Ethyl (E)-2-methoxyimino-2-(4-nitrobenzoyl)acetate

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

(Z)-Ethyl 2-hydroxyimino-2-(4-nitrobenzyl)ethanoate

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Cellulose pyrolysis and quantum chemistry

Cellulose is the major constituent of most plants of interest as renewable sources of energy and is the most extensively studied form of biomass or biomass constituent. Predicting the mass loss and product yields when cellulose is subjected to increased temperature represents a fundamental problem in the thermal release of biomass energy. Unfortunately, at this time, there is no internally consistent model of cellulose pyrolysis that can organize the varied experimental data now available or provide a guide for additional experiments. Here, we present a model of direct cellulose pyrolysis using a multistage decay scheme that we first presented in the IJQC in 1984. This decay scheme can, with the help of an inverse method of assigning reaction rates, provide a reasonable account of the direct fast pyrolysis yield measurements. The model is suggestive of dissociation states of d-glucose (C6H10O5,), the fundamental cellulose monomer. The model raises the question as to whether quantum chemistry could now provide the dissociation energies for the principal breakup modes of glucose into C-1, C-2, C-3, C-4, and C-5 compounds. These calculations would help in achieving a more fundamental description of volatile generation from cellulose pyrolysis and could serve as a guide for treating hemicellulose and lignin, the other major biomass constituents. Such advances could lead to the development of a predictive science of biomass pyrolysis that would facilitate the design of liquifiers and gasifiers based upon renewable feedstocks. (C) 1998 John Wiley & Sons, Inc.

Image analysis of modified cellulose fibers from sugarcane bagasse by zirconium oxychloride

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

PREPARATION and CHARACTERIZATION of CELLULOSE/HYDROUS NIOBIUM PHOSPHATE HYBRID

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Sugarcane bagasse cellulose/HDPE composites obtained by extrusion

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Quantitative microscopy characterization of hydrous niobium phosphate into bleached cellulose

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

NOVEL CELLULOSE/NbOPO4 center dot nH(2)O HYBRID MATERIAL FROM SUGARCANE BAGASSE

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

SURFACE MODIFICATION of SUGARCANE BAGASSE CELLULOSE and ITS EFFECT on MECHANICAL and WATER ABSORPTION PROPERTIES of SUGARCANE BAGASSE CELLULOSE HDPE COMPOSITES

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Preparation and characterization of cellulose/hydrous niobium oxide hybrid

A composite of cellulose extracted from bagasse with Nb2O5 center dot nH(2)O in three different proportions (16.67, 37.5 and 50.0 wt%) was prepared using the co-precipitation method. The materials were characterized by X-ray diffractometry (XRD), Fourier transform infra-red spectroscopy (FTIR), thermogravimetric analysis (TG/DTG), differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). TG data obtained show that the presence of inorganic material influenced slightly the stability of the hybrid material. The precipitation of 16.67 wt.% of oxide was sufficient to inhibit the combustion peaks present in the DSC curve of cellulose. This work will help find new applications for these materials. Published by Elsevier Ltd.

Eficácia do carfentrazone-ethyl no controle de plantas aquáticas latifoliadas em caixas-d'água

Atualmente, alguns herbicidas estão sendo desenvolvidos para o controle de plantas daninhas aquáticas. O objetivo deste trabalho foi avaliar a eficácia do carfentrazone-ethyl em ambiente aquático para o controle pós-emergente de aguapé, alface-d'água e salvínia. O trabalho foi desenvolvido em caixas-d'água, no período de julho a setembro de 2004, no NUPAM - FCA/UNESP, em Botucatu. O delineamento experimental adotado foi o de blocos ao acaso, com sete tratamentos e quatro repetições, sendo as unidades experimentais constituídas pelas caixasd'água. Os tratamentos foram os seguintes: testemunha sem herbicida; Aurora 400 CE (75, 150 e 300 mL ha-1); Roundup (3,0 L ha-1), Aurora 400 CE + Roundup (75 mL + 3,0 L ha-1) e Aurora 400 CE + Arsenal N.A. (75 mL + 2,0 L ha-1). Observou-se que o tratamento Aurora 400 CE (300 mL ha-1) é altamente eficaz no controle de alface-d'água (Pistia stratiotes); o tratamento Roundup (3,0 L ha-1) é altamente eficaz no controle de aguapé (Eichhornia crassipes); o tratamento Aurora 400 CE + Roundup (75 mL + 3,0 L ha-1) é eficaz no controle de aguapé (E. crassipes), alface-d'água (P. stratiotes) e salvínia (Salvinia auriculata); e o tratamento Aurora 400 CE + Arsenal (75 mL + 2,0 L ha-1) é eficaz no controle de aguapé (E. crassipes) e alface-d'água (P. stratiotes). A mistura Aurora 400 CE + Roundup (75 mL + 3,0 L ha-1) apresentou-se viável e foi o único tratamento eficaz no controle das três espécies estudadas.

