937 resultados para Metales pesados


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Mode of access: Internet.

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Heavy metals are present in industrial waste. These metals can generate a large environmental impact contaminating water, soil and plants. The chemical action of heavy metals has attracted environmental interest. In this context, this study aimed to test t he performance of electrochemical technologies for removing and quantifying heavy metals. First ly , the electroanalytical technique of stripping voltammetry with glassy carbon electrode (GC) was standardized in order to use this method for the quantificatio n of metals during their removal by electrocoagulation process (EC). A nalytical curves were evaluated to obtain reliability of the determin ation and quantification of Cd 2+ and Pb 2+ separately or in a mixture. Meanwhile , EC process was developed using an el ectrochemical cell in a continuous flow (EFC) for removing Pb 2+ and Cd 2+ . The se experiments were performed using Al parallel plates with 10 cm of diameter (  63.5 cm 2 ) . The optimization of conditions for removing Pb 2+ and Cd 2+ , dissolved in 2 L of solution at 151 L h - 1 , were studied by applying different values of current for 30 min. Cd 2+ and Pb 2+ concentrations were monitored during electrolysis using stripping voltammetry. The results showed that the removal of Pb 2 + was effective when the EC pro cess is used, obtaining removals of 98% in 30 min. This behavior is dependent on the applied current, which implies an increase in power consumption. From the results also verified that the stripping voltammetry technique is quite reliable deter mining Pb 2+ concentration , when compared with the measurements obtained by atomic absorption method (AA). In view of this, t he second objective of this study was to evaluate the removal of Cd 2+ and Pb 2+ (mixture solution) by EC . Removal efficiency increasing current was confirmed when 93% and 100% of Cd 2+ and Pb 2+ was removed after 30 min . The increase in the current promotes the oxidation of sacrificial electrodes, and consequently increased amount of coagulant, which influences the removal of heavy metals in solution. Adsortive voltammetry is a fast, reliable, economical and simple way to determine Cd 2+ and Pb 2+ during their removal. I t is more economical than those normally used, which require the use of toxic and expensive reagents. Our results demonstrated the potential use of electroanalytical techniques to monitor the course of environmental interventions. Thus, the application of the two techniques associated can be a reliable way to monitor environmental impacts due to the pollution of aquatic ecosystems by heavy metals.

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The success achieved by thermal methods of recovery, in heavy oils, prompted the emergence of studies on the use of electromagnetic waves as heat generating sources in oil reservoirs. Thus, this generation is achieved by three types of different processes according to the frequency range used. They are: the electromagnetic induction heating, the resistive and the dielectric, also known as radiation. This study was based on computer simulations in oil reservoirs with characteristics similar to those found in the sedimentary basins of the Brazilian Northeast. All cases studied were simulated using the software STARS, CMG (Computer Group, version 2012.10 Modeling). Some simulations took into account the inclusion of electrically sensitive particles in certain sectors of the reservoir model studied by fracturing. The purpose of this work is the use of the electromagnetic induction heating as a recovery method of heavy oil, to check the influence of these aforementioned particles on the reservoir model used. Comparative analyses were made involving electromagnetic induction heating, the operation of hydraulic fracturing and the injection of water to the different situations of the reservoir model studied. It was found that fracturing the injection well in order that the electromagnetic heating occurs in the same well where there is water injection, there was a considerable increase in the recovery factor and in the cumulative oil production in relation to the models in which hydraulic fracturing occurred in the production well and water injection in the injection well. This is due to the generation of steam in situ in the reservoir.

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En los últimos años se esta introduciendo al ambiente marino grandes cantidades de contaminantes como resultado del desarrollo industrial y manufacturero, así como del aumento demográfico en el Perú.

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En el presente documento se estudia el desempeño que ha tenido Perú durante la última fase expansiva del ciclo de precios de commodities, específicamente entre los años 2001 y 2015. Para esto, se desarrolla un modelo de equilibrio general estocástico y dinámico, basado en Medina y Soto (2007) y Fornero y Kichner (2014), que incorpora un sector productor de commodities con inversión del tipo time to build. El modelo es estimado de forma lineal y a partir de este se muestra la importancia que tienen los choques de precios commodities sobre el resto de la actividad económica. Asimismo, se analizan distintos tipos de políticas fiscales y monetarias, ante este tipo de choques. También se obtienen políticas monetarias óptimas a partir de la función de pérdida de la autoridad monetaria. Los resultados de la investigación apuntan a que, cuando hay un incremento en el precio de los commodities, se genera una dinámica procíclica en el valor de la producción de todos los sectores, en la inversión, el consumo y el gasto del Gobierno. Además, se encuentra que la incorporación del mecanismo de time to build permite explicar mejor la dinámica observada. Dicho mecanismo ayuda a comprender que el choque en cuestión demora en propagarse, ya que los proyectos mineros toman tiempo en construirse. Este aporte metodológico es de particular relevancia en los ejercicios de modelamiento y predicción que se quieran realizar sobre la economía peruana.

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Bogotá (Colombia) : Universidad de La Salle. Facultad de Ingeniería. Programa de Ingeniería Ambiental y Sanitaria