Organic geochemical characteristics at DSDP Holes 76-534A and 44-391C

Pyrolysis assay, bitumen analysis, and elemental analysis of kerogen were used to characterize the organic matter of selected core samples from Hole 534A (Leg 76) and Hole 391C (Leg 44) on the Blake-Bahama Plateau. The organic matter throughout the stratigraphic section appears to be principally of a terrestrial origin. The data from several isolated horizons in the Hatteras and Blake-Bahama Formations imply the presence of significant quantities of autochthonous marine organic matter. However, these horizons appear so limited that they cannot be considered potential liquid hydrocarbon source rocks. All the analyzed samples are immature and have not evolved sufficiently to enter into the main stage of hydrocarbon generation. The temporal and spatial restrictions of strata rich in marine organic matter suggest that they do not represent major expansions and contractions of anoxic bottom-water masses, but represent limited occurrences of anoxic conditions.

Paleomagnetism of DSDP Leg 80 holes

Paleomagnetic results from sediments acquired from the continental margin at DSDP Sites 548, 549, 550, and 551 are described. Where possible, the results were used to construct a polarity reversal stratigraphy for the sections sampled, thus enabling the biostratigraphic dating of the sediments to be refined. Several sections in this study were found to be suitable for magnetostratigraphic work, in particular the upper Paleocene to middle Eocene sediments from Site 549, which contained rich faunal assemblages. These sediments are underlain by a thick sequence of Cretaceous sediments that formed during the Long Cretaceous normal polarity interval. Sediments that formed during the later part of this magnetically quiet interval were also recovered at Site 550. Three short reverse polarity intervals were also recovered at this site; they lie directly over basement and are thought to represent a mixed-polarity interval of late Albian age. They may therefore provide important evidence concerning the age of the earliest sediments at this site. In addition, measurements of the magnetic susceptibility and intensity of remanent magnetism proved to be of interest. A significant decrease in the susceptibility and intensity values close to the early/middle Eocene boundary was noted at Sites 548 and 549. This decrease may be correlated with the results from Holes 400A and 401, which were drilled on DSDP Leg 48 in the northeast Bay of Biscay. The decrease may represent an abrupt reduction in the supply of terrigenous material at the end of the early Eocene, reflecting, perhaps, a change in sediment transport processes at that time

Heavy minerals from Paleogene sediments at DSDP Leg 81 Holes

Five heavy mineral associations occur in the Paleocene and Eocene sediments recovered during Leg 81 of the Deep Sea Drilling Project (DSDP) in the SW Rockall area. Association 1, consisting of augite, iddingsite, and olivine, was derived from the basaltic rocks of the northern part of the Rockall Plateau. Association 2 consists of epidote group minerals, including piedmontite, and amphiboles of actinolite, actinolitic hornblende, and magnesio-hornblende compositions, and was derived from the metamorphic basement of south Greenland. Association 3 comprises garnet, augite, apatite, and edenitic and pargasitic amphiboles and has a provenance in the southern Rockall Plateau. Associations 4 (garnet, apatite, edenitic/pargasitic amphiboles) and 5 (garnet, apatite) are intrastratal solution derivatives of Association 3, with successive removal of first pyroxene and then amphibole with increasing depth of burial. Throughout the SW Rockall Plateau area there is a significant change in the spectrum of the above assemblages in the lower part of the Eocene. This change has been noted at Sites 403, 404, 553, and 555 and is defined by the last appearance of Association 2. This level therefore marks the cessation of sediment supply from southern Greenland and is the result of the final separation of Rockall and Greenland immediately prior to magnetic Anomaly 24.

