Putkilämmönsiirtimien mitoitustyökalujen kehittäminen

Diplomityön tarkoituksena on kehittää tietokoneohjelma putkilämmönsiirtimen vaippapuolen painehäviön laskemiseksi. Ohjelmalla voidaan varmistaa lämmönsiirtimen mitoitusvaiheessa, että vaippapuolen painehäviö ei ylitä sallittuja rajoja. Ohjelmatäydentää olemassa olevia mitoitusohjelmia. Tässä diplomityössä käsitellään ainoastaan höyryvoimalaitosprosesseissa käytettäviä putkilämmönsiirtimiä. Työn kirjallisessa osassa on selvitetty periaate höyryvoimalaitosprosessista ja siinä käytettävistä putkilämmönsiirtimistä sekä esitetty putkilämmönsiirtimien rakenne, yleinen suunnittelu ja lämpö- ja virtaustekninen mitoitus. Painehäviön laskennassa käytetyt ja lämpö- ja virtausteknistä mitoitusta käsittelevässä kappaleessa esitetyt yhtälöt perustuvat Bell-Delawaren menetelmään. Painehäviönlaskentaohjelma on toteutettu hyväksikäyttäen Microsoft Excel taulukkolaskentaa ja Visual Basic -ohjelmointikieltä. Painehäviön laskenta perustuu segmenttivälilevyillä varustetun putkilämmönsiirtimen vaippapuolen yksifaasivirtaukseen. Lämmönsiirtimen lauhdutinosan painehäviö oletetaan merkityksettömäksi, joten kokonaispainehäviö muodostuu höyryn- ja lauhteenjäähdyttimessä. Kehitetty ohjelma on suunniteltu erityisesti lauhteenjäähdyttimessä muodostuvan painehäviön laskentaan. Ohjelmalla laskettuja painehäviön arvoja on verrattu todellisesta lämmönsiirtimestä mitattuihin arvoihin. Lasketut arvotvastaavat hyvin mittaamalla saatuja, eikä tuloksissa ilmene mitään systemaattista virhettä. Ohjelma on valmis käytettäväksi putkilämmönsiirtimien mitoitustyökaluna. Diplomityön pohjalta on tehty ehdotukset ohjelman edelleen kehittämiseksi.

Flow phenomena, heat and mass transfer in microchannel reactors

The studies of flow phenomena, heat and mass transfer in microchannel reactors are beneficial to estimate and evaluate the ability of microchannel reactors to be operated for a given process reaction such as Fischer-Tropsch synthesis. The flow phenomena, for example, the flow regimes and flow patterns in microchannel reactors for both single phase and multiphase flow are affected by the configuration of the flow channel. The reviews of the previous works about the analysis of related parameters that affect the flow phenomena are shown in this report. In order to predict the phenomena of Fischer-Tropsch synthesis in microchannel reactors, the 3-dimensional computational fluid dynamic simulation with commercial software package FLUENT was done to study the flow phenomena and heat transfer for gas phase Fischer-Tropsch products flow in rectangular microchannel with hydraulic diameter 500 ¿m and length 15 cm. Numerical solution with slip boundary condition was used in the simulation and the flowphenomena and heat transfer were determined.

Effect of Noncondensable Gases on Circulation of Primary Coolant in Nuclear Power Plants in Abnormal Situations

The present study focuses on two effects of the presence of a noncondensable gas on the thermal-hydraulic behavior of thecoolant of the primary circuit of a nuclear reactor in the VVER-440 geometry inabnormal situations. First, steam condensation with the presence of air was studied in the horizontal tubes of the steam generator (SG) of the PACTEL test facility. The French thermal-hydraulic CATHARE code was used to study the heat transfer between the primary and secondary side in conditions derived from preliminary experiments performed by VTT using PACTEL. In natural circulation and single-phase vapor conditions, the injection of a volume of air, equivalent to the totalvolume of the primary side of the SG at the entrance of the hot collector, did not stop the heat transfer from the primary to the secondary side. The calculated results indicate that air is located in the second half-length (from the mid-length of the tubes to the cold collector) in all the tubes of the steam generator The hot collector remained full of steam during the transient. Secondly, the potential release of the nitrogen gas dissolved in the water of the accumulators of the emergency core coolant system of the Loviisa nuclear power plant (NPP) was investigated. The author implemented a model of the dissolution and release ofnitrogen gas in the CATHARE code; the model created by the CATHARE developers. In collaboration with VTT, an analytical experiment was performed with some components of PACTEL to determine, in particular, the value of the release time constant of the nitrogen gas in the depressurization conditions representative of the small and intermediate break transients postulated for the Loviisa NPP. Such transients, with simplified operating procedures, were calculated using the modified CATHARE code for various values of the release time constant used in the dissolution and release model. For the small breaks, nitrogen gas is trapped in thecollectors of the SGs in rather large proportions. There, the levels oscillate until the actuation of the low-pressure injection pumps (LPIS) that refill the primary circuit. In the case of the intermediate breaks, most of the nitrogen gas is expelled at the break and almost no nitrogen gas is trapped in the SGs. In comparison with the cases calculated without taking into account the release of nitrogen gas, the start of the LPIS is delayed by between 1 and 1.75 h. Applicability of the obtained results to the real safety conditions must take into accountthe real operating procedures used in the nuclear power plant.