Influência do cálcio na calda de pulverização sobre a eficácia do carfentrazone-ethyl no controle de Euphorbia heterophylla

Alguns herbicidas podem ter sua eficácia de controle das plantas daninhas diminuída quando o cálcio encontra-se presente na calda de pulverização. Sendo assim, o presente trabalho foi desenvolvido com o objetivo de estudar a influência do cálcio na eficácia do herbicida carfentrazone-ethyl aplicado em pós-emergência sobre plantas adultas de Euphorbia heterophylla. Foram conduzidos dois experimentos com as concentrações de cálcio variando de 30 a 240 ppm e de 0 a 1.000 ppm respectivamente em cada experimento. O delineamento experimental utilizado foi o de blocos ao acaso, com quatro repetições. Observou-se que a eficácia do herbicida carfentrazone-ethyl não é afetada pela presença de cálcio em concentrações na calda de pulverização de até 1.000 ppm e que, na dose de 30 g i.a.ha-1 o herbicida é eficiente no controle de plantas adultas de E. heterophylla.

In situ application of a cellulose bag and an ion exchanger for differentiation of labile and inert metal species in aquatic systems

This work involved the development and application of a new analytical procedure for in-situ characterization of the lability of metal species in aquatic systems by using a system equipped with a diffusion membrane and cellulose organomodified with p-aminobenzoic acid groups (DM-Cell-PAB). To this end, the DM-Cell-PAB system was prepared by adding cellulose organomodified with p-aminobenzoic acid groups (Cell-PAB) to pre-purified cellulose bags. After the DM-Cell-PAB system was sealed, it was examined in the laboratory. The in-situ application involved immersing the DM-Cell-PAB system in two different rivers, enabling us to study the relative lability of metal species (Cu, Cd, Fe, Mn, and Ni) as a function of time and quantity of exchanger. The procedure is simple and opens up a new perspective for understanding environmental phenomena relating to the complexation, transport, stability, and lability of metal species in aquatic systems rich in organic matter.

Bacterial cellulose-silica organic-inorganic hybrids

Bacterial cellulose (BC) hydrated membranes present nanometric reticulated structure that can be used as a template in the preparation of new organic-inorganic hybrids. BC-silica hybrids were prepared from BC membranes and tetraethoxysilane, (TEOS) at neutral pH conditions at room temperature. Macroscopically homogeneous membranes were obtained containing up to 66 wt.% of silica spheres, 20-30 nm diameter. Scanning electron micrographs clearly show the silica spheres attached to cellulose microfibrils. By removing the cellulose, the silica spheres can be easily recovered. The new hybrids are stable up to 300 degrees C and display a broad emission band under UV excitation assigned to oxygen-related defects at the silica particles surface. Emission color can be tuned by changing the excitation wavelength.

Cellulose nanowhiskers from coconut husk fibers: Effect of preparation conditions on their thermal and morphological behavior

Cellulose nanowhiskers were prepared by sulfuric acid hydrolysis from coconut husk fibers which had previously been submitted to a delignification process. The effects of preparation conditions on the thermal and morphological behavior of the nanocrystals were investigated. Cellulose nanowhisker suspensions were characterized by Fourier transform infrared spectroscopy (FTIR), transmission electron microscopy (TEM), thermogravimetric analysis (TGA) and X-ray diffraction. Results showed that it was possible to obtain ultrathin cellulose nanowhiskers with diameters as low as 5 nm and aspect ratio of up to 60. A possible correlation between preparation conditions and particle size was not observed. Higher residual lignin content was found to increase thermal stability indicating that by controlling reaction conditions one can tailor the thermal properties of the nanowhiskers. Published by Elsevier Ltd.