral Energy Bundle model allows the reduction of the computational time associated to the Monte Carlo solution. The referred model is here analyzed for applications in media constituted for nonparticipating species and water vapor, which is an important emitting species formed during the combustion of hydrocarbon fuels. Aspects related to computer time optimization are investigated the model solutions are compared with benchmark line-by-line solutions

Análise de superfícies seletivas em frequência com geometria multifractal

Frequency Selective surfaces are increasingly common structures in telecommunication systems due to their geometric and electromagnetic advantages. As a matter of fact, the frequency selective surfaces with fractal geometry type would allow an even bigger reduction of the electrical length which provided greater flexibility in the design of these structures. In this work, we investigated the use of multifractal geometry in frequency selective surfaces. Three structures with different multifractal geometries have been proposed and analyzed. The first structure allowed the design of multiband structures with greater flexibility in controlling the resonant frequencies and bandwidth. The second structure provided a bandwidth increase even with the rising of the fractal level. The third structure showed response with angle stability, dual polarization and provided room for a bandwidth increase with the rising of the structural multifractality. Furthermore, the proposed structures increased the degree of freedom in the multiband designs because they have multiple resonant frequencies ratios between adjacent bands and are easy to deploy. The validation of the proposed structures was initially verified through simulations in Ansoft Designer software and then the structures were constructed and the experimental results obtained

Processing of highly porous titanium parts by metal injection moulding in combination with innovative plasma treatment

A combinação da Moldagem por Injeção de pós Metálicos (Metal Injection Moulding MIM) e o Método do Retentor Espacial (Space Holder Method - SHM) é uma técnica promissora para fabricação de peças porosas de titânio com porosidade bem definida como implantes biomédicos, uma vez que permite um alto grau de automatização e redução dos custos de produção em larga escala quando comparado a técnica tradicional (SHM e usinagem a verde). Contudo a aplicação desta técnica é limitada pelo fato que há o fechamento parcial da porosidade na superfície das amostras, levando ao deterioramento da fixação do implante ao osso. E além disso, até o presente momento não foi possível atingir condições de processamento estáveis quando a quantidade de retentor espacial excede 50 vol. %. Entretanto, a literatura descreve que a melhor faixa de porosidade para implantes de titânio para coluna vertebral está entre 60 - 65 vol. %. Portanto, no presente estudo, duas abordagens foram conduzidas visando a produção de amostras altamente porosas através da combinação de MIM e SHM com o valor constante de retentor espacial de 70 vol. % e uma porosidade aberta na superfície. Na primeira abordagem, a quantidade ótima de retentor espacial foi investigada, para tal foram melhorados a homogeneização do feedstock e os parâmetros de processo com o propósito de permitir a injeção do feedstock. Na segunda abordagem, tratamento por plasma foi aplicado nas amostras antes da etapa final de sinterização. Ambas rotas resultaram na melhoria da estabilidade dimensional das amostras durante a extração térmica do ligante e sinterização, permitindo a sinterização de amostras de titânio altamente porosas sem deformação da estrutura.

Caracterização morfológica-sedimentar do vale inciso Apodi-Mossoró e plataforma continental adjacente - Bacia Potiguar Offshore

Systems of incised valleys have been studied in different continental shelves, including the Brazilian continental margin. The interest to characterize this feature is given by the information that it can provide variations on sea level, as well as the ability to host economically significant quantities of hydrocarbons in reservoirs located in deposits filling of the incised valleys. This thesis has the overall objective to characterize the morphology and sedimentary cover of the incised valley Apodi-Mossoró, located in the Northern Continental shelf of Rio Grande do Norte state, adjacent to Areia Branca city. The methodology included the integration of satellite imagery, bathymetric data, sedimentological data, shallow seismic, and the identification of foraminifera. The results indicate that the ApodiMossró incised valley is currently formed by two channels, shallow channel and deep channel, which have distinct morphological and sedimentological characteristics. The deep channel has connection with one of the heads of the Apodi Canyon, located in the slope area. The acquisition, processing and interpretation of shallow seismic data allowed the recognition of the depositional surface, erosional surface, discordance, and sismofaceis. The erosional surface mapped from shallow seismic sections is possibly a indicative of an ancient surface of valley incision, where it would probably be associated with the limit Pleistocene/Holocene. Different sismofaceis were identified and reflect the rise in sea level with standards sometimes agradacional, sometimes progradational. The thickness of sediments on this surface was estimated at a maximum of 22m thick in the central portion of the incised valley. Statistically, there are differences between the adjacent continental shelf and channels, and between these channels, for the content of calcium carbonate, organic matter, sand and mud perceptual, except for the gravel grain size. The analysis of living and dead foraminifera showed the presence of fifty species distributed in regards to morphology, depth and type of sediment. Four type of seismic echocharacteres were identified and mapped, as well as their bedforms, indicating different sedimentary processes along the incised valley. The integration of results suggests an activation of the Apodi-Mossoró incised valley in the Late Pleistocene.

