Charcoal production using tropical pine thinnings

In Brazil, the wood from pine-plantation thinnings is difficult to sell. However, these wood thinnings could be used to produce charcoal. The physical and chemical properties of charcoal produced from logs or first and fourth thinnings of Pinus caribaea var. hondurensis and Pinus oocarpa were determined. Similar properties were also determined for sawmill slabs cut from first and fourth thinnings. Properties were compared to charcoal made from pine materials and 7-yr-old Eucalyptus grandis. Results show that Pinus spp had better chemical properties than did E. grandis. In contrast, charcoal obtained from E. grandis had higher values of apparent density and lower values of bulk density than did Pinus spp. © 1992.

Stacking faults in SiCf/SiC composite obtained by chemical vapor reaction process

SiC fiber-reinforced SiC matrix composite (SiCf/SiC) is one of the leading candidates in ceramic materials for engineering applications due to its unique combination of properties such as high thermal conductivity, high resistance to corrosion and working conditions. Fiber-reinforced composites are materials which exhibit a significant improvement in properties like ductility in comparison to the monolithic SiC ceramic. The SiCf/SiC composite was obtained from a C/C composite precursor using convertion reaction under high temperature and controlled atmosphere. In this work, SiC phase presented the stacking faults in the structure, being not possible to calculate the unit cell size, symmetry and bond lengths but it seem equal card number 29-1129 of JCPDS.

Effect of different radiopacifying agents on the physicochemical properties of white portland cement and white mineral trioxide aggregate

Introduction: The aim of this study was to evaluate the pH, calcium ion release, setting time, and solubility of white mineral trioxide aggregate (WMTA) and white Portland cement (WPC) combined with the following radiopacifying agents: bismuth oxide (BO), calcium tungstate (CT), and zirconium oxide (ZO). Methods: Fifty acrylic teeth with root-end filling material were immersed in ultrapure water for measurement of pH and calcium release (atomic absorption spectrophotometry) at 3, 24, 72, and 168 hours. For evaluation of setting time, each material was analyzed according to the American Society for Testing and Materials guidelines 266/08. The solubility test was performed according to American National Standards Institute/American Dental Association specification no. 57/2000. Solubility, setting time, and pH values were compared by using analysis of variance and Tukey test, and the values of calcium release were compared by the Kruskal-Wallis and Miller tests. The significance level was set at 5%. Results: The pH and calcium release were higher at 3 and 24 hours. WPC was the material with the higher values for both properties. WMTA had the greatest solubility among all materials (P <.05). All radiopacifiers increased the setting time of WPC, and WMTA had the shortest setting time among all materials (P < .05). Conclusions: All materials released calcium ions. Except for WPC/CT at 168 hours, all materials promoted an alkaline pH. On the basis of the obtained results, ZO and CT can be considered as potential radiopacifying agents to be used in combination with Portland cement. Copyright © 2012 American Association of Endodontists.

Chemical characterization and flexural strength of a denture base acrylic resin with monomer 2-tert-butylaminoethyl methacrylate

Purpose: The objectives of this study were to investigate the flexural strength (FS) and chemical interaction between 2-tert-butylaminoethyl methacrylate (TBAEMA) and a denture base acrylic resin. Materials and Methods: Specimens were divided into five groups according to the concentration of TBAEMA incorporated in acrylic resin Onda-Cryl (0%, 1%, 2%, 3%, 4%) and were submitted to Fourier transform infrared spectroscopy (FTIR), electron spectroscopy for chemical analysis (XPS-ESCA), and differential scanning calorimetry (DSC) analyses. FS of the specimens was tested, and results were analyzed by ANOVA/Tukey's test (α < 0.05). Results: Different nitrogen ratios were observed on specimens' surfaces: 0.36%, 0.54%, 0.35%, and 0.20% for groups 1%, 2%, 3%, and 4%, respectively. FTIR indicated copolymerization of acrylic resin and TBAEMA, and DSC results demonstrated a decrease in glass transition temperature (Tg). Significant differences were found for FS (p < 0.05). The mean values were 91.1 ± 5.5,A 77.0 ± 13.1,B 67.2 ± 12.5,B 64.4 ± 13.0,B and 67.2 ± 5.9B MPa for groups 0%, 1%, 2%, 3% and 4%, respectively (same superscript letters indicate no significant difference). Conclusions: The incorporation of TBAEMA in acrylic resin resulted in copolymerization and the presence of amine groups on specimens' surfaces, and in decreases of Tg and FS. © 2012 by the American College of Prosthodontists.

