Photocurrent spectroscopic studies of diketopyrrolopyrrole-based statistical copolymers

Diketopyrrolopyrrole (DPP) containing copolymers have gained a lot of interest in organic optoelectronics with great potential in organic photovoltaics. In this work, DPP based statistical copolymers, with slightly different bandgap energies and a varying fraction of donor-acceptor ratio are investigated using monochromatic photocurrent spectroscopy and Fourier-transform photocurrent spectroscopy (FTPS). The statistical copolymer with a lower DPP fraction, when blended with a fullerene derivative, shows the signature of an inter charge transfer complex state in photocurrent spectroscopy. Furthermore, the absorption spectrum of the blended sample with a lower DPP fraction is seen to change as a function of an external bias, qualitatively similar to the quantum confined Stark effect, from where we estimate the exciton binding energy. The statistical copolymer with a higher DPP fraction shows no signal of the inter charge transfer states and yields a higher external quantum efficiency in a photovoltaic structure. In order to gain insight into the origin of the observed charge transfer transitions, we present theoretical studies using density-functional theory and time-dependent density-functional theory for the two pristine DPP based statistical monomers.

Nonlinear preconditioning for efficient and accurate interface capturing in simulation of multicomponent compressible flows

Single fluid schemes that rely on an interface function for phase identification in multicomponent compressible flows are widely used to study hydrodynamic flow phenomena in several diverse applications. Simulations based on standard numerical implementation of these schemes suffer from an artificial increase in the width of the interface function owing to the numerical dissipation introduced by an upwind discretization of the governing equations. In addition, monotonicity requirements which ensure that the sharp interface function remains bounded at all times necessitate use of low-order accurate discretization strategies. This results in a significant reduction in accuracy along with a loss of intricate flow features. In this paper we develop a nonlinear transformation based interface capturing method which achieves superior accuracy without compromising the simplicity, computational efficiency and robustness of the original flow solver. A nonlinear map from the signed distance function to the sigmoid type interface function is used to effectively couple a standard single fluid shock and interface capturing scheme with a high-order accurate constrained level set reinitialization method in a way that allows for oscillation-free transport of the sharp material interface. Imposition of a maximum principle, which ensures that the multidimensional preconditioned interface capturing method does not produce new maxima or minima even in the extreme events of interface merger or breakup, allows for an explicit determination of the interface thickness in terms of the grid spacing. A narrow band method is formulated in order to localize computations pertinent to the preconditioned interface capturing method. Numerical tests in one dimension reveal a significant improvement in accuracy and convergence; in stark contrast to the conventional scheme, the proposed method retains its accuracy and convergence characteristics in a shifted reference frame. Results from the test cases in two dimensions show that the nonlinear transformation based interface capturing method outperforms both the conventional method and an interface capturing method without nonlinear transformation in resolving intricate flow features such as sheet jetting in the shock-induced cavity collapse. The ability of the proposed method in accounting for the gravitational and surface tension forces besides compressibility is demonstrated through a model fully three-dimensional problem concerning droplet splash and formation of a crownlike feature. (C) 2014 Elsevier Inc. All rights reserved.

Electric field induced short range to long range structural ordering and its influence on the Eu+3 photoluminescence in the lead-free ferroelectric Na1/2Bi1/2TiO3

Eu+3 was incorporated into the lattice of a lead-free ferroelectric Na1/2Bi1/2TiO3 (NBT) as per the nominal formula Na0.5Bi0.5-xEuxTiO3. This system was investigated with regard to the Eu+3 photoluminescence (PL) and structural behaviour as a function of composition and electric field. Electric field was found to irreversibly change the features in the PL spectra and also in the x-ray diffraction patterns below the critical composition x = 0.025. Detailed analysis revealed that below the critical composition, electric field irreversibly suppresses the structural heterogeneity inherent of the host matrix NBT and brings about a long range ferroelectric state with rhombohedral (R3c) distortion. It is shown that the structural disorder on the nano-scale opens a new channel for radiative transition which manifests as a new emission line branching off from the main D-5(0)-> F-7(0) line along with a concomitant change in the relative intensity of the other crystal field induced Stark lines with different J values. The study suggests that Eu+3 luminescence can be used to probe the relative degree of field induced structural ordering in relaxor ferroelectrics and also in high performance piezoelectric alloys where electric field couples very strongly with the lattice and structural degrees of freedom. (C) 2015 AIP Publishing LLC.

Gain bandwidth characterization of surface-emitting quantum well laser gain structures for femtosecond operation

We present a method to experimentally characterize the gain filter and calculate a corresponding parabolic gain bandwidth of lasers that are described by "class A" dynamics by solving the master equation of spectral condensation for Gaussian spectra. We experimentally determine the gain filter, with an equivalent parabolic gain bandwidth of up to 51 nm, for broad-band InGaAs/GaAs quantum well gain surface-emitting semiconductor laser structures capable of producing pulses down to 60 fs width when mode-locked with an optical Stark saturable absorber mirror. © 2010 Optical Society of America.

