De la fidelidad a la revolución: el proceso de la independencia de la antigua provincia de Guayaquil, 1809-1820 (Estudios)

Este articulo analiza las transformaciones políticas e ideológicas que tuvieron lugar en Guayaquil entre 1809 y 1820, período en el que la ciudad transitó de un marcado fidelismo hacia la autonomía e independencia. Se estudian las disputas entre los grupos de poder local y las reacciones del cabildo a las sucesivas coyunturas peninsulares y regionales. El ensayo muestra la relación entre las tensiones sociales internas y la dinámica, hasta ahora desconocida, de las diferentes elecciones ocurridas entre 1809 y 1813, as¡ como el impacto local de la vigencia y posterior supresión de la constitución gatidatana. El estudio concluye con una reconsideración de la independencia guayaquileña de 1820.

Habiendo roto el freno de la obediencia: participación indígena en la insurgencia de Quito, 1809-1812 (Estudios)

El artículo analiza un ámbito de la participación de los indígenas en la coyuntura de quiebre del régimen monárquico producida en Quito ante las noticias de la invasión napoleónica y la abdicación del trono español en favor de José Bonaparte. El trabajo investiga si los indígenas de Quito fueron fundamentalmente indiferentes ante la proclamación de autonomía de la primera junta quiteña en 1809 o si tuvieron alguna propuesta específica durante el período de mayor convulsión y movilización entre 1810 y 1812. De otro lado, explora las actitudes de la élite y la plebe en el período. El trabajo pone atención en el ambiente de temor que la movilización popular suscitó luego de los abusos y la cruenta represión cometidas por las tropas limeñas acantonadas en Quito, en 1810.

Los orígenes de la Revolución de Quito en 1809 (Debates)

La Revolución de Quito de 1809 no fue un movimiento por la independencia. Lejos de ello, se trató de una reacción local ante la crisis de la monarquía española. A lo largo del siglo XVIII, el Reino de Quito experimentó un declive económico, político y jurídico. Supeditado a las capitales de dos virreinatos –Lima y Santa Fe–, Quito buscaba el estatus de una capitanía general independiente con el fin de liberarse del dominio de Nueva Granada y Perú. Convencido de que España estaba perdida y de que los españoles en Quito traicionarían al reino y aceptarían el gobierno francés, un grupo de quiteños tomó el control del gobierno y puso en práctica un programa que garantizara la autonomía y que promoviera sus intereses económicos. No obstante, otras provincias del reino, cuyos intereses se vieron amenazados, se opusieron a Quito y unieron fuerzas con los virreyes de Perú y Nueva Granada para extinguir el levantamiento que duró unos tres meses.

Lewis Fry Richardson's forecast factory - for real

The idea that supercomputers are an important part of making forecasts of the weather and climate is well known amongst the general population. However, the details of their use are somewhat mysterious. A concept used to illustrate many undergraduate numerical weather prediction courses is the idea of a giant 'forecast factory,' conceived by Lewis Fry Richardson in 1922. In this article, a way of using the same idea to communicate key ideas in numerical weather prediction to the general public is outlined and tested amongst children from local schools.

Epoxide ring opening in a zinc(II) complex in water without any Lewis acid catalyst: formation of only one diastereomer out of 2

