949 resultados para Surfaces, Coatings and Films
Resumo:
David Katz a fait l’observation que le mouvement entre la peau et l’objet est aussi important pour le sens du toucher que la lumière l’est pour la vision. Un stimulus tactile déplacé sur la peau active toutes les afférences cutanées. Les signaux résultants sont très complexes, covariant avec différents facteurs dont la vitesse, mais aussi la texture, la forme et la force. Cette thèse explore la capacité des humains à estimer la vitesse et la rugosité de surfaces en mouvements. Les bases neuronales de la vitesse tactile sont aussi étudiées en effectuant des enregistrements unitaires dans le cortex somatosensoriel primaire (S1) du singe éveillé. Dans la première expérience, nous avons montré que les sujets peuvent estimer la vitesse tactile (gamme de vitesses, 30 à 105 mm/s) de surfaces déplacées sous le doigt, et ceci sans indice de durée. Mais la structure des surfaces était essentielle (difficulté à estimer la vitesse d’une surface lisse). Les caractéristiques physiques des surfaces avaient une influence sur l’intensité subjective de la vitesse. La surface plus rugueuse (8 mm d’espacement entre les points en relief) semblait se déplacer 15% plus lentement que les surfaces moins rugueuses (de 2 et 3 mm d’espacement), pour les surfaces périodiques et non périodiques (rangées de points vs disposition aléatoire). L’effet de la texture sur la vitesse peut être réduit en un continuum monotonique quand les estimés sont normalisés avec l’espacement et présentés en fonction de la fréquence temporelle (vitesse/espacement). L'absence de changement des estimés de vitesse entre les surfaces périodiques et non périodiques suggère que les estimés de rugosité devraient aussi être indépendants de la disposition des points. Dans la deuxième expérience, et tel que prévu, une équivalence perceptuelle entre les deux séries de surfaces est obtenue quand les estimés de la rugosité sont exprimés en fonction de l'espacement moyen entre les points en relief, dans le sens de l'exploration. La troisième expérience consistait à rechercher des neurones du S1 qui pourraient expliquer l’intensité subjective de la vitesse tactile. L’hypothèse est que les neurones impliqués devraient être sensibles à la vitesse tactile (40 à 105 mm/s) et à l’espacement des points (2 à 8 mm) mais être indépendants de leur disposition (périodique vs non périodique). De plus, il est attendu que la fonction neurométrique (fréquence de décharge/espacement en fonction de la fréquence temporelle) montre une augmentation monotonique. Une grande proportion des cellules était sensible à la vitesse (76/119), et 82% d’entres elles étaient aussi sensibles à la texture. La sensibilité à la vitesse a été observée dans les trois aires du S1 (3b, 1 et 2). La grande majorité de cellules sensibles à la vitesse, 94%, avait une relation monotonique entre leur décharge et la fréquence temporelle, tel qu’attendu, et ce surtout dans les aires 1 et 2. Ces neurones pourraient donc expliquer la capacité des sujets à estimer la vitesse tactile de surfaces texturées.
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The finite-size-dependent enhancement of pairing in mesoscopic Fermi systems is studied under the assumption that the BCS approach is valid and that the two-body force is size independent. Different systems are investigated such as superconducting metallic grains and films as well as atomic nuclei. It is shown that the finite size enhancement of pairing in these systems is in part due to the presence of a surface which accounts quite well for the data of nuclei and explains a good fraction of the enhancement in Al grains.
