半焦在流化床燃烧中Cl元素影响CO氧化的试验

在非均匀布风的流化床燃烧系统中进行了半焦中添加PVC/NaCl的混烧试验,研究了Cl元素对燃烧中CO氧化的影响以及混烧时SO_x等污染物的生成规律.试验结果表明,半焦与PVC/NaCl混烧在技术上可行,添加Cl元素抑制CO氧化,加入PVC增加SO_2排放,而加入NaCl则减少SO_2排放.

变截面流化床理论模型及数值模拟

基于双流体模型,在一定假设的条件下推导得到了用于描述变截面床流化过程的局部平衡模型。对于局部平衡模型,空间导数项的离散采用五阶精度的WENO有限差分格式,时间导数项的离散采用TVD Runge-Kutta型的离散格式,对流量突变后的瞬态过程进行了模拟,得到固相体积分数在整个变化过程中沿床高的分布以及床高变化规律和床层表面颗粒速度变化曲线。对于流量突增过程,在床内不同位置形成了一系列的连续波,当所有的连续波到达床面整个变化过程结束。而对于流量突然减小过程,将会有固相体积分数间断在分布板处形成,当所有间断到达床面时,塌落过程结束。

用激波管研究超音速气固两相流

在激波管里进行了可压缩性气固两相流的实验研究。测量了激波通过颗粒群时的压力的衰减过程。用纹影仪拍摄了激波与颗粒群相互干涉的照片。试验了颗粒群的不同构造对压力衰减的影响。指出了激波反射、聚焦等非线性气动因素是可压缩性气固两相流的关键问题。

非均匀布风对流化床密相床区燃烧温度的影响

由于采用非均匀布风，内旋流流化床的移动区空气量不足，导致燃烧不充分，温度较低。当移动区未流化时，密相区内存在较明显的温度不均匀性。随着移动区流速的提高，温度差迅速减小。当移动区流速超过2.0 u_(mf)后，密相区温度基本均匀一致。流动区流速对密相区温度均匀有一定的影响，流速越高，温度越均匀。

The effect of addition of ZrO2 to Fe2O3 for hydrogen production by chemical looping

In this paper, a synthetic mixture of ZrO2 and Fe 2O3 was prepared by coprecipitation for use in chemical looping and hydrogen production. Cycling experiments in a fluidized bed showed that a material composed of 30 mol % ZrO2 and 70 mol % Fe 2O3 was capable of producing hydrogen with a consistent yield of 90 mol % of the stoichiometric amount over 20 cycles of reduction and oxidation at 1123 K. Here, the iron oxide was subjected to cycles consisting of nearly 100% reduction to Fe followed by reoxidation (with steam or CO 2 and then air) to Fe2O3. There was no contamination by CO of the hydrogen produced, at a lower detection limit of 500 ppm, when the conversion of Fe3O4 to Fe was kept below 90 mol %. A preliminary investigation of the reaction kinetics confirmed that the ZrO2 support does not inhibit rates of reaction compared with those observed with iron oxide alone. © 2012 American Chemical Society.

Hard magnetic properties of Sm3Fe26.7VxN4 and Sm3Fe26.7VxCy

Sm3Fe26.7V2.3N4 nitrides and Sm3Fe26.7V2.3Cy carbides have been synthesized by gas-solid phase reaction. Their hard magnetic properties have been investigated by means of additional ball-milling at room temperature. The saturation magnetization of Sm3Fe26.7V2.3N4 almost decreases linearly with increasing ball-milling time t, but that of Sm3Fe26.7V2.3Cy has no obvious change when the ball-milling time increases from t = 1 to 28 h. As a preliminary result, the maximum remanence B-r of 0.94 and 0.88 T, the coercivity mu(0i)H(C) of 0.75 and 0.25 T, and the maximum energy product (BH) of 108.5 and 39.1 kJ/m(3) for their resin-bonded permanent magnets are achieved, respectively, by ball-milling at 293 K. (C) 1999 Published by Elsevier Science B.V. All rights reserved.