Mineralogy and geochemistry of weathered serpentinites in DSDP Leg 84 sediments

At Sites 566, 567, and 570 of Leg 84, ophiolitic serpentinite basement was covered by a sequence of serpentinitic mud that was formed by weathering of the serpentinites under sea- or pore-water conditions. Several mineralogical processes were observed: (1) The serpentinitic mud that consists mainly of chrysotile was formed from the lizardite component of the serpentinites by alteration. (2) Slightly trioctahedral smectites containing nonexpandable mica layers, trioctahedral smectites containing nonexpandable chlorite layers, and swelling chlorites were presumably formed from detrital chlorite and/or serpentine. (3) The occurrence of tremolite, chlorite, analcime, and talc can be attributed to reworking of gabbroic ophiolite rocks. (4) Dolomite, aragonite, and Mg-calcite, all authigenic, occur in the serpentinitic mud.

Geochemistry and petrography of organic matter at DSDP Hole 77-535

Organic geochemical and organic petrographic methods were used to study three Lower to middle Cretaceous sediment samples from Hole 535 in the southeastern Gulf of Mexico for organic matter contents and origin and level of maturation. All three samples contain mixed kerogen Type II/III organic matter with a maturity corresponding to about 0.4% vitrinite reflectance. The marine component increases with stratigraphic age, and microbial reworking of the organic matter is significant in each age. The lower two samples of Hauterivian to Valanginian age appear to be impregnated (or contaminated) with soluble polar organic compounds, but there is only a weak indication for the presence of more mature, nonindigenous hydrocarbons.

Survey of pollen and spores in DSDP Holes 96-618 and 619

A preliminary palynological survey of 118 samples from the Mississippi Fan (Sites 615, 616, and 620) and from 2 intraslope basins (Sites 619 and 618) shows pollen in all samples. Reworked pollen is generally abundant, forming over 50% of the sum of pollen and reworked pollen. Concentration of nonreworked pollen is usually low (on the order of tens to hundreds of pollen grains per cubic centimeter wet sediment). Conifers, primarily Pinus, Picea, and Tsuga, dominate Pleistocene marine pollen spectra; significant percentages of Quercus are present in Holocene sediments and in sediments deposited during oxygen-isotope Stage 5.

Foraminiferal, lithic, and isotopic changes across four major unconformities at DSDP Hole 80-548A

Sediment samples taken at close intervals across four major unconformities (middle Miocene/upper Miocene, lower Oligocene/upper Oligocene, lower Eocene/upper Eocene, lower Paleocene/upper Paleocene) at DSDP-IPOD Site 548, Goban Spur, reveal that coeval biostratigraphic gaps, sediment discontinuities, and seismic unconformities coincide with postulated low stands of sea level. Foraminiferal, lithic, and isotopic analyses demonstrate that environments began to shift prior to periods of marine erosion, and that sedimentation resumed in the form of turbidites derived from nearby upper-slope sources. The unconformities appear to have developed where a water-mass boundary intersected the continental slope, rhythmically crossing the drill site in concert with sea-level rise and fall.

Grain-size, carbon and calcium carbonate at DSDP Leg 77 Holes

Sand-silt-clay distribution was determined on 10-cm**3 sediment samples collected at the time the cores were split and described.