表面张力液柱中粘性引起的模分裂

本文证明粘性会使得表面张力所维持的无限长液柱运动模发生分裂(或称分叉),结果是每个轴对称模一次分裂为无穷个。这种现象类似于原生物理学中的 Zeemen 和 Stark效应。无粘条件下的不稳定模分裂后还出现可数无穷个负势能的稳定模,这是关于连续系统模稳定性的 Hare 和 Chandrasekhar 势能判据的一个反例,并解释其物理意义。

El desarrollo profesional de los trabajadores como ventaja competitiva de las empresas

[ES] En este trabajo se hace una revisión de la literatura sobre el concepto de profesión y a continuación se propone un modelo de desarrollo profesional en el que se destacan los retos profesionales de los trabajadores y la posibilidad de las empresas de ayudarles a afrontarlos. También se analizan los sistemas de desarrollo profesional y los roles que en ellos juegan empleados, directores y empresas. Para finalizar, se exponen varias cuestiones de actualidad relativas al desarrollo profesional: incorporación y orientación, estabilización, obsolescencia de las habilidades, doble trayectoria profesional, conflictos trabajo-familia, pérdida del puesto de trabajo y jubilación.

Neuartige flexible Selektionseinrichtungen für Schleppnetzsteerte

Die wissenschaftlich-technische Zusammenarbeit zwischen dem Institut für Fischereitechnik (IFH) und dem russischen Institut MariNPO in Kaliningrad war 1997/98 schwerpunktmäßig auf die Entwicklung flexibler Vorrichtungen zur Größenselektion von Fischen in Schleppnetzsteerten sowie deren gemeinsame Erprobung in der Ostsee-Dorschfischerei ausgerichtet. Die Vorteile solcher flexiblen Vorrichtungen aus textilem Material verglichen mit starren, meist aus Metall gefertigten bestehen darin, daß sie bei der Handhabung keine dauerhaften Verformungen bekommen, keine Erschwernisse oder Gefährdungen der Decksbesatzung, insbesondere bei schwerem Wetter, verursachen und problemlos mit dem Netz aufgetrommelt werden können. Außerdem sind sie wesentlich billiger in den Anschaffungskosten als Metallgitter aus nichtrostendem Stahl. Ihre Installation vor dem Hievteil ermöglicht zudem ein ungestörteres Selektieren als bei Fluchtfenstern im Bereich des Steertendes, wo die Fische stark verdichtet sind und mehr oder weniger gewaltsam an bzw. durch die Maschen gepreßt werden. Der Umlauftank in Kaliningrad sowie das geschleppte, steuerbare UW-Videosystem des IFH bieten gute Voraussetzungen für eine umfassende experimentelle Untersuchung der entwickelten Vorrichtungen, über die im folgenden berichtet wird.

Fangtechnische Untersuchungen zur Aal- und Plattfischfischerei in der Ostsee

Seit 1996 werden im Institut für Fischereitechnik (IFH) fangtechnische Untersuchungen zwecks Reduzierung des Beifangs bei der stark discardbelasteten Aalschleppnetzfischerei in der Ostsee durchgeführt. Diese Arbeiten wurden in Zusammenarbeit mit dem Institut für Fischerei der Landesforschungsanstalt für Landwirtschaft und Fischerei Mecklenburg-Vorpommern sowie dem Verein MARITEC e. V. durchgeführt (Gabriel und Thiele 1997; Gabriel et al. 1998). Nach Auswertung der bisher vorliegenden Ergebnisse und nach einer weiterführenden Beifanganalyse zur Schleppnetzfischerei auf Grundfischarten, insbesondere Plattfisch, in den Küstengewässern Mecklenburg-Vorpommerns wurden 1998 folgende technische Untersuchungen vorgesehen: • Überprüfung einer kombinierten Fischerei mit Plattfisch-Grundschleppnetzen und passiven Aalfanggeräten (Körbe, Langleinen, Korbketten) • Erprobung einer neuen Steertkonstruktion im Plattfischfang auf verbesserte Selektionseigenschaften • Blankaalfang mit einern pelagischen Tucknetz • Versuche in der passiven Fischerei mit verbesserten bzw. neuartigen Aalfanggeräten

Space-resolved spectral diagnosis of line-shaped laser-produced magnesium plasmas

Space-resolved spectra of line-shaped laser-produced magnesium plasmas in the normal direction of the target have been obtained using a pinhole crystal spectrograph. These spectra are treated by a spectrum analyzing code for obtaining the true spectra and fine structures of overlapped lines. The spatial distributions of electron temperature and density along the normal direction of the target surface have been obtained with different spectral diagnostic techniques. Especially, the electron density plateaus beyond the critical surface in line-shaped magnesium plasmas have been obtained with a fitting technique applied to the Stark-broadened Ly-alpha wings of hydrogenic ions. The difference of plasma parameters between those obtained by different diagnostic techniques is discussed. Other phenomena, such as plasma satellites, population inversion, etc., which are observed in magnesium plasmas, are also presented.