Asymmetric hydrogenation of alkenes with cationic iridium(I) complexes of 2-phosphino-1-aminoferrocene ligands

Iridium complexes with bidentate P,N ligands represent a class of catalysts that significantly expand the application range of asymmetric hydrogenation. New substrate classes, for which there have previously been no suitable catalysts, can now be efficiently hydrogenated in high conversion and enantioselectivity. These substrates are often of synthetic importance, thus iridium catalysis represents a significant advance in the field of asymmetric catalysis. Planar chiral ferrocenyl aminophosphine ligands in which both heteroatoms were directly bound to the cyclopentadienyl ring were prepared by BF3-activated lithiationsubstitution in the presence of a chiral diamine in 49-59% yield and 75-85% enantiomeric excess. Some of these ligands were recrystallized to enantiomeric purity via ammonium fluoroborate salt formation of the phosphine sulfide. A crystal structure of one of these compounds was obtained and features an intramolecular hydrogen bond between the nitrogen, hydrogen, and sulfur atoms. Neutralization, followed by desulfurization, provided the free ligands in enantiomeric purity. Iridium complexes with these ligands were formed via reaction with [Ir(COD)Clh followed by anion exchange with NaBArF. These complexes were successfully applied in homogeneous hydrogenation of several prochiral substrates, providing products in up to 92% enantiomeric excess. Variation of the dimethyl amino group to a pyrrolidine group had a negative effect on the selectivity of hydrogenation. Variation of the substituents on phosphorus to bulkier ortho-tolyl groups had a positive effect, while variation to the more electron rich dicyclohexyl phosphine had a negative effect on selectivity.

The History of the Consulate & The Empire of France Under Napoleon

The book is stamped in the front and back with the "Upper Canada College" crest. There is also a plate within the book indicating that it was presented to H.K. Woodruff by the senate as an acknowledgement of merit and as a reward for general proficiency in Upper Canada College in June, 1878. On the top of this plate it says: 1st Form Prize, Upper Modern Form. The full text is available in the Brock University Special Collections and Archives or view the full text at the following link: http://www.archive.org/details/consulateempire1and2thie

Richard III as duke of Gloucester and King of England

UANL

A history of France

UANL

The Broken "I" : fragmentation of self and otherness in modern urban narratives

Ce mémoire mélange théorie et fiction pour explorer la technique narrative du “nous” performatif. Le premier chapitre démontre le role du discours dans le processus de formation d’identité, pour éventuellement démontrer que la nature performative du langage est responsable de la creation des constructions sociales du soi et de l’autre. En étudiant les failles de ce système, cet essai tentera de créer une entité narrative libre de ces contraintes. Un second chapitre théorique, après des exemples de fiction, se penchera sur l’entité narrative du flâneur, qui à travers sa relation intime avec la cité, souligne une dichotomie présente dans la relation entre le soi et l’autre. Le flâneur emergera comme un site de traduction dans lequel le “nous” performatif peut prendre action. Toutefois, les limites du flâneur en tant qu’outil narratif l’empêchera d’être la representation ultime de cette dichotomie. Après d’autres exemples de fiction, un troisième chapitre combinera ce qui aura été apprit dans les chapitres précédents pour démontrer que le “nous” performatif et sa dissolution du “je” et du “tu” mène à une narration qui est responsable, consciente d’elle-même et représentative de la réalité urbaine moderne et ses effets sur la création de l’identité.

María Antonieta, la última reina: sinopsis fílmica y reseña literaria [Ressenya del llibre María Antonieta: la última reina, d'Antonia Fraser; Ressenya de la pel·lícula María Antonieta, de Sofia Coppola]

Sinopsi fílmica i ressenya literària d’aquestes dues obres sobre la figura de la última reina de França, amb 8 suggeriments didàctics que tenen com a fil conductor ambdues obres

Juan Valdez in the coffe market of France

El objetivo de este trabajo es presentar un marco organizacional en profundidad de las operaciones de Juan Valdez y sus posibilidades de incursionar en el mercado Francés. El Análisis se presenta en base a una investigación de mercados que tiene como referencia las tendencias de consumo, más exactamente hacía bebidas con alto contenido de cafeína, (Bebidas energizantes, deportivas, café etc.). Igualmente se analizan los socios estratégicos con más fuerza de realizar alianzas con la empresa colombiana, sus posibilidades financieras, así como su experiencia y conocimiento de su mercado local, y la similitud de procesos o cultura organizacional. La investigación de la propuesta nos lleva a generar una aplicación y conocimiento más a fondo de aspectos teóricos relacionados con el estudio del consumidor, la diversidad cultural y su influencia en el momento de realizar estrategias de mercadeo, el concepto de red y complejidad, así como aspectos teóricos relacionados con la organización y desafíos de una empresa al optar el camino de la internacionalización.

Rediscovering the King of Woodpeckers: Exploring the Implications

The Ivory-billed Woodpecker has long held a special place in the psyche of North American conservation, eliciting unusually colorful prose, even from scientists, as an icon of the wild. The reverence in which it was held did little to slow the habitat loss that led to its apparent extinction 60 years ago. A consequence of the emotion and attention associated with the amazing rediscovery of this species is that conservation biologists will be under considerable pressure to make good on this “second chance.” This poses a challenge to conservation paradigms that has important political consequences. First, the decline of the species is due to habitat loss, recovery from which has been much more seldom achieved than recovery from declines due to impacts on vital rates. This challenge is exacerbated by the enormous area requirements of the species. Second, the species at best exists as a critically small population. It will be difficult to make the case that a viable population can be established without undermining the small population paradigm that underlies conservation strategies for many other species. This has already resulted in some political backlash. Conservation of this species is best based on the one point of clear scientific consensus, that habitat is limiting, but this may result in additional political backlash because of conflicts with other land uses.