Preparação de compostos de alumínio a partir da bauxita: considerações sobre alguns aspectos envolvidos em um experimento didático

Aluminum metal and aluminum compounds have many applications in several branches of the industry and in our daily lives. The most important raw material for aluminum and its manufactured compounds is bauxite, a rock constituted mainly by aluminum hydroxides minerals. In this work, a didactic experiment aiming the preparation of alumina and potassium alum starting from bauxite is proposed for undergraduate students. Both compounds are of great commercial, scientific and historical interest. The experiment involves applications of important chemical principles such as acid-base and precipitation. Some chemical properties and uses of aluminum compounds are also illustrated.

Indicadores naturais de pH: usar papel ou solução?

In this work, the fruit extracts of Morus nigra - mulberry, Syzygium cuminii - jambolão, Vitis vinifera ¾ grape, Myrciaria cauliflora - jabuticaba are suggested as pH indicators in the form of either solutions or paper. The pH indicator solutions were prepared by soaking the fruits or their peels in ethanol 1:3 (m/V) for 24 h, followed by simple filtration. The pH indicator papers were prepared by imersion of the qualitative filter paper strips in the pH indicator solutions. The different pH leads to color changes in the indicator solutions or papers and it can be used for teaching elementary chemistry concepts.

Construção e aplicação de eletrodo de aço inoxidável UNS S31254 como eletrodo indicador em titulações condutimétricas

UNS S31254 SS electrodes have been built to substitute platinum in conductimetric titrations. The electrodes were tested in both acid-basic titration (chloridric acid and sodium hydroxide) and precipitation titration (sodium chloride and argentum nitrate as titrant). The practical application was exemplified from conductimetric tritations of HF ¾ HNO3 mixtures used in metalurgical industry to passivate stainless steels. The results were compared with those obtained using commercial platinum electrodes. The equivalent volumes obtained were comparable within 3% experimental error. Its application depends on the nature of electrolyte. These results have shown that stainless steel, less expensive than platinum (about three order of magnitude), can substitute platinum electrodes in routine analyses and didactic laboratories.

Decomposição térmica do bicarbonato de sódio: do processo Solvay ao diagrama tipo Ellingham

A didactic experiment based on the thermal decomposition of sodium bicarbonate using a reagent found in the marketplace is proposed. The reaction products are identified by qualitative tests and stoichiometric calculations. The thermal stability of carbonates and the influence of lattice energies are discussed, emphasizing periodic trends in the alkali and alkaline earth families. The industrial importance of the reaction is also explored.

Química geral experimental: uma nova abordagem didática

This essay describes a new didactic approach, in according with the national curriculum guidelines for chemistry undergraduate courses in Brazil, employed during the one-semester course "Experimental General Chemistry" for chemistry undergraduate students at the Federal University of Piauí. The new approach has positively helped student's training by improving their reading skills and their understanding of scientific reports, by developing the use of electronic tools to search and to recover the required knowledge for their learning activities, and by improving their skills of understanding published texts and dealing with digital sources. At the same time the students are strongly stimulated to enter the research program for undergraduate students available at the University.

Entrenamiento de la fuerza orientado a la mejora de la velocidad de golpeo en tenis

El golpeo de la bola a velocidades elevadas, es un factor determinante para el rendimiento en el tenis moderno. Durante los últimos 20 años se ha producido una gran evolución del juego y los cambios en el juego moderno se han traducido en el uso de poderosos servicios y golpes de fondo. Aunque la fuerza es una capacidad determinante desde la perspectiva de la condición física, ha habido poca investigación para fundamentar la eficacia de los programas de entrenamiento de fuerza para los jugadores de tenis. El objetivo de este estudio es realizar una revisión sobre los criterios básicos para dirigir correctamente el entrenamiento de la fuerza orientado a la mejora de la de la velocidad de golpeo de la pelota. Aunque las necesidades de fuerza dinámica máxima (FDM) en los golpeos son bajas, la literatura científica parece apuntar que unos adecuados niveles de FDM ejercen efectos positivos sobre el aumento de velocidad de golpeo en el tenis. La mejora y mantenimiento de esta manifestación de fuerza se busca a expensas de factores neurales. Los entrenamientos de fuerza útil deben utilizar medios que permitan ejecutar el gesto técnico, implicar las mismas cadenas musculares, rango de movimiento o velocidades de ejecución. En este sentido, se han propuesto la utilización de pelotas medicinales, mancuernas de peso ligero, gomas elásticas, máquinas multifuncionales de resistencia neumática o poleas.