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Metal phthalocyanines have some unique optical properties which are exploited for dyeing fibers and films used in applicationslike dye lasing and optical information storage. Aggregation of dye molecules modifies their absorption and emission spectra with concomitant degradation in their energy transfer characteristics. MPcs as such have poor processability and are seldom used in solid matrices. The finest energy transfer characteristics are shown by the monomers of metal phthalocyanines. In the third chapter of this thesis the studies on two series of metal phthalocyanines are repoted
Resumo:
OBJETIVO: Cuantificar Bacterias gram positivas, Bacterias gram negativas y Hongos mediante monitoreo microbiológico de aire, superficies y manos del personal asistencial en cinco entidades de salud del departamento del Meta en el año 2007. MÉTODOS: Estudio ejecutado en cinco entidades, donde se realizó el diagnostico microbiológico del entorno hospitalario, tomando muestras en cada área asistencial de: superficies horizontales antes y después de aplicar el protocolo de limpieza y desinfección de cada institución, manos de personal asistencial antes y después del lavado rutinario de manos y del aire de áreas críticas y no críticas. RESULTADOS: La IPS 3 presentó el Aire de Zona crítica con mayor contaminación bacteriana y la IPS 4 mayor contaminación fúngica. Hospitalización, Urgencias y Apoyo diagnostico evidenciaron las mayores concentraciones microbianas. Se encontraron diferencias estadísticamente significativas entre la carga microbiana antes respecto a después del lavado de manos (p<0,05) y antes y después de la aplicación del protocolo de limpieza y desinfección de superficies. CONCLUSIONES: Con el presente estudio fue posible demostrar que la capacitación, supervisión y monitorización de los procesos de lavado de manos y limpieza y desinfección de superficies pueden llegar a garantizar la reducción de la biomasa bacteriana y fúngica presente en las entidades de la salud.
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Whitish and whitish-light brown milky-like textural pedofeatures and impregnations were found in the voids and the matrix of buried paleosols older than 2.7 million years in a site in Sardinia, Italy. The pedofeatures were described and analysed using micromorphology, X-ray diffraction and microprobe techniques, and their spatial distribution correlated with field evidence. The suite of analyses showed that the main components of the pedofeatures were more or less ordered silica phases. As well as forming a matrix cement, these pedofeatures also occurred as coatings and infillings in pores. Significant amounts of alumina and, less, Mg, Ca and Fe were also present in the pedofeatures, possibly in the form of silicate coatings and inclusions/impurities, or alumino-silicates of the adjacent soil matrix. A number of hypotheses are drawn on the possible mechanisms of formation of these silica-rich pedofeatures, including the possibility of prolonged weathering of volcanic materials and the resulting formation of colloids and more or less ordered silica phases, with successive dehydration and progressive ordering of phases during the at least 2.5 million years. (C) 2003 Elsevier B.V. All rights reserved.
Resumo:
Whitish and whitish-light brown milky-like textural pedofeatures and impregnations were found in the voids and the matrix of buried paleosols older than 2.7 million years in a site in Sardinia, Italy. The pedofeatures were described and analysed using micromorphology, X-ray diffraction and microprobe techniques, and their spatial distribution correlated with field evidence. The suite of analyses showed that the main components of the pedofeatures were more or less ordered silica phases. As well as forming a matrix cement, these pedofeatures also occurred as coatings and infillings in pores. Significant amounts of alumina and, less, Mg, Ca and Fe were also present in the pedofeatures, possibly in the form of silicate coatings and inclusions/impurities, or alumino-silicates of the adjacent soil matrix. A number of hypotheses are drawn on the possible mechanisms of formation of these silica-rich pedofeatures, including the possibility of prolonged weathering of volcanic materials and the resulting formation of colloids and more or less ordered silica phases, with successive dehydration and progressive ordering of phases during the at least 2.5 million years. (C) 2003 Elsevier B.V. All rights reserved.
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Model catalysts of Pd nanoparticles and films on TiO2 (I 10) were fabricated by metal vapour deposition (MVD). Molecular beam measurements show that the particles are active for CO adsorption, with a global sticking probability of 0.25, but that they are deactivated by annealing above 600 K, an effect indicative of SMSI. The Pd nanoparticles are single crystals oriented with their (I 11) plane parallel to the surface plane of the titania. Analysis of the surface by atomic resolution STM shows that new structures have formed at the surface of the Pd nanoparticles and films after annealing above 800 K. There are only two structures, a zigzag arrangement and a much more complex "pinwheel" structure. The former has a unit cell containing 7 atoms, and the latter is a bigger unit cell containing 25 atoms. These new structures are due to an overlayer of titania that has appeared on the surface of the Pd nanoparticles after annealing, and it is proposed that the surface layer that causes the SMSI effect is a mixed alloy of Pd and Ti, with only two discrete ratios of atoms: Pd/Ti of 1: 1 (pinwheel) and 1:2 (zigzag). We propose that it is these structures that cause the SMSI effect. (c) 2005 Elsevier Inc. All rights reserved.