Eocene calcareous nannofossils in DSDP Holes 95-612 and 95-613

Lower Eocene calcareous nannofossil limestone cored at DSDP Site 612 on the middle slope off New Jersey represents an almost complete biostratigraphic sequence; only the lowest biozone (CP9a; NP10*) was not recovered. The thickness of the strata (198 m), the good preservation of the nannofossils, and the lack of long hiatuses justify the acceptance of this section as a lower Eocene reference for the western North Atlantic margin. The widely recognized and very similar nannofossil zonations of Martini (NP zones) and Bukry-Okada (CP zones) are emended slightly to make their lower Eocene biozones coeval; in addition, five new subzones are erected that subdivide zones CP10 and CPU (NP12 and NP13). Established biozone names are retained as they are altered little in concept, but alphanumeric code systems are changed somewhat by appending an asterisk (*) to identify zones that are emended. Zone CP10* (NP12*) is divided into two parts, the Lophodolithus nascens Subzone (CP10*a; NP12*a) and the Helicosphaera seminulum Subzone (CP10*b; NP12*b). Zone CPU* (NP13*) is divided into three parts, the Helicosphaera lophota Subzone (CP11*a; NP13*a), the Cyclicargolithuspseudogammation Subzone (CP11*b; NP13*b), and the Rhabdosphaera tenuis Subzone (CP11*c; NP13*c). At Site 612, a time-depth curve based on nannofossil datums dated in previous studies reveals a smoothly declining sediment accumulation rate, from 4.9 cm/10**3yr in CP10* (NP12*) to 2.8 cm/103 yr. in CP12* (NP14*). The ages of first-occurrence datums not previously dated are approximated by projection onto this timedepth curve and are as follows: Helicosphaera seminulum, 55.0 Ma; Helicosphaera lophota, 54.5 Ma; Cyclicargolithus pseudogammation, 53.7 Ma; Rhabdosphaera tenuis, 52.6 Ma; and Rhabdosphaera inflata, 50.2 Ma. At nearby Site 613 on the upper rise, strata of similar age, 139 m thick, contain an unconformity representing Subzone CPll*b (NP13*b) and a hiatus of approximately 1.1 m.y. duration. The sediment accumulation rate in the lower part of this section (9.7 cm/10**3yr.) is twice that observed for equivalent strata at Site 612. The hiatus and the heightened sediment accumulation rate at Site 613 probably represent the effects of episodic mass wasting on the early Eocene continental slope and rise.

Organic geochemistry of lower Cretaceous sediments at DSDP Hole 77-535

At Site 535, the four lithologic units of Cretaceous age are controlled by two types of sedimentologic facies: (1) the massive light-colored limestones or marly limestones in which the total organic carbon (TOC) content is low and the organic matter more or less oxidized and (2) laminated dark facies in which the TOC content is higher and associated with a well-preserved organic matter of Type II origin. Very little typical Type III organic matter occurs in the whole series from late Berriasian to Aptian and Cenomanian. Fluctuations from oxidizing to reducing environments of deposition are proposed to account for the variations in properties of the Type II organic matter between the different facies. Dark laminated layers are good but immature potential source rocks: petroleum potential is often higher than 2 kg HC/t of rock.

Mechanical properties and comparisons of dynamic and static Young's moduli at DSDP Holes 69-504B, 70-504B and 83-504B

From laboratory tests under simulated downhole conditions we tentatively conclude that the higher the triaxial-compressive strength, the lower the drilling rate of basalts from DSDP Hole 504B. Because strength is roughly proportional to Young's modulus of elasticity, which is related in turn to seismic-wave velocities, one may be able to estimate drilling rates from routine shipboard measurements. However, further research is needed to verify that P-wave velocity is a generally useful predictor of relative drilling rate.

Magnetic viscosity and paleomagnetism of the basement complex at DSDP Hole 77-538A

The basement at Catoche Knoll consists of Paleozoic gneiss and amphibolite intruded by several generations of early Jurassic diabase dikes. Upon exposure to a 1-oersted field for 9 days, the diabase and amphibolite acquire a viscous remanent magnetization (VRM) which ranges from 42 to 2047% of their natural remanent magnetization (NRM). A magnetic field of similar intensity is observed in the paleomagnetic facility of the Glomar Challenger, and it is therefore doubtful if accurate measurements of magnetic moments in such rocks can be made on board unless the facility is magnetically shielded. The significant VRM also indicates the futility of attempting to discern magnetic lineations from an ocean floor composed of such rocks. No strong correlation exists between the Königsberger ratio, which is usually less than 1, and the tendency to acquire a VRM. The VRM decay is typical of a Richter aftereffect, but the relaxation times vary widely among the samples studied. A stable remanence is observed after alternating field demagnetization to 200 Oe. The range of magnetic inclinations in the diabase dikes is consistent with 40Ar/39Ar dates of 190 and 160 Ma. The inclinations suggest that the Catoche Knoll block tilted more than 20° to the north after the final dike intrusion.