The epoxide ring in 5,6-dihydro-5,6-epoxy-1,10-phenanthroline (L) opens up in its reaction with 4-methylaniline and 4-methoxyaniline in water in equimolar proportion at room temperature without any Lewis acid catalyst to give a monohydrate of 6-(4-methyl-phenylamino)-5,6-dihydro-1,10-phenanthrolin-5-ol (L′·H2O) and 6-(4-methoxyphenyl-amino)-5,6-dihydro-1,10-phenanthrolin-5-ol (L″) respectively. Reaction time decreases from 72 to 14 h in boiling water. But the yields become less. Reaction of L with Zn(ClO4)2·6H2O in methanol in 3:1 molar ratio at room temperature affords white [ZnL3](ClO4)2·H2O. The X-ray crystal structure of the acetonitrile solvate [ZnL3](ClO4)2·MeCN has been determined which shows that the metal has a distorted octahedral N6 coordination sphere. [ZnL3](ClO4)2·2H2O reacts with 4-methylaniline and 4-methoxyaniline in boiling water in 1:3 molar proportion in the absence of any Lewis acid catalyst to produce [ZnL′3](ClO4)2·4H2O and [ZnL″3](ClO4)2·H2O, respectively in 1–4 h time in somewhat low yield. In the 1H NMR spectra of [ZnL′3](ClO4)2·4H2O and [ZnL″3](ClO4)2·H2O, only one sharp methyl signal is observed implicating that only one diastereomer out of the 23 possibilities is formed. The same diastereomers are obtained when L′·H2O and L″ are reacted directly with Zn(ClO4)2·6H2O in tetrahydrofuran at room temperature in very good yields. Reactions of L′·H2O and L″ with Ru(phen)2Cl2·2H2O (phen = 1,10-phenanthroline) in equimolar proportion in methanol–water mixture under refluxing condition lead to the isolation of two diastereomers of [Ru(phen)2L′](ClO4)2·2H2O and [Ru(phen)2L″](ClO4)2·2H2O.

John Lewis Partnership lessons in logical incrementalism and organic growth: a case study and interview with the Chairman, Mr Charlie Mayfield

Purpose – The purpose of this paper is to demonstrate how strategy is developed and implemented in an organisation with an unusual ownership model. Partnerships are not a prevalent form of ownership but as this case demonstrates they can be extremely effective. Furthermore this case demonstrates how logical incrementalism can be used to implement major strategic decisions. Design/methodology/approach – The paper draws on company documentary evidence and a semi-structured interview with Mr Charlie Mayfield, Chairman of John Lewis Partnership. A chairman has a helicopter view of business whose perspectives are rarely captured by strategy researchers. This case study offers an insight into strategic thinking of a chairman and chief executive of a successful company. Research limitations/implications – The case study and interview offer a unique insight into the rationale behind strategic decisions within a successful partnership that has grown organically in a highly competitive retail market without high gearing. Originality/value – This case study sheds light on strategic moves within partnership. Furthermore, very few case studies offer insight into the thinking of a chief executive who has successfully managed a business in a turbulent environment.

New insights on the Lewis acidity of diorganolead(IV) compounds: Diphenyllead(IV) complexes with N,O,S-chelating ligands

The reactions of PbPh2(OAC)(2) with alkylglyoxylate thiosemicarbazones (HRGTSC, R = Et, Bu) afforded complexes of the type [PbPh2(GTSC)] center dot H2O, [PbPh2(RGTSC)(2)] and [PbPh2Cl(BUGTSC)]. The structures of HRGTSC (R = Me, Et, Bu), [PbPh2(OAc)(RGTSC)](R = Me, Et, Bu), [PbPh2Cl(BuGTSC)] and [PbPh2(GTSC)] center dot H2O have been studied by X-ray diffraction. [PbPh2(OAc)(RGTSC)] and [PbPh2(GTSC)] center dot H2O have [PbC2NO3S] kernels and the coordination sphere of the metal is pentagonal bipyramidal. [PbPh2Cl(BuGTSC)] has a [PbC2NOSCI] kernel and the coordination geometry around lead is pentagonal bipyramidal with one vacant site. Analysis of the bond distances in [PbPh2(GTSC)] center dot H2O suggests a significant affinity between diphenyllead(IV) and carboxylate donor groups, supporting a borderline acidic character for this organometallic cation. H-1 and C-13 NMR spectra in DMSO-d(6) suggest the partial dissociation of the acetate in [PbPh2(OAc)(RGTSC)] solutions and indicate some differences in the coordination mode of the two RGTSC(-) ligands in [PbPh2(RGTSC)(2)] complexes. (C) 2007 Elsevier Ltd. All rights reserved.