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Cycloaddition reactions have been employed in polymer synthesis since the mid-nineteen sixties. This critical review will highlight recent notable advances in this field. For example, [2 + 2] cycloaddition reactions have been utilized in numerous polymerizations to enable the construction of strained polymer systems such as poly(2-azetidinone)s that can, in turn, afford polyfunctional beta-amino acid derived polymers. Polymers have also been synthesized successfully via (3 + 2) cycloaddition methods utilizing both thermal and high-pressure conditions. 'Click chemistry'-a process involving the reaction of azides with olefins, has also been adopted to generate linear and hyperbranched polymer architectures in a very efficient manner. [4 + 2] Cycloadditions have also been utilized under thermal and high-pressure conditions to produce rigid polymers such as polyimides and polyphenylenes. These cycloaddition polymerization methods afford polymers with potential for use in high performance polymers applications such as high temperature resistant coatings and polymeric organic light emitting diodes.
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A Kalman filter algorithm has been applied to interpret the optical reflectance excursions during vacuum deposition of infrared coatings and multilayer thin-film filters. The application has been described in detail elsewhere and this paper now reports on-line experience for estimating deposition rate and thickness. The estimation proved sufficiently reliable to firstly 'navigate' regular manufacture (as controlled by a skilled operator) and to subsequently reproduce the skill without interpretation or intervention whilst maintaining exemplary product quality. Optical control by means of this Kalman filter application is therefore considered suitable as a basis for the automated manufacture of infrared coatings and multilayer thin-film filters.
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Techniques for modelling urban microclimates and urban block surfaces temperatures are desired by urban planners and architects for strategic urban designs at the early design stages. This paper introduces a simplified mathematical model for urban simulations (UMsim) including urban surfaces temperatures and microclimates. The nodal network model has been developed by integrating coupled thermal and airflow model. Direct solar radiation, diffuse radiation, reflected radiation, long-wave radiation, heat convection in air and heat transfer in the exterior walls and ground within the complex have been taken into account. The relevant equations have been solved using the finite difference method under the Matlab platform. Comparisons have been conducted between the data produced from the simulation and that from an urban experimental study carried out in a real architectural complex on the campus of Chongqing University, China in July 2005 and January 2006. The results show a satisfactory agreement between the two sets of data. The UMsim can be used to simulate the microclimates, in particular the surface temperatures of urban blocks, therefore it can be used to assess the impact of urban surfaces properties on urban microclimates. The UMsim will be able to produce robust data and images of urban environments for sustainable urban design.
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We present simulations of London's meteorology using the Met Office Unified Model with a new, sophisticated surface energy-balance scheme to represent the urban surfaces, called MORUSES. Simulations are performed with the urban surfaces represented and with the urban surfaces replaced with grass in order to calculate the urban increment on the local meteorology. The local urban effects were moderated to some extent by the passage of an onshore flow that propagated up the Thames estuary and across the city, cooling London slightly in the afternoon. Validations of screen-level temperature show encouraging agreement to within 1–2 K, when the urban increment is up to 5 K. The model results are then used to examine factors shaping the spatial and temporal structure of London's atmospheric boundary layer. The simulations reconcile the differences in the temporal evolution of the urban heat island (UHI) shown in various studies and demonstrate that the variation of UHI with time depends strongly on the urban fetch. The UHI at a location downwind of the city centre shows a decrease in UHI during the night, while the UHI at the city centre stays constant. Finally, the UHI at a location upwind of the city centre increases continuously. The magnitude of the UHI by the time of the evening transition increases with urban fetch. The urban increments are largest at night, when the boundary layer is shallow. The boundary layer experiences continued warming after sunset, as the heat from the urban fabric is released, and a weakly convective boundary layer develops across the city. The urban land-use fraction is the dominant control on the spatial structure in the sensible heat flux and the resulting urban increment, although even the weak advection present in this case study is sufficient to advect the peak temperature increments downwind of the most built-up areas. Copyright © 2011 Royal Meteorological Society and British Crown Copyright, the Met Office
Resumo:
An ozonesonde profile over the Network for Detection of Stratospheric Change (NDSC) site at Lauder (45.0° S, 169.7° E), New Zealand, for 24 December 1998 showed atypically low ozone centered around 24 km altitude (600 K potential temperature). The origin of the anomaly is explained using reverse domain filling (RDF) calculations combined with a PV/O3 fitting technique applied to ozone measurements from the Polar Ozone and Aerosol Measurement (POAM) III instrument. The RDF calculations for two isentropic surfaces, 550 and 600 K, show that ozone-poor air from the Antarctic polar vortex reached New Zealand on 24–26 December 1998. The vortex air on the 550 K isentrope originated in the ozone hole region, unlike the air on 600 K where low ozone values were caused by dynamical effects. High-resolution ozone maps were generated, and their examination shows that a vortex remnant situated above New Zealand was the cause of the altered ozone profile on 24 December. The maps also illustrate mixing of the vortex filaments into southern midlatitudes, whereby the overall mid-latitude ozone levels were decreased.
