(Table 1) Age determination of Cape Shpindler, Yugorski Peninsula, northwest Russia

Depositional environments, stratigraphic relations, and 35 new AMS 14C dates at Cape Shpindler, Yugorski Peninsula, help constrain the late Pleistocene glacial and environmental history of the southern Kara Sea region. Fifteen- to fifty-meter-high coastal exposures reveal a complex package of shallow marine, fluvial, glacial, and postglacial deposits, and are documented here in a 19-km-long cross-section and eight vertical sections. The shallow marine (Unit A), estuarine or prodeltaic (Unit B), and fluvio-deltaic (Unit C) deposits contain an interglacial molluscan fauna, yield radiocarbon dates greater than 40 ka, and may correspond with a regional sea-level highstand during the Eemian. These units are overlain by a diamicton (Unit D), and are pervasively deformed by folds and low- to high-angle faults into a stacked glaciotectonic accretionary complex. The diamicton (Unit D) is a subglacial till, and associated massive ground ice with deformed debris bands (Unit E) appears to be relict glacier ice. Glaciotectonic structures document both southward- and northward-directed glacier movement. Above the till and associated glaciotectonic horizons lies 0- to 11-m-thick postglacial deposits of peatland, eolian, fluvial, and primarily lacustrine origin (Unit F). The postglacial deposits yield radiocarbon ages of 12.8 to 0.8 ka. Thus, at least one regional glaciation is prominently represented in the stratigraphy, and occurred probably after the Eemian but before 12.8 ka. We infer that the bulk of the glacial record corresponds with southward advance by an early Weichselian Kara Sea Ice Sheet, in agreement with other recently documented, regional records from Yamal Peninsula and the Pechora Basin. The timing and source of northward-directed glacier ice are less well constrained. Across the broad expanse of the Eurasian Arctic, Quaternary stratigraphy is still sparsely documented. The new data from Cape Shpindler fill a spatial gap in paleoenvironmental research.

INTCAL98

The focus of this paper is the conversion of radiocarbon ages to calibrated (cal) ages for the interval 24,00-0 cal BP (Before Present, 0 cal BP = AD 1950), based upon a sample set of dendrochronologically dated tree rings, uranium-thorium dated corals, and varve-counted marine sediment. The 14C age-cal age information, produced by many laboratories, is converted to 14C profiles and calibration curves, for the atmosphere as well as the oceans. We discuss offsets in measured 14C ages and the errors therein, regional 14C age diferences, tree-coral 14C age comparisons and the time dependence of marine reservoir ages, and evaluate decadal vs. single-year 14C results. Changes in oceanic deepwater circulation, especialy for the 16,00-1,00 cal BP interval, are reflected in the Delta14C values of INTCAL98.

Age determination of sediments and biomarkers of ODP Hole 169-1034C

The radiocarbon contents of various biomarkers extracted from the varve-counted sediments of Saanich Inlet, Canada, were determined to assess their applicability for dating purposes. Calibrated ages obtained from the marine planktonic archaeal biomarker crenarchaeol compared favorably with varve-count ages. The same conclusion could be drawn for a more general archaeal biomarker (GDGT-0), although this biomarker proved to be less reliable due to its less-specific origin. The results also lend support to earlier indications that marine crenarchaeota use dissolved inorganic carbon (DIC) as their carbon source. The average reservoir age offset DR of 430 years, determined using the crenarchaeol radiocarbon ages, varied by ±110 years. This may be caused by natural variations in ocean-atmosphere mixing or upwelling at the NE Pacific coast but variability may also be due to an inconsistency in the marine calibration curve when used at sites with high reservoir ages.

Water chemistry and sediment age of lake Terrasovoje, Amery Oasis, East Antarctica

The late Quaternary palaeoenvironmental history of the southern Windmill Islands, East Antarctica, has been reconstructed using diatom assemblages from two long, well-dated sediment cores taken in two marine bays. The diatom assemblage of the lowest sediment layers suggests a warm climate with mostly open water conditions during the late Pleistocene. During the following glacial, the Windmill Islands were covered by grounded ice preventing any in situ bioproductivity. Following deglaciation, a sapropel with a well-preserved diatom assemblage was deposited from ~10?500 cal yr BP. Between ~10?500 and ~4000 cal yr BP, total organic carbon (Corg) and total diatom valve concentrations as well as the diatom species composition suggest relatively cool summer temperatures. Hydrological conditions in coastal bays were characterised by combined winter sea-ice and open water conditions. This extensive period of glacial retreat was followed by the Holocene optimum (~4000 to ~1000 cal yr BP), which occurred later in the southern Windmill Islands than in most other Antarctic coastal regions. Diatom assemblages in this period suggest ice-free conditions and meltwater-stratified waters in the marine bays during summer, which is also reflected in high proportions of freshwater diatoms in the sediments. The diatom assemblage in the upper sediments of both cores indicates Neoglacial cooling from ~1000 cal yr BP, which again led to seasonally persistent sea-ice on the bays. The Holocene optimum and cooling trends in the Windmill Islands did not occur contemporaneously with other Antarctic coastal regions, showing that the here presented record reflects partly local environmental conditions rather than global climatic trends.