Physico-chemical characterization of seed oils extracted from oranges (Citrus sinensis)

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Evaluation of the chemical interaction between carbon nanotubes functionalized with TGDDM tetrafunctional resin and hardener DDS

In this work, the chemical interaction between carbon nanotubes (MWCNT) functionalized with acyl chloride (SOCl2) and polymer chain tetrafuncional N,N,N′,N′-tetraglycidyl-4,4′- diaminodiphenylmethane (TGDDM) and hardener 4,4′diaminodiphenyl sulfone (DDS) has been monitored by Fourier transform infrared spectroscopy (FTIR) with a attenuated total reflectance (ATR) coupled. MWCNT were obtained from the pyrolysis of a mixture of camphor and ferrocene into a oven. The functionalization process was done by oxidative treatment in order to incorporate carboxylic group over the walls of MWCNT, before to be used SOCl2. The functionalized carbon nanotubes were evaluated by X-ray photoelectron spectroscopy (XPS), Raman and transmission electron microscopy (TEM). Nanostructured composites were processed by using epoxy resin with MWCNT in varying percentages. In this work it was observed that different percentages of functionalized nanotubes modify the interaction between the composite matrix and curing agent, where can be observed that in specimens with content less than 1 wt% MWCNT the chemical bond occurs preferentially from the opening of the SO double bond of the hardener and when is used MWCNT content higher than 1 wt% there is little chemical interaction with the SO bond of the hardener and most MWCNT binds to amine. © 2013 Elsevier Ltd.

Sugarcane vinasse: Environmental implications of its use

The inadequate and indiscriminate disposal of sugarcane vinasse in soils and water bodies has received much attention since decades ago, due to environmental problems associated to this practice. Vinasse is the final by-product of the biomass distillation, mainly for the production of ethanol, from sugar crops (beet and sugarcane), starch crops (corn, wheat, rice, and cassava), or cellulosic material (harvesting crop residues, sugarcane bagasse, and wood). Because of the large quantities of vinasse produced, alternative treatments and uses have been developed, such as recycling of vinasse in fermentation, fertirrigation, concentration by evaporation, and yeast and energy production. This review was aimed at examining the available data on the subject as a contribution to update the information on sugarcane vinasse, from its characteristics and chemical composition to alternatives uses in Brazil: fertirrigation, concentration by evaporation, energy production; the effects on soil physical, chemical and biological properties; its influence on seed germination, its use as biostimulant and environmental contaminant. The low pH, electric conductivity, and chemical elements present in sugarcane vinasse may cause changes in the chemical and physical-chemical properties of soils, rivers, and lakes with frequent discharges over a long period of time, and also have adverse effects on agricultural soils and biota in general. Thus, new studies and green methods need to be developed aiming at sugarcane vinasse recycling and disposal. © 2013 Elsevier Ltd. All rights reserved.

Desempenho do stellite como material de ferramenta no serramento da madeira

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudos químicos e anatômicos de cascas de clones de Eucalyptus

The barks generated from the wood processing industries are wastes generated in significant quantities, becoming interesting to have basic studies of their anatomical and chemical properties in order to make better use of this material. This study aimed to carry out anatomical studies, chemical and tannins from the barks of commercial clones of Eucalyptus. For this, permanent histological slides for anatomical characterization and percentage of cellular elements were prepared; and cellular elements were dissociated for biometry of the elements. The analyses were related to chemical extractives, ash, lignin, suberin, sugars, phenols, tannins, flavonoids and antioxidant activity of the extracts. The tannins were extracted in pure water and with water mixed with sodium sulfite, and were subsequently evaluated the properties by FT-IR. It was verified by the anatomical characterization and chemical quantification, the similarity between the clones. Regarding the biometrics of cellular elements, statistically significant differences were not observed for the following parameters: length and diameter of sieve tube, axial parenchyma diameter, and rays hight. The yield of condensed tannins and Stiasny index for studied clones are low, showing the infeasibility of using bark for the extraction of tannins to produce adhesives, however tannins and other bioactive phenolic compounds can be used in the pharmaceutical and cosmetics sectors due to its antioxidant potential. The spectrum of tannins is the same as the one found the literature. Due to the high yield of verified sugar, (around 46,68%) sugars are potencial products, with a high yield of glucose , it is interesting for application in biorefinery.

Estudo comparativo da madeira e polpação de Eucalyptus urophylla e do híbrido E. urophylla x E. grandis em dois modelos silviculturais

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Efeito da vaporização na madeira de Eucalyptus grandis sobre as suas propriedades químicas e resistência natural a fungos e cupins

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Propriedades químico-mineralógicas e cerâmicas de rochas da formação Corumbataí: aplicação na diversificação de produtos

Pós-graduação em Geologia Regional - IGCE

Sugarcane trash management assessed by the interaction of yield with soil properties

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Synthesis and photocatalytic properties of bismuth titanate with different structures via oxidant peroxo method (OPM)

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Magnetic susceptibility and diffuse reflectance spectroscopy to characterize the spatial variability of soil properties in a Brazilian Haplustalf

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)