Effect of pressure on La2(WO4)3 with a modulated scheelite-type structure

We have studied the effect of pressure on the structural and vibrational properties of lanthanum tritungstate La2(WO4)3. This compound crystallizes under ambient conditions in the modulated scheelite-type structure known as the α phase. We have performed x-ray diffraction and Raman scattering measurements up to a pressure of 20 GPa, as well as ab initio calculations within the framework of the density functional theory. Up to 5 GPa, the three methods provide a similar picture of the evolution under pressure of α-La2(WO4)3. At 5 GPa, we begin to observe some structural changes, and above 6 GPa we find that the x-ray patterns cannot be indexed as a single phase. However, we find that a mixture of two phases with C2/c symmetry accounts for all diffraction peaks. Our ab initio study confirms the existence of several C2/c structures, which are very close in energy in this compression range. According to our measurements, a state with medium-range order appears at pressures above 9 and 11 GPa, from x-ray diffraction and Raman experiments, respectively. Based upon our theoretical calculations we propose several high-pressure candidates with high cationic coordinations at these pressures. The compound evolves into a partially amorphous phase at pressures above 20 GPa.

Preparação de nanocompósitos através do encapsulamento de polímeros condutores em 2H-MoS2 e 1T-TiS2

Nanocomposites obtained by the encapsulation of conducting polymers such as polyaniline and polydiphenylamine in 2H-MoS2 and 1T-TiS2 are synthesized and characterized by X-ray diffraction and infrared spectrophotometry. The synthesis consists in intercalating the layered compound with n-butyllithium and subsequent exfoliation in water and organic solvents. The nanocomposites are obtained by the adsorption of the polymers into the single-layers sulfides and posterior restacking. The X-ray diffraction measurements showed that the organic conducting polymers are encapsulated in mono and bilayers arrangement in a well-ordered fashion to produce single phase compounds.

Extração líquido-líquido em sistemas de fluxo

This review deals with principles of the liquid-liquid extraction, when performed in flow systems. This approach is frequently used for sample treatment to improve the selectivity and/or sensitivity in analytical measurements. The advances in this area are reported, including the use of monosegmented flow systems to perform metal extraction through both two-phase and single phase processes.

Monitoisioisen muuntajan parametrien mittaus

Tässä kandidaatintyössä on tarkoitus määrittää monitoisioisen muuntajan yksivaiheisen sijaiskytkentä ja sen parametrit käyttämällä perinteisiä mittausmenetelmiä. Näihin kuuluvat tyhjäkäynti-, oikosulku- sekä tasajännitekoe. Muuntajasta on tehty simulointimalli, jota varten sijaiskytkennän parametreja tarvitaan.

Síntese e caracterização dos nanocompósitos K0,1(PEO)xMoS2 (X= 0,5; 1,2)

The reaction of an aqueous solution of poly(ethylene oxide) (peo - mw 100.000) with a neutral aqueous suspension of single layers of MoS2 was studied. The single layers aqueous suspension was prepared by first intercalating lithium (using n-Butyllithium in n-hexane) and reaction of these ternary compound with water under ultrasound stirring. The suspension was washed several times with water until neutral pH. The suspension was mixed with the PEO aqueous solution in the presence of KCl. Two single phase compounds were obtained with the expansion of 4,8 and 9,0Å, attributed to the solvation of the intercalated potassium cations with mono and double layers, respectively.