Asma y actividad física. Revisión

El asma es una enfermedad inflamatoria crónica de elevada prevalencia a nivel mundial, siendo el colectivo más afectado el formado por niños y adolescentes. Su sintomatología se caracteriza por la aparición de tos, disnea, sibilancias, sensación de opresión en el pecho y broncoconstricción. Tradicionalmente se había pensado que el deporte y el ejercicio físico estaban contraindicados en pacientes asmáticos. Por otro lado, el paciente asmático suele presentar niveles de condición física y práctica deportiva menores que los sujetos sanos. Actualmente se ha propuesto la actividad física regular como un camino válido para mejorar la percepción y el autoconocimiento personal sobre esta enfermedad. Se aconseja la prescripción de actividad física como forma de mejorar su sintomatología y evolución. La práctica de una actividad física regular en pacientes asmáticos debería ser considerada dentro de los actuales y futuros programas de salud como un objetivo fundamental.

Análise de imagem em química analítica: empregando metodologias simples e didáticas para entender e prevenir o escurecimento de tecidos vegetais

A simple and didactic experiment was developed for image monitoring of the browning of fruit tissues caused by the enzyme polyphenol oxidase. The procedure, easy and inexpensive, is a valuable tool to teach and demonstrate the redox reaction between the enzyme and the natural polyphenols. To obtain the browning percentage for apple, pear and banana, digital photographs were employed, and the images were analyzed by means of Monte Carlo methods and digital analysis programs. The effects of several experimental conditions were studied, such as pH, light, temperature and the presence of oxygen or anti-oxidants. It was observed that each fruit presented a different condition that better minimized the oxidation process. The absence of oxygen and the application of a bissulphite solution were sufficient to keep the quality of all fruits tested.

Síntese de biodiesel: uma proposta contextualizada de experimento para laboratório de química geral

The contextualized understanding of concepts in Chemistry by students from other areas is a challenging task. In this experiment, the synthesis of biodiesel is done by base catalyzed transesterification of refined soy oil with methanol at room temperature and common glassware found in any chemistry laboratory. The proposal permits introducing several concepts, such as that of emulsion, viscosity and catalysis to illustrate an activity based on an actual problem. In this didactic approach, some common problems of biodiesel production, such as soap formation and phase separation, are introduced into the procedure in order to raise questions and motivate the students to participate in the experimental work and stimulate reflections about critical aspects of biodiesel production. This experiment was carried out in the first semester of 2006, in experimental general chemistry taken by physics and agricultural, civil and chemical engineering students of UNICAMP.

Simulando catástrofes : recursos para la enseñanza de los riesgos naturales

Los riesgos naturales son abordados por distintas asignaturas de ciencias naturalesa lo largo de la ESO y el bachillerato. Su tratamiento en el aula es una evidencia del interés y el carácter aplicado de muchos aspectos de las ciencias de la tierra. Para facilitar su enfoque didáctico se proponen algunas actividades prácticas

Los Riesgos geológicos: algunas consideraciones didácticas

From the development of concepts related with Natural and Geological Hazards different exercises and activities are proposed. All of them can be used as didactic recourses in order to study such a subject for the most appropriate educative levels

Considerações sobre o papel da comunicação científica na educação em química

In the present work, we provide some considerations about the role of scientific communication in Chemistry Education. Such considerations may subsidize the development of communication in scientific language by Chemistry students. These considerations are based on information collected during a participatory research for the production of didactic material about scientific communication. The meetings were audio recorded and the contents of the participants' speeches were divided into categories. The category analysis supported the elaboration of the considerations.

Uso de scanner em espectrofotometria de absorção molecular: aplicação em experimento didático enfocando a determinação de ácido ascórbico

Quantitative analysis of colored substances is generally performed using a spectrophotometer for detection of radiation. However, the combination of digital images and mathematical conversion of colors is an alternative for quantitative procedures based on colored chemical reactions. This work proposes a didactic experiment using a scanner for determination of ascorbic acid in medicines based on the formation of the Prussian blue complex. Results were in good agreement with a conventional spectrophotometer method and the procedure is attractive for instrumental analysis undergraduate courses.

Eletrodo compósito à base de grafite-araldite®: aplicações didáticas

A composite electrode prepared by mixing a commercial epoxy resin Araldite® and graphite powder is proposed to be used in didactic experiments. The electrode is prepared by the students and applied in simple experiments to demonstrate the effect of the composite composition on the conductivity and the voltammetric response of the resulting electrode, as well as the response in relation to the scan rate dependence on mass transport. The possibility of using the composite electrode in quantitative analysis is also demonstrated.

Conflicto, colaboración y consenso en la enseñanza de las ciencias sociales = Conflict, collaboration and consensus in the teaching of the Social sciences

This article suggests the study of the key concept of conflict as a means of implementing a critical and communicativecurriculum based on the study of relevant social themes. To this end we put forward the principal characteristics of thecritical/communicative curriculum. We offer a didactic proposal about conflict and explain the results of its application intwo Secondary Education classrooms