Avaliação do controle da diagênese na qualidade de reservatório siliciclástico do cenomaniano superior da formação Açu, sudoeste da bacia potiguar

The distribution of diagenetic alterations in Late Cenomanian siliciclastic reservoirs from Potiguar Basin was influenced by the stratigraphic framework and the depositional system. Seismic sections and geophysical logs of two wells drilled in the SW portion of the mentioned basin above register regional stratigraphic surfaces representing maximum floods related to a transgressive event. The sequential analysis of 80 m of drill core (~450 m deep) recognized nine depositional facies with an upwards granodecrescent standard piling that limits cycles with an erosional conglomeratic base (lag) overlain by intercalations of medium to very fine sandstones showing cross bedding (channel, planar and low angled) and horizontal bedding (plane-parallel , wave and flaser). The top of the cycles is marked by the deposition of pelites and the development of paleosoils and lagoons. The correlation of genetically related facies reveals associations of channel fillings, crevasse, and flood plains deposited in a transgressive system. Detailed descriptions of seventy nine thin sections aided by MEV-EBSD/EDS, DRX and stable isotope analyses in sandstones revealed an arcosian composition and complex textural arrays with abundant smectite fringes continuously covering primary components, mechanically infiltrated cuticles and moldic and intragrain pores. K-feldspar epitaxial overgrowth covers microcline and orthoclase grains before any other phase. Abundant pseudomatrix due to the compactation of mud intraclasts concentrate along the stratification planes, locally replaced by macrocristalline calcite and microcrystalline and framboidal pyrite. Kaolinite (booklets and vermicular), microcrystalline smectite, microcrystalline titanium minerals and pyrite replace the primary components. The intergrain porosity prevails over the moldic, intragrain and contraction porosities. The pores are poorly connected due to the presence of intergranular smectite, k-feldspar overgrowth, infiltrated mud and pseudomatrix. The sandstones were subjected to eodiagenetic conditions next to the surface and shallow burial mesodiagenetic conditions. The diagenetic alterations reduced the porosity and the permeability mainly due to the precipitation of smectite fringes, compactation of mud intraclasts onto the pseudomatrix and cementing by poikilotopic calcite characterizing different reservoir petrofacies. These diagenetic products acted as barriers and detours to the flow of fluids thus reducing the quality of the reservoir.

Evolução estratigráfica da sequência neocarbonífera-eotriássica da Bacia do Parnaíba, NE do Brasil

The Parnaíba Basin consists in an intracratonic basin whose sucession of rocks is arranged in five supersequences. The Upper Carboniferous-Lower Triassic Sequence represents the third major sedimentary cycle and corresponds to Balsas Group, which is divided into four units: Piauí Formation, Pedra de Fogo Formation, Motuca Formation and Sambaíba Formation, from base to top. Different interpretations have been made by several authors in recent decades to interpreted the depositional system and environments related to each unit that belongs to this sequence. In general way, it is described as a thick pack of siliciclastic sediments deposited under complex conditions, varying from clastic/evaporitic shallow marine to lacustrine and desert environment. Aiming to clarify the sedimentary sequence evolution, this work underwent a stratigraphic analysis of the Upper Carboniferous-Lower Triassic deposits by applying modern concepts of the sequence stratigraphy based on well and seismic database. Three main depositional sequences of higher frequency were identified in each well analyzed. The sequence 1 corresponds to rocks initially deposited by a fluvial system with braided channel characteristics which evolved to shallow marine with coastal sabkha conditions related to a transgressive stage, that later evolved to a deltaic system. The Sequence 2 corresponds to rocks deposited in a lacustrine/desert environment associated with sabkha generated during a period of increased aridity in which the area occupied by the Parnaíba Basin had been suffering. The registration of a major regressive phase is shown in Sequence 2 which evolved to a dominantly desert environment recorded in Sequence 3. Seismic stratigraphy analyses allow to define a series of stratigraphic surfaces and related genetic units, as well as to infer its lateral expression. Seismic facies associated with such sequences are dominantly parallel and sub-parallel, with good lateral continuity, suggesting the sedimentary rate was relatively constant during deposition.