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This chapter analyses how children, and especially boys, are constructed as ‘savage’ in relation to warlike toys and representations that narrate particular versions of conflict, such as war and terrorism. The chapter uses Action Man toys as a case study that is contextualized against a wider background of other toys, television programmes and films. Action Man is most familiar as a twelve-inch costumed toy figure, but the brand also extends into related media representations such as television programmes, comics and advertising. The chapter focuses increasingly on the specifics of Action Man representations produced from the 1960s to the 1990s, prefacing this detailed discussion with some examples of transmedia texts aimed at children in film and television. This chapter suggests that making the toy a central object of analysis allows for insights into representations of the gendered body that are particularly useful for work on the child-savage analogy. Some of the cultural meanings of war toys, warlike play and representations of war that can be analysed from this perspective include their role in the construction of masculine identity, their representation of particular wars and warlikeness in general, and their relationship to consumer society. This complex of meanings exhibits many of the contradictions that inhabit the construction of ‘the child’ in general, such as that the often extreme masculinity of war toys and games is countered by an aesthetic of spatial disposition, collecting and sometimes nurturing that is more conventionally feminine. Such inter-dependent but apparently opposed meanings can also be seen in the construction of the child as untainted by adult corruption yet also savage, or as in need of adult guidance yet also offering a model of innocence and purity that adults are expected to admire.
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The objective of this study was to evaluate and compare the print performance of some of the new most promising, cost effective absorbent pigments specialised for inkjet coatings on the market in a continuous drive to find an alternative to silica. The target was a lower production cost for ArjoWiggins inkjet products, OMD 01 and OMD 02. Five absorbent pigments are being evaluated through measuring the qualities of the coating mix itself, visual evaluations of print performance and physical testing of the coated paper. Pigments 1,2 and 3, which all are said to be tailored for inkjet coatings, did not reach the print performance needed for an OMD 01 and OMD 02 equal, due to severe bleed and feathering identified especially on the Epson 950 printer. They are therefore currently not seen as viable formulations. A blend of 50% pigment 5 and 50% silica had excellent print performance as OMD 01 and OMD 02 equivalents and is therefore recommended as a potential alternative to 100% silica. It is of the company’s interest to find a more cost effective solution to their inkjet coatings, and a 50/50 blend of Pigment 5 will save the company more than 35 000 euro per year.
Resumo:
O objetivo deste estudo foi investigar a organização espaço-temporal dos segmentos da perna e da coxa no saltar à horizontal, verificando as infiuências do organismo e do ambiente (dois tipos de piso: concreto e areia). Participaram do estudo 21 sujeitos, 3 de cada faixa etária: 4, 5, 7, 9, 11, 13 e adulta (X = 19 anos de idade). Os sujeitos foram filmados realizando o saltar à horizontal com marcas desenhadas no centro das articulações do tornozelo, joelho e quadril. Estes pontos foram digitalizados e processados obtendo a posição e velocidade angular dos segmentos da perna e da coxa. A partir da posição e velocidade angular foi possível delinear os gráficos dos atratores (retratos de fase) e calcular os valores dos ângulos de fase para cada segmento, durante a realização da tarefa. Duas reversões para cada segmento, na posição angular, foram identificadas e nestes momentos os valores dos ângulos de fase foram capturados. Analisando as trajetórias dos retratos de fase verificou-se que os segmentos da perna e da coxa apresentaram um conjunto específico de características topológicas, na realização do saltar à horizontal. A análise dos valores dos ângulos de fase, nas duas reversões, indicou que ao longo das faixas etárias e nos dois tipos de piso os segmentos da perna e da coxa apresentaram organização espaço-temporal semelhante, indicando coordenação invariante.