Heat Transfer in Plate Heat Exchangers

This study illustrates the different types of plate heat exchangers that are commonly used in various domestic and industrial applications. The main purpose of this paper was to devise a methodology that is capable of calculating optimum number of plates in the design of a plate heat exchanger. To obtain the appropriate number of plates, typically several iterations must be made before a final acceptable design is completed, since plate amount depends on many factors such as, flow velocities, physical properties of the streams, flow channel geometry, allowable pressure drop, plate dimensions, and the gap between the plates. The methodology presented here can be used as a general guide for designing a plate heat exchanger. To investigate the effects of relevant parameters on the thermal-hydraulic design of a plate heat exchanger, several experiments were carried out for single-phase and counter flow arrangement with two brazed plate heat exchangers by varying the flow rates and the inlet temperatures of the fluid streams. The actual heat transfer coefficients obtained based on the experiment were nearly close to the calculated values and to improve the design, a correction factor was introduced. Besides, the effect of flow channel velocity on the pressure drop inside the unit is presented.

Tasasähkönjakeluverkon asiakaspäätelaitteen galvaanisen erotuksen toteuttaminen

Tässä työssä tutkitaan LLC resonanssipiirin soveltuvuutta galvaanisen erotuksen toteuttamiseen tasasähkönjakeluverkon asiakaspäätelaitteessa. Tarkastellaan resonanssipiirin ominaisuuksia ja aikaisempia käyttökohteita. Tutkitaan piirin soveltuvuutta vaihtosähkö sovellukseen ja esitellään piirin toimintaa, häviöitä ja ohjausta. Esitellään pulssin leveys moduloitu (PWM) ja pulssin tiheys moduloitu (PDM) invertteri sovellukset ja näiden toimintaa. Esitetään vielä parannusehdotuksia ja kytkentäkuvio kytkennän ominaisuuksien ja hyö-tysuhteen parantamiseksi. Tutkimuksessa selvisi, että suora PDM topologia ei sovellu tähän käyttötarkoitukseen suuren suodin induktanssin vuoksi. PWM invertteri topologia jännitteen tasasuuntauksella taas sopii sovellukseen ja tällä rakenteella on mahdollista tehdä galvaaninen erotus hyvinkin hyvällä hyötysuhteella. Pehmeän kytkennän aiheuttamien häviöiden tarkka määrittely simulointimallista on parhaimmillaankin vain suuntaa-antava, mutta tulokset olivat mielestäni oikein positiivisia. LLC resonanssipiirin toimintaa tutkittiin vain resonanssitaajuudella kytkettäessä, jolloin sen jännitevahvistusominaisuuksien hyödyntäminen jää tarkastelun ulko-puolelle.

Tasasähkönjakeluverkon vaihtosuuntaajan pulssintiheysmoduloidun pääteasteen ja prototyypin toteutus

Työssä esiteltävä laite on osa DC-AC hakkuria, jolla muodostetaan 750 V tasajännitteestä yksivaiheista (230 VRMS, 50 Hz) galvaanisesti erotettua verkkojännitettä. Tasajännite muunnetaan resonanssikonvertterilla korkeataajuiseksi vaihtojännitteeksi, joka johdetaan erotusmuuntajaan. Galvaanisen erotuksen jälkeen korkeataajuisesta vaihtojännitteestä muodostetaan suoraan verkkotaajuista vaihtojännitettä työssä esiteltävällä syklokonvertterilla. Suunnittelussa on pyritty minimoimaan häviöt mahdollisimman tarkkaan, jotta laite olisi kilpailukykyinen ei-galvaanisesti erottavien konverttereiden kanssa. Tämä on toteutettu käyttämällä mahdollisimman vähän komponentteja virran kulkureitillä sekä soveltamalla pehmeää kytkentää kaikissa tilanteissa. Lopuksi esitellään prototyyppi, jonka tarkoitus oli selvittää laitteen toiminta ja ongelmakohdat käytännössä.

CFD modeling of dispersion water feed in wastewater cleaning application

Fluid particle breakup and coalescence are important phenomena in a number of industrial flow systems. This study deals with a gas-liquid bubbly flow in one wastewater cleaning application. Three-dimensional geometric model of a dispersion water system was created in ANSYS CFD meshing software. Then, numerical study of the system was carried out by means of unsteady simulations performed in ANSYS FLUENT CFD software. Single-phase water flow case was setup to calculate the entire flow field using the RNG k-epsilon turbulence model based on the Reynolds-averaged Navier-Stokes (RANS) equations. Bubbly flow case was based on a computational fluid dynamics - population balance model (CFD-PBM) coupled approach. Bubble breakup and coalescence were considered to determine the evolution of the bubble size distribution. Obtained results are considered as steps toward optimization of the cleaning process and will be analyzed in order to make the process more efficient.