Evolução estratigráfica da sequência neocarbonífera-eotriássica da Bacia do Parnaíba, NE do Brasil

The Parnaíba Basin consists in an intracratonic basin whose sucession of rocks is arranged in five supersequences. The Upper Carboniferous-Lower Triassic Sequence represents the third major sedimentary cycle and corresponds to Balsas Group, which is divided into four units: Piauí Formation, Pedra de Fogo Formation, Motuca Formation and Sambaíba Formation, from base to top. Different interpretations have been made by several authors in recent decades to interpreted the depositional system and environments related to each unit that belongs to this sequence. In general way, it is described as a thick pack of siliciclastic sediments deposited under complex conditions, varying from clastic/evaporitic shallow marine to lacustrine and desert environment. Aiming to clarify the sedimentary sequence evolution, this work underwent a stratigraphic analysis of the Upper Carboniferous-Lower Triassic deposits by applying modern concepts of the sequence stratigraphy based on well and seismic database. Three main depositional sequences of higher frequency were identified in each well analyzed. The sequence 1 corresponds to rocks initially deposited by a fluvial system with braided channel characteristics which evolved to shallow marine with coastal sabkha conditions related to a transgressive stage, that later evolved to a deltaic system. The Sequence 2 corresponds to rocks deposited in a lacustrine/desert environment associated with sabkha generated during a period of increased aridity in which the area occupied by the Parnaíba Basin had been suffering. The registration of a major regressive phase is shown in Sequence 2 which evolved to a dominantly desert environment recorded in Sequence 3. Seismic stratigraphy analyses allow to define a series of stratigraphic surfaces and related genetic units, as well as to infer its lateral expression. Seismic facies associated with such sequences are dominantly parallel and sub-parallel, with good lateral continuity, suggesting the sedimentary rate was relatively constant during deposition.

Análise estratigráfica da sequência mesodevoniana-eocarbonífera da Bacia do Parnaíba, nordeste do Brasil

The Middle Devonian-Early Carboniferous sequence of the Parnaíba Basin, lithostratigraphically defined as Canindé Group, has been reinterpreted using the basic model of sequence stratigraphy. Therefore, lithology and gamma ray well-logs and seismic lines of central portion of the basin were analyzed, producing up from there diagrams 1D, isochore maps and stratigraphic sections. As results of this study, were defined two depositional cycles of second order, referred as Depositional Sequence 1 (SEQ1) and the Depositional Sequence 2 (SEQ2). The SEQ1, with interval about 37 Ma, is limited below by Early Devonian Unconformity and is equivalent to the formations Itaim, Pimenteiras and Cabeças. The SEQ2, which follows, comprises a range of about 15 Ma and is equivalent to the Longá Formation The SEQ1 starts with the lowstand systems tract, consisting of progradational parasequence set in the basal part, predominantly pelitic, deposited on a prodelta under influence of storms and the upper part consists in sandstones of deltaic front, with the maximum regressive surface on the upper limit. The transgressive systems tract, deposited above, is characterized by retrogradacional parasequence set composed of shallow shelf mudstones, deposited under storm conditions. The maximum flooding surface, upper limit of this tract, is positioned in a shale level whose radioactivity in gammaray well-log is close to 150 API. The highstand systems tract presents progradational parasequence set, comprising mudstones and sandstones deposited in shelf, fluvial-estuarine or deltaic and periglacial environments, with the upper limit the Late Devonian Unconformity. The SEQ2 was deposited in shelf environment, starting with the lowstand systems tract, that is characterized by a progradational parasequence set, followed by the transgressive systems tract, with retrogradational character. The upper limit of the tract corresponding to the fusion between maximum flooding surface with the upper limit of this sequence, which is the Early Carboniferous Unconformity, where the overlapping section was eroded. This section, which corresponds the highstand systems tract is restricted to portions at which the erosion that generate the Early-Carboniferous Unconformity was less effective, preserving the records of this unit.

