Application of impedance spectroscopy to evaluate the effect of different setting accelerators on the developed microstructures of calcium phosphate cements

The main goal of the present study was to evaluate the effect of different setting accelerator agents on the developed microstructures of calcium phosphate cements (CPCs) by employing the impedance spectroscopy (IS) technique. Six compositions of CPCs were prepared from mixtures of commercial dicalcium phosphate anhydrous (DCPA) and synthesized tetracalcium phosphate (TTCP) as the solid phases. Two TTCP/DCPA molar ratios (1/1 and 1/2) and three liquid phases (aqueous solutions of Na(2)HPO(4), tartaric acid (TA) and oxalic acid (OA), 5% volume fraction) were employed. Initial (I) and final (F) setting times of the cement pastes were determined with Gillmore needles (ASTM standard C266-99). The hardened samples were characterized by X-ray powder diffraction (XRD), Fourier transformed infrared (FTIR) spectroscopy, scanning electron microscopy (SEM), and apparent density measurements. The IS technique was employed as a non-destructive tool to obtain information related to porosity, tortuosity and homogeneity of the cement microstructures. The formulation prepared from a TTCP/DCPA equimolar mixture and OA as the liquid phase presented the shortest I and F (12 and 20 min, respectively) in comparison to the other studied systems. XRD analyses revealed the formation of low-crystallinity hydroxyapatite (HA) (as the main phase) as well as the presence of little amounts of unreacted DCPA and TTCP after 24 h hardening in 100% relative humidity. This was related to the proposed mechanisms of dissolution of the reactants. The bands observed by FTIR allowed identifying the presence of calcium tartrate and calcium oxalate in the samples prepared from TA and OA, in addition to the characteristic bands of HA. High degree of entanglement of the formed crystals was observed by SEM in samples containing OA. SEM images were also correlated to the apparent densities of the hardened cements. Changes in porosity, tortuosity and microstructural homogeneity were determined in all samples, from IS results, when the TTCP/DCPA ratio was changed from 1/1 to 1/2. The cement formulated from an equimolar mixture of TTCP/DCPA and OA as the liquid phase presented setting times, degree of conversion to low-crystallinity HA and microstructural features suitable to be used as potential bone cement in clinical applications. The IS technique was shown to be a very sensitive and non-destructive tool to relate the paste composition to the developed microstructures. This approach could be very useful to develop calcium phosphate bone cements for specific clinical demands.

Multipartite quantum correlations in open quantum systems

In this paper, we present a measure of quantum correlation for a multipartite system, defined as the sum of the correlations for all possible partitions. Our measure can be defined for quantum discord (QD), geometric quantum discord or even for entanglement of formation (EOF). For tripartite pure states, we show that the multipartite measures for the QD and the EOF are equivalent, which allows direct comparison of the distribution and the robustness of these correlations in open quantum systems. We study dissipative dynamics for two distinct families of entanglement: a W state and a GHZ state. We show that, for the W state, the QD is more robust than the entanglement, while for the GHZ state, this is not true. It turns out that the initial genuine multipartite entanglement present in the GHZ state makes the EOF more robust than the QD. © IOP Publishing and Deutsche Physikalische Gesellschaft.

Sending classical information through relativistic quantum channels

We investigate how special relativity influences the transmission of classical information through quantum channels by evaluating the Holevo bound when the sender and the receiver are in (relativistic) relative motion. By using the spin degrees of freedom of spin-1/2 fermions to encode the classical information, we show that, for some configurations, the accessible information in the receiver can be increased when the spin detector moves fast enough. This is possible by allowing the momentum wave packet of one of the particles to be sufficiently wide while the momentum wave packets of other particles are kept relatively narrow. In this way, one can take advantage of the fact that boosts entangle the spin and momentum degrees of freedom of spin-1/2 fermions to increase the accessible information in the former. We close the paper with a discussion of how this relativistic quantum channel cannot in general be described by completely positive quantum maps. © 2013 American Physical Society.

Variação lexical e sintática na produção escrita formal do português em Moçambique

Pós-graduação em Estudos Linguísticos - IBILCE

Ensaios sobre computação e informação quânticas: fundamentação e simulações sobre o efeito da entropia

Pós-graduação em Ciência da Computação - IBILCE

Discurso crítico e posicionamento lírico em Orides Fontela e Natália Correia

Pós-graduação em Letras - IBILCE

Espaço de Hilbert e quantificação de emaranhamento via entropia não extensiva

Pós-graduação em Matemática - IBILCE

Dinâmica de sistemas bipartites de spins no espaço de fase quântico discreto

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Non-Markovianity through Accessible Information

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Extracting Information from Qubit-Environment Correlations

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Non-Markovianity through flow of information between a system and an environment

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Entropy effect in quantum computing and information: an open-source environment simulation

The technologies are rapidly developing, but some of them present in the computers, as for instance their processing capacity, are reaching their physical limits. It is up to quantum computation offer solutions to these limitations and issues that may arise. In the field of information security, encryption is of paramount importance, being then the development of quantum methods instead of the classics, given the computational power offered by quantum computing. In the quantum world, the physical states are interrelated, thus occurring phenomenon called entanglement. This study presents both a theoretical essay on the merits of quantum mechanics, computing, information, cryptography and quantum entropy, and some simulations, implementing in C language the effects of entropy of entanglement of photons in a data transmission, using Von Neumann entropy and Tsallis entropy.

Busca quântica de dados XML usando algoritmo de Grover

This paper presents a quantum search algorithm implementation with small modifications. The algorithm idea is to be hybrid, capable to run on classical systems and quantum systems. We present the concepts of quantum search and introduced a pseudo-framework able to generate code for classical computers (C++) and quantum computers (QCL). The algorithms were submitted to simulations, which resulted in a comparative study of the operation of Grover’s algorithm on both systems, carrying out searches in a mass of data in XML format files. As a result, we see very similar numbers between classical and quantum systems, this creates an expectation that the search in real quantum computers is much more efficient.

Da receita à paixão: a mise en abyme em Clarice Lispector

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Análise do efeito de entropia em computação quântica: simulações em ambiente paralelo

Pós-graduação em Ciência da Computação - IBILCE