Hydrogen Production by Steam Reforming of Ethanol on Rh-Pt Catalysts: Influence of CeO2, ZrO2, and La2O3 as Supports

CeO2-, ZrO2-, and La2O3-supported Rh-Pt catalysts were tested to assess their ability to catalyze the steam reforming of ethanol (SRE) for H2 production. SRE activity tests were performed using EtOH:H2O:N2 (molar ratio 1:3:51) at a gaseous space velocity of 70,600 h−1 between 400 and 700 °C at atmospheric pressure. The SRE stability of the catalysts was tested at 700 °C for 27 h time on stream under the same conditions. RhPt/CeO2, which showed the best performance in the stability test, also produced the highest H2 yield above 600 °C, followed by RhPt/La2O3 and RhPt/ZrO2. The fresh and aged catalysts were characterized by TEM, XPS, and TGA. The higher H2 selectivity of RhPt/CeO2 was ascribed to the formation of small (~5 nm) and stable particles probably consistent of Rh-Pt alloys with a Pt surface enrichment. Both metals were oxidized and acted as an almost constant active phase during the stability test owing to strong metal-support interactions, as well as the superior oxygen mobility of the support. The TGA results confirmed the absence of carbonaceous residues in all the aged catalysts.

Enantioselective addition of aryl ketones and acetone to nitroalkenes organocatalyzed by carbamate-monoprotected cyclohexa-1,2-diamines

Enantiomerically pure carbamate-monoprotected trans-cyclohexane-1,2-diamines are used as chiral organocatalysts for the addition of aryl ketones and acetone to nitroalkenes to give enantioenriched β-substituted γ-nitroketones. The reaction was performed in the presence of 3,4-dimethoxybenzoic acid as an additive, in chloroform as the solvent at room temperature, achieving enantioselectivities up to 96%. Theoretical calculations are used to justify the observed sense of the stereoinduction.

Reforming the System of Financing the EU Budget. Egmont European Affairs Paper, January 2013

No abstract.

Reforming the Market Design of EU Electricity Markets: Addressing the Challenges of a Low-Carbon Power Sector. CEPS Task Force Report, 27 July 2015

This CEPS Task Force Report focuses on whether there is a need to adapt the EU’s electricity market design and if so, the options for doing so. In a first step, it analyses the current market trends by distinguishing between their causes and their consequences. Then, the current blueprint of EU power market design – the target model – is briefly introduced, followed by a discussion of the shortcomings of the current approach and the challenges in finding suitable solutions. The final chapter offers an inventory of solutions differentiating between recommendations shared among Task Force members and non-consensual options.

Reforming government : what really needs to be done? : hearing before the Committee on Governmental Affairs, United States Senate, One Hundred Third Congress, second session, January 27, 1994.

Shipping list no.: 95-0021-P.

Reforming postal procurement and contracting : Eagle Air hub example : hearing before the Committee on Governmental Affairs, United States Senate, One Hundred Second Congress, second session, September 24, 1992.

Shipping list no.: 93-0298-P.

The Clinton administration's policy on reforming multinational peace operations.

Mode of access: Internet.

Reforming federal deposit insurance /

Author from p. [iii].

Ketones: acetone, methyl ethyl ketone (MEK), methyl isobutyl ketone (MIBK).

Mode of access: Internet.

A defence of the reformation-principles of the Church of Scotland : with a continuation of the same : and a letter from a member of the Associate Presbytery to a minister in the Presbytery of D---e, wherein the exceptions that are laid aginst the conduct of the Associate Presbytery, as also against their judicial act and testimony, by the Rev. Mr. Currie in his Essay on separation, are examined and the injurious reflections cast upon our reforming period from 1638 to 1650, in the foresaid essay, are discovered /

Added title pages for: A continuation of the defence. A letter from a member of the Associate Presbytery.

Conductibilites limites de quelques electrolytes dans l'acetone...

Thesis (doctoral)--

The absorption spectra of solutions of certain salts of cobalt, nickel, copper, iron, chromium, neodymium, praseodymium, and erbium in water, methyl alcohol, ethyl alcohol, and acetone, and in mixtures of water with the other solvents.

"A continuation of the work of Jones and Uhler on the absorption spectra of solutions (Carnegie publication no. 60)" cf. Pref.

Reforming federal hiring : beyond faster and cheaper : a report to the President and the Congress of the United States by the U.S. Merit Systems Protection Board.

Includes bibliographical references.

Preparation and catalytic properties of ZrO2-Al2O3 composite oxide supported nickel catalysts for methane reforming with carbon dioxide

ZrO2-Al2O3 composite oxides and supported Ni catalysts were prepared, and characterized by N-2 adsorption/desorption, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) techniques. The catalytic performance and carbon deposition was also investigated. This mesoporous composite oxide is shown to be a promising catalyst support. An increase in the catalytic activity and stability of methane and carbon dioxide reforming reaction was resulted from the zirconia addition, especially at 5wt% ZrO2 content. The Ni catalyst supported ZrO2-Al2O3 has a strong resistance to sintering and the carbon deposition in a relatively long-term reaction.