Análise estratigráfica da sequência mesodevoniana-eocarbonífera da Bacia do Parnaíba, nordeste do Brasil

The Middle Devonian-Early Carboniferous sequence of the Parnaíba Basin, lithostratigraphically defined as Canindé Group, has been reinterpreted using the basic model of sequence stratigraphy. Therefore, lithology and gamma ray well-logs and seismic lines of central portion of the basin were analyzed, producing up from there diagrams 1D, isochore maps and stratigraphic sections. As results of this study, were defined two depositional cycles of second order, referred as Depositional Sequence 1 (SEQ1) and the Depositional Sequence 2 (SEQ2). The SEQ1, with interval about 37 Ma, is limited below by Early Devonian Unconformity and is equivalent to the formations Itaim, Pimenteiras and Cabeças. The SEQ2, which follows, comprises a range of about 15 Ma and is equivalent to the Longá Formation The SEQ1 starts with the lowstand systems tract, consisting of progradational parasequence set in the basal part, predominantly pelitic, deposited on a prodelta under influence of storms and the upper part consists in sandstones of deltaic front, with the maximum regressive surface on the upper limit. The transgressive systems tract, deposited above, is characterized by retrogradacional parasequence set composed of shallow shelf mudstones, deposited under storm conditions. The maximum flooding surface, upper limit of this tract, is positioned in a shale level whose radioactivity in gammaray well-log is close to 150 API. The highstand systems tract presents progradational parasequence set, comprising mudstones and sandstones deposited in shelf, fluvial-estuarine or deltaic and periglacial environments, with the upper limit the Late Devonian Unconformity. The SEQ2 was deposited in shelf environment, starting with the lowstand systems tract, that is characterized by a progradational parasequence set, followed by the transgressive systems tract, with retrogradational character. The upper limit of the tract corresponding to the fusion between maximum flooding surface with the upper limit of this sequence, which is the Early Carboniferous Unconformity, where the overlapping section was eroded. This section, which corresponds the highstand systems tract is restricted to portions at which the erosion that generate the Early-Carboniferous Unconformity was less effective, preserving the records of this unit.

Método híbrido para projeto de superfícies seletivas em frequência

This thesis presents a hybrid technique of frequency selective surfaces project (FSS) on a isotropic dielectric layer, considering various geometries for the elements of the unit cell. Specifically, the hybrid technique uses the equivalent circuit method in conjunction with genetic algorithm, aiming at the synthesis of structures with response single-band and dual-band. The equivalent circuit method allows you to model the structure by using an equivalent circuit and also obtaining circuits for different geometries. From the obtaining of the parameters of these circuits, you can get the transmission and reflection characteristics of patterned structures. For the optimization of patterned structures, according to the desired frequency response, Matlab™ optimization tool named optimtool proved to be easy to use, allowing you to explore important results on the optimization analysis. In this thesis, numeric and experimental results are presented for the different characteristics of the analyzed geometries. For this, it was determined a technique to obtain the parameter N, which is based on genetic algorithms and differential geometry, to obtain the algebraic rational models that determine values of N more accurate, facilitating new projects of FSS with these geometries. The optimal results of N are grouped according to the occupancy factor of the cell and the thickness of the dielectric, for modeling of the structures by means of rational algebraic equations. Furthermore, for the proposed hybrid model was developed a fitness function for the purpose of calculating the error occurred in the definitions of FSS bandwidths with transmission features single band and dual band. This thesis deals with the construction of prototypes of FSS with frequency settings and band widths obtained with the use of this function. The FSS were initially reviewed through simulations performed with the commercial software Ansoft Designer ™, followed by simulation with the equivalent circuit method for obtaining a value of N in order to converge the resonance frequency and the bandwidth of the FSS analyzed, then the results obtained were compared. The methodology applied is validated with the construction and measurement of prototypes with different geometries of the cells of the arrays of FSS.