Heterogeneous mass transfer in fluidized beds by computational fluid dynamics

The main objective of this research is to estimate and characterize heterogeneous mass transfer coefficients in bench- and pilot-scale fluidized bed processes by the means of computational fluid dynamics (CFD). A further objective is to benchmark the heterogeneous mass transfer coefficients predicted by fine-grid Eulerian CFD simulations against empirical data presented in the scientific literature. First, a fine-grid two-dimensional Eulerian CFD model with a solid and gas phase has been designed. The model is applied for transient two-dimensional simulations of char combustion in small-scale bubbling and turbulent fluidized beds. The same approach is used to simulate a novel fluidized bed energy conversion process developed for the carbon capture, chemical looping combustion operated with a gaseous fuel. In order to analyze the results of the CFD simulations, two one-dimensional fluidized bed models have been formulated. The single-phase and bubble-emulsion models were applied to derive the average gas-bed and interphase mass transfer coefficients, respectively. In the analysis, the effects of various fluidized bed operation parameters, such as fluidization, velocity, particle and bubble diameter, reactor size, and chemical kinetics, on the heterogeneous mass transfer coefficients in the lower fluidized bed are evaluated extensively. The analysis shows that the fine-grid Eulerian CFD model can predict the heterogeneous mass transfer coefficients quantitatively with acceptable accuracy. Qualitatively, the CFD-based research of fluidized bed process revealed several new scientific results, such as parametrical relationships. The huge variance of seven orders of magnitude within the bed Sherwood numbers presented in the literature could be explained by the change of controlling mechanisms in the overall heterogeneous mass transfer process with the varied process conditions. The research opens new process-specific insights into the reactive fluidized bed processes, such as a strong mass transfer control over heterogeneous reaction rate, a dominance of interphase mass transfer in the fine-particle fluidized beds and a strong chemical kinetic dependence of the average gas-bed mass transfer. The obtained mass transfer coefficients can be applied in fluidized bed models used for various engineering design, reactor scale-up and process research tasks, and they consequently provide an enhanced prediction accuracy of the performance of fluidized bed processes.

Content marketing performance measurement system in the context of customer acquisition

This thesis examines how content marketing is used in B2B customer acquisition and how content marketing performance measurement system is built and utilized in this context. Literature related to performance measurement, branding and buyer behavior is examined in the theoretical part in order to identify the elements influence on content marketing performance measurement design and usage. Qualitative case study is chosen in order to gain deep understanding of the phenomenon studied. The case company is a Finnish software vendor, which operates in B2B markets and has practiced content marketing for approximately two years. The in-depth interviews were conducted with three employees from marketing department. According to findings content marketing performance measurement system’s infrastructure is based on target market’s decision making processes, company’s own customer acquisition process, marketing automation tool and analytics solutions. The main roles of content marketing performance measurement system are measuring performance, strategy management and learning and improvement. Content marketing objectives in the context of customer acquisition are enhancing brand awareness, influencing brand attitude and lead generation. Both non-financial and financial outcomes are assessed by single phase specific metrics, phase specific overall KPIs and ratings related to lead’s involvement.

Electronic and magnetic properties of LaV1-xO3 /

A series of LaVi^xOs compounds (x=0.00, 0.02, 0.04, 0.06, 0.08) were prepeired using the standard solid reaction. The samples were chareicterized by X-ray diffraction (XRD), fourprobe resistivity, smd magnetic susceptibility studies. Powder X-ray diffraction analysis indicated the formation of a single-phase sample with a orthorhombic structure which was first found in GdFeOs (space group Pnma) . The Unit Cell program was used for calculating lattice peirameters from XFID data. The XRD spectnim could be indexed on a cubic lattice with Og = 2ap ~ (7.8578 to 7.9414 A). The lattice parameter was observed to increase as the Vanadium vacancy increased. Four-probe resistivity measurements exhibited semiconductor behavior for all sajnples from room temperature down to 19K. The resistivity of samples increased with increasing Vanadium vacancy. The resistivity of samples demonstrated activated conduction with an activation energy of approximately 0.2 eV. The activation energy increased with increasing lattice parameter. Field cool magnetic susceptibility measurements were performed with field of 500 G from 300 K to 5 K. These measurements indicated the presence of an antiferromagnetic transition at about 140 K. The data was fitted above Neel temperature to Ciurie-Weiss law yielding a negative parameignetic Curie temperature. This implies that antiferromagnetic ordering is present.