Age determination of sediment cores from the Weddell Sea

We report here the results of a study aimed at providing radiometric age control on glacial events in the Weddell Sea during the late Quaternary. Sediment cores from the eastern continental shelf, where the East Antarctic ice sheet was grounded, have recovered glacial-marine sediments resting on tills and the latter deposits predate the isotope stage 2 last glacial maximum. Sediment cores from the continental slope and rise sampled a prominent ice-rafted debris layer, and radiocarbon ages indicate that this ice-rafting event took place prior to 26 000 yr B.P. Thus, the combined data indicate that significant deglaciation of the Weddell Sea continental shelf took place prior to the last glacial maximum. Our data also suggest that the ice masses that border the Weddell Sea are more extensive than they were during the previous glacial minimum.

Pollen record and age determination of sediment core Fersina 2

Pollen analysis of samples taken from the core of the water well Fersina 2 (Adige Valley, Prov. Trento, NE Italy) did not reveal any indication of an interglacial or Holocene age of the uppermost 190 m in the sediment sequence deposited in the over-deepened Adige River Valley. The sediment sequence dates entirely from late-glacial times. Four radiocarbon ages of pieces of wood indicate that about 165 m of the upper part of the profile are of Younger Dryas age. The lower part of the sequence dates from the Allerød or Bølling/Allerød and a preceding cold phase, probably the Oldest Dryas. Accordingly the deposition of the sequence took about 2500 or 3500 years and was completed long before the onset of the Neolithic. Our results are in excellent agreement with findings in other formerly glaciated alpine valleys (e.g. the Traun, Salzach and Enns valleys in the Northern Alps). The final depth of the Fersina 2 well is 190 m. It is very likely that the sediment sequence found below this level in the nearby 423 m deep Fersina 1 well was also deposited after the deglaciation of the Adige Valley at the end of the last glacial period.

Age determination of foraminifera shells

The causes for discordant radiocarbon results on multiple species of planktonic foraminifera from high-sedimentation-rate marine sediments are investigated. We have documented two causes for these anomalous results. One is the addition of secondary radiocarbon for which we have, to date, only one firm example. It involves an opal-rich sediment. The other is the incorporation of reworked material. Again, we have, to date, only one firm example. It involves a rapidly deposited ocean margin sediment. However, we have three other examples where reworking is the most likely explanation. On the basis of this study it is our conclusion that, where precise radiocarbon dating of high-deposition-rate marine sediment is required, a prerequisite is to demonstrate that concordant ages can be obtained on pairs of fragile and robust planktic shells. For sediment rich in opal, it is advisable to check for secondary calcite by comparing ages obtained on acid-leached samples with those on unleached samples.

Age determination and stable oxygen isotope record of ODP Hole 167-1017E

Oxygen isotopic (d18O) climatic stratigraphy and radiocarbon chronology, at high resolution, have been used to establish an age model for Ocean Drilling Program Hole 1017E, a continuous 25-m sequence of hemipelagic sediments from the continental slope (956 m water depth), east of Point Arguella, Southern California. The upper part of Hole 1017E from ~33 ka (7.445 mbsf) was dated using 13 calendar-corrected radiocarbon ages of mixed planktonic foraminiferal assemblages. Benthic oxygen isotopic stratigraphy records a continuous 130-k.y. sequence ranging from marine isotope Stage 6 to the present day. The benthic d18O curve, representing the last two interglacial and glacial cycles, closely resembles the well-dated, deep-sea reference sequence, providing a detailed chronologic framework. Sedimentation rates remained relatively constant throughout the sequence at ~18 cm/k.y. and were sufficiently rapid to provide considerable potential for high-resolution paleoceanographic/paleoclimatic investigations. Planktonic foraminiferal oxygen isotopic stratigraphy based on the surface-dwelling form Globigerina bulloides defines an almost complete sequence of interstadial/stadial oscillations (Dansgaard/Oeschger cycles [D/O]). Combined use of radiocarbon chronology, deep-sea oxygen isotopic datums, and visual pattern matching has enabled us to identify the sequence of D/O cycles as described for the Greenland (GRIP2) ice core. This has strengthened the stratigraphic framework for the last 60 k.y. in the sequence as a basis for further paleoenvironmental investigations.

Age determination, carbon geochemistry and palynology of section AC003

Sedimentary records from California's Northern Channel Islands and the adjacent Santa Barbara Basin (SBB) indicate intense regional biomass burning (wildfire) at the Ållerød-Younger Dryas boundary (~13.0-12.9 ka) (All age ranges in this paper are expressed in thousands of calendar years before present [ka]. Radiocarbon ages will be identified and clearly marked "14C years".). Multiproxy records in SBB Ocean Drilling Project (ODP) Site 893 indicate that these wildfires coincided with the onset of regional cooling and an abrupt vegetational shift from closed montane forest to more open habitats. Abrupt ecosystem disruption is evident on the Northern Channel Islands at the Ållerød-Younger Dryas boundary with the onset of biomass burning and resulting mass sediment wasting of the landscape. These wildfires coincide with the extinction of Mammuthus exilis [pygmy mammoth]. The earliest evidence for human presence on these islands at 13.1-12.9 ka (~11,000-10,900 14C years) is followed by an apparent 600-800 year gap in the archaeological record, which is followed by indications of a larger-scale colonization after 12.2 ka. Although a number of processes could have contributed to a post 18 ka decline in M. exilis populations (e.g., reduction of habitat due to sea-level rise and human exploitation of limited insular populations), we argue that the ultimate demise of M. exilis was more likely a result of continental scale ecosystem disruption that registered across North America at the onset of the Younger Dryas cooling episode, contemporaneous with the extinction of other megafaunal taxa. Evidence for ecosystem disruption at 13-12.9 ka on these offshore islands is consistent with the Younger Dryas boundary cosmic impact hypothesis [Firestone et al., 2007, doi:10.1073/pnas.0706977104].

Ikaite of sediment cores from the Zaire deep-sea fan

Most concentration profiles of sulfate in continental margin sediments show constant or continuously increasing gradients from the benthic boundary layer down to the deep sulfate reduction zone. However, a very marked change in this gradient has been observed several meters below the surface at many locations, which has been attributed to anoxic sulfide oxidation or to non-local transport mechanisms of pore waters. The subject of this study is to investigate whether this feature could be better explained by non-steady state conditions in the pore-water system. To this end, data are presented from two gravity cores recovered from the Zaire deep-sea fan. The sediments at this location can be subdivided into two sections. The upper layer, about 10 m thick, consists of stratified pelagic deposits representing a period of continuous sedimentation over the last 190 kyr. It is underlain by a turbidite sequence measuring several meters in thickness, which contains large crystals of authigenic calcium carbonate (ikaite: CaCO3·6H2O). Ikaite delta13C values are indicative of a methane carbon contribution to the CO2 pool. Radiocarbon ages of these minerals, as well as of the adjacent bulk sediments, provide strong evidence that the pelagic sediments have overthrust the lower section as a coherent block. Therefore, the emplacement of a relatively undisturbed sediment package is postulated. Pore-water profiles show the depth of the sulfate-methane transition zone within the turbiditic sediments. By the adaptation of a simple transport-reaction model, it is shown that the change in the geochemical environmental conditions, resulting from this slide emplacement, and the development towards a new steady state are fully sufficient to explain all features related to the pore-water profiles, particularly, [SO4]2- and dissolved inorganic carbon (DIC). The model shows that the downslope transport took place about 300 yr ago.

Nd and Sr isotope compositions, REE concentrations and Al/Ca ratios of different phases of surface sediments in the South Pacific

The radiogenic isotope composition of neodymium (Nd) and strontium (Sr) are useful tools to investigate present and past oceanic circulation or input of terrigenous material. We present Nd and Sr isotope compositions extracted from different sedimentary phases, including early diagenetic Fe-Mn coatings, "unclean" foraminiferal shells, fossil fish teeth, and detritus of marine surface sediments (core-tops) covering the entire midlatitude South Pacific. Comparison of detrital Nd isotope compositions to deep water values from the same locations suggests that "boundary exchange" has little influence on the Nd isotope composition of western South Pacific seawater. Concentrations of Rare Earth Elements (REE) and Al/Ca ratios of "unclean" planktonic foraminifera suggest that this phase is a reliable recorder of seawater Nd isotope composition. The signatures obtained from fish teeth and "nondecarbonated" leachates of bulk sediment Fe-Mn oxyhydroxide coatings also agree with "unclean" foraminifera. Direct comparison of Nd isotope compositions extracted using these methods with seawater Nd isotope compositions is complicated by the low accumulation rates yielding radiocarbon ages of up to 24 kyr, thus mixing the signal of different ocean circulation modes. This suggests that different past seawater Nd isotope compositions have been integrated in authigenic sediments from regions with low sedimentation rates. Combined detrital Nd and Sr isotope signatures indicate a dominant role of the Westerly winds transporting lithogenic material from South New Zealand and Southeastern Australia to the open South Pacific. The proportion of this material decreases toward the east, where supply from the Andes increases and contributions from Antarctica